Related papers: Crystal-field interaction and oxygen stoichiometry…
An application of resonant inelastic x-ray scattering technique for studying of optical scale excitations in electron-correlated materials is discussed. Examples are given including data obtained for 3d transition metal, lanthanide, and…
Inelastic neutron scattering experiments were performed to investigate the crystalline electric field (CEF) excitations of Nd3+ (J = 9/2) in the iron pnictide NdFeAsO. The crystal field level structures for both the high-temperature…
Surface alloying is a straightforward route to control and modify the structure and electronic properties of surfaces. Here, We present a systematical study on the structural and electronic properties of three novel rare earth-based…
In the skutterudite compounds the anharmonic 'rattling' oscillations of 4f-host ions in the surrounding Sb12 cages are found to have significant influence on the low temperature properties. Recently specific heat analysis of…
We show that the Bloch states in the conduction band of SrTiO$_3$ arise from the interplay between highly anisotropic hopping in sub-bands derived from the Ti $t_{2g}$ orbitals and spin-orbit coupling that mixes these orbitals. Because of…
We report new quantum states in spin-orbit-coupled single crystals that are synthesized using a game-changing technology that "field-edits" crystal structures (borrowing from the phrase "genome editing") via application of magnetic field…
An influence of high magnetic fields on hyperfine interaction in the rare-earth ions with non-magnetic ground state (Van Vleck ions) is theoretically investigated for the case of $Tm^{3+}$ ion in axial symmetrical crystal electric field…
Synthesis and crystal structures are described for the compounds Ln2(Ti2-xLnx)O7-x/2, where Ln = Tb, Dy, Ho, Er, Tm, Yb, Lu, and x ranges from 0 to 0.67. Rietveld refinements on X-ray powder diffraction data indicate that in Tb and Dy…
Rare-earth ion doped crystals have proven to be solid platforms for implementing quantum memories. Their potential use for integrated photonics with large multiplexing capability and unprecedented coherence times is at the core of their…
Rare earth oxides have attracted interest as a platform for studying frustrated magnetism arising from bond dependent anisotropic interactions. Ordered rock salt compounds Na$_2$PrO$_3$ crystallize in two polymorphs ($\alpha$ and $\beta$)…
Neutron time-of-flight spectroscopy has been employed to study the crystal-field splitting of Pr$^{3+}$ in the pyrochlore stannate Pr$_{2}$Sn$_{2}$O$_{7}$. The crystal field has been parameterized from a profile fit to the observed neutron…
We characterise optical transitions of neodymium ions (Nd3+) in antiferromagnetic neodymium gallate (NdGaO3) with applied fields up to 3 T. The magnetic phase of this material has not previously been studied with the field along its…
The misfit oxide, Bi$_{2}$Ba$_{1.3}$K$_{0.6}$Co$_{2.1}$O$_{y}$, made of alternating rocksalt-structured [BiO/BaO] layers and hexagonal CoO$_{2}$ layers, was studied by angle-resolved photoemission spectroscopy. Detailed electronic structure…
We present a theory describing the local electronic properties of the perovskite rare earth nickelates--materials which have negative charge transfer energies, strong O $2p$ -- Ni $3d$ covalence, and breathing mode lattice distortions at…
Strong field ionization provides a unique mean to address complex dynamics of an electron in competing Coulomb and laser fields. Recent streak camera experiment (K\"ubel, et al., Phys. Rev. Lett. 119, 183201) analyzed asymmetries in the…
Three orders of magnitude cavity-linewidth narrowing in a rare-earth-ion-doped crystal cavity, induced by strong intra-cavity dispersion caused by off-resonant interaction with dopant ions is demonstrated. The strong dispersion is created…
In the framework of the LDA+U approximation we propose the direct way of calculation of crystal-field excitation energy and apply it to La and Y titanates. The method developed can be useful for comparison with the results of spectroscopic…
The interaction of high energy particles with atomic axes and planes allows to observe in crystal various effects predicted by the quantum electrodynamics of phenomena in strong electromagnetic field. In particular, the effect of…
Optically active defects suspended in an inert solid are an interesting system for sensing and magnetometry at the nanometer scale, in addition to being a potential source of high-density, identical quantum emitters for quantum information.…
Ce compounds feature a remarkable diversity of electronic properties, which motivated extensive investigations over the last decades. Inelastic neutron scattering represents an important tool for understanding their underlying electronic…