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An investigation of the pressure induced phase transition from the scheelite phase (I41/a, Z=4) to the fergusonite-like phase (I2/a, Z=4)/LaTaO(P21/c, Z=4) of LiYF4 is presented. Employing density functional theory (DFT) within the…

We report the results of both angle-dispersive x-ray diffraction and x-ray absorption near-edge structure studies in BaWO4 and PbWO4 at pressures of up to 56 GPa and 24 GPa, respectively. BaWO4 is found to undergo a pressure-driven phase…

The pressure response of the scheelite phase of CaWO4 (YLiF4) and the occurrence of the pressure induced scheelite-to-wolframite (M-fergusonite) transition are reviewed and discussed. It is shown that the change of the axial parameters…

Materials Science · Physics 2009-11-10 D. Errandonea , F. J. Manjon , M. Somayazulu , D. Hausermann

We report here the combined results of angle-dispersive x-ray diffraction experiments performed on ThGeO4 up to 40 GPa and total-energy density-functional theory calculations. Zircon-type ThGeO4 is found to undergo a pressure-driven phase…

Materials Science · Physics 2010-07-02 D. Errandonea , Ravhi. S. Kumar , L. Gracia , A. Beltran , S. N. Achary , A. K. Tyagi

Angle-dispersive x-ray diffraction (ADXRD) and x-ray absorption near edge structure (XANES) measurements have been performed in the AWO4 tungstates CaWO4 and SrWO4 under high pressure up to approximately 20 GPa. Similar phase transitions…

Using in-situ angle dispersive x-ray diffraction, we have shown that barium tungstate, which exists in scheelite phase at ambient conditions, transforms to a new phase about seven giga pascal. Analysis of our data based on Le bail…

Materials Science · Physics 2009-11-10 Vinod Panchal , Nandini Garg , A. K. Chauhan , Sangeeta , Surinder M. Sharma

The pressure-driven tetragonal-to-monoclinic phase transition in CaWO4 and related scheelite-structured orthotungstates is analysed in terms of spontaneous strains. Based upon our previous high-pressure x-ray diffraction results and the…

Materials Science · Physics 2007-05-23 D. Errandonea

SrMoO4 was studied under compression up to 25 GPa by angle-dispersive x-ray diffraction. A phase transition was observed from the scheelite-structured ambient phase to a monoclinic fergusonite phase at 12.2(9) GPa with cell parameters a =…

Materials Science · Physics 2008-02-04 Daniel Errandonea , Ravhi S. Kumar , Xinghua Ma , Chaoyang Tu

X-ray diffraction and Raman scattering studies on scheelite structured barium molybdate show that, at 5.8 GPa, it undergoes a first order phase transition to fergusonite structure (I2/a, Z=4), asobserved in iso-structural barium…

Materials Science · Physics 2009-11-11 Vinod Panchal , Nandini Garg , Surinder M. Sharma

LuFe$_4$Ge$_2$ crystallizes in the ZrFe$_4$Si$_2$-type structure, hosting chains of Fe-tetrahedra giving rise to geometric frustration and low-dimensionality. The compound orders antiferromagnetically at around 36 K accompanied by a…

Room temperature angle-dispersive x-ray diffraction measurements on zircon-type EuVO4, LuVO4, and ScVO4 were performed up to 27 GPa. In the three compounds we found evidence of a pressure-induced structural phase transformation from zircon…

Materials Science · Physics 2010-05-04 D. Errandonea , R. Lacomba-Perales , J. Ruiz-Fuertes , A. Segura , S. N. Achary , A. K. Tyagi

We report a high-pressure study of tetragonal scheelite-type CaMoO4 up to 29 GPa. In order to characterize its high-pressure behavior, we have combined Raman and optical-absorption measurements with density-functional theory calculations.…

Materials Science · Physics 2017-09-29 V. Panchal , N. Garg , H. K. Poswal , D. Errandonea , P. Rodriguez-Hernandez , A. Munoz , E. Cavalli

We study the effects of pressure on the structural, vibrational, and magnetic behavior of cuproscheelite. We performed powder x-ray diffraction and Raman spectroscopy experiments up to 27 GPa as well as ab initio total-energy and…

In this paper we perform a high-pressure study of fergusonite-type HoNbO4. Powder x-ray diffraction experiments and ab initio density-functional theory simulations provide evidence of a phase transition at 18.9(1.1) GPa from the monoclinic…

Materials Science · Physics 2025-08-08 A. B. Garg , D. Errandonea , P. Rodriguez-Hernandez , A. Munoz

Two-dimensional (2D) Fe-chalcogenides with rich structures, magnetisms and superconductivities are highly desirable to reveal the torturous transition mechanism and explore their potential applications in spintronics and nanoelectronics.…

We report a detailed investigation of the elastic properties of Rb4LiH3(SO4)4 measured as a function of temperature and pressure. Rb4LiH3(SO4)4 is known to show a 4 - 2 ferroelastic phase transition at Tc = 134 K. In order to clarify the…

Other Condensed Matter · Physics 2007-05-23 G. Quirion , W. Wu , J. Rideout , B. Mroz

The high-pressure structural behavior of europium orthovanadate has been studied using in-situ, synchrotron based, high-pressure x-ray powder diffraction technique. Angle-dispersive x-ray diffraction measurements were carried out at room…

Materials Science · Physics 2015-03-12 Alka B. Garg , D. Errandonea

We report studies of in-situ x-ray diffraction (XRD) and electronic properties on the single crystalline of Fe1.05Te compound under high pressure. The results demonstrated that the sample undergoes a pressure-induced lattice collapse in…

Superconductivity · Physics 2009-12-01 Chao Zhang , Wei Yi , Liling Sun , Wei Lu , Xiaoli Dong , Ligang Bai , Jing Liu , Genfu Chen , Nanlin Wang , Zhongxian Zhao

AgClO4 has been studied under compression by x-ray diffraction and density functional theory calculations. Experimental evidence of a structural phase transition from the tetragonal structure of AgClO4 to an orthorhombic barite-type…

Materials Science · Physics 2012-04-20 D. Errandonea , L. Gracia , A. Beltran , A. Vegas , Y. Meng

We report on the crystal structure and electronic properties of the heavy fermion superconductor UTe2 at high pressure up to 11 GPa, as investigated by X-ray diffraction and electrical resistivity experiments. The X-ray diffraction…

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