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We report density functional theory calculations on the crystal structure, elastic, lattice dynamics and electronic properties of iso-structural layered monoclinic alkali azides, LiN3 and NaN3. The effect of van der Waals interactions on…

Materials Science · Physics 2013-11-04 K. Ramesh Babu , G. Vaitheeswaran

The crystal structure, mechanical properties and electronic structure of ground state BeH$_{2}$ are calculated employing the first-principles methods based on the density functional theory. Our calculated structural parameters at…

Materials Science · Physics 2015-05-13 Bao-Tian Wang , Ping Zhang , Hongliang Shi , Bo Sun , Weidong Li

We report a detailed first principles study on the structural, elastic, vibrational and thermodynamic properties of layered structure energetic alkali metal azides KN$_3$ and RbN$_3$. All the calculations were carried out by means of plane…

Materials Science · Physics 2013-11-07 K. Ramesh Babu , G. Vaitheeswaran

We report a detailed theoretical study of the structural, vibrational, and optical properties of solid nitromethane using first principles density functional calculations. The ground state properties were calculated using a plane wave…

Materials Science · Physics 2015-06-17 S. Appalakondaiah , G. Vaitheeswaran , S. Lebegue

Titanium nitride halides, TiNX (X = F, Cl, Br, I) in the {\alpha}-phase (orthorhombic) are exciting quasi two-dimensional (2D) electronic systems exhibiting a fascinating series of electronic ground states under different conditions.…

Materials Science · Physics 2020-04-22 M. M. Hossain , S. H. Naqib

The electronic band structures of two-dimensional materials are significantly different from those of their bulk counterparts, due to quantum confinement and strong modifications of electronic screening. An accurate determination of…

Mesoscale and Nanoscale Physics · Physics 2020-07-08 Tomáš Rauch , Miguel A. L. Marques , Silvana Botti

We report the structural, elastic and vibrational properties of five ionic-molecular solid oxidizers MNO$_3$ (M = Li, Na, K) and MClO$_3$ (M = Na, K). By treating long range electron-correlation effects, dispersion corrected method leads to…

Materials Science · Physics 2016-09-05 N. Yedukondalu , G. Vaitheeswaran

We have investigated the electronic, vibrational, optical, thermal and piezoelectric properties of LiNbO$_3$, LiTaO$_3$ and Li$_2$NbTaO$_6$ using the first-principles calculation based on the density functional theory. It also shows…

Materials Science · Physics 2025-03-28 Debidutta Pradhan , Rojalin Swain , Souvagya Kumar Biswal , Jagadish Kumar

We study the electronic structures and dielectric functions of the simple hydrides LiH, NaH, MgH2 and AlH3, and the complex hydrides Li3AlH6, Na3AlH6, LiAlH4, NaAlH4 and Mg(AlH4)2, using first principles density functional theory and GW…

Materials Science · Physics 2007-05-23 M. J. van Setten , V. A. Popa , G. A. de Wijs , G. Brocks

NaSn2P2 is a recently discovered superconducting system belonging to a particular class of materials with van der Waals structure. There is enormous interest in such compounds because of their intriguing electrical, optical, chemical,…

Materials Science · Physics 2020-11-24 F. Parvin , S. H. Naqib

A systematic computational study on the structural, electronic, bonding, and optical properties of orthorhombic ammonium azide (NH$_4$N$_3$) has been performed using planewave pseudopotential (PW-PP) method based on density functional…

Materials Science · Physics 2013-11-07 N. Yedukondalu , Vikas D. Ghule , G. Vaitheeswaran

In the present work, the atomic and the electronic structures of Au3N, AuN and AuN2 are investigated using first-principles density-functional theory (DFT). We studied cohesive energy vs. volume data for a wide range of possible structures…

Materials Science · Physics 2015-11-24 Mohammed S. H. Suleiman , Daniel P. Joubert

Theoretically, various physical properties of AV$_{2}$O$_{4}$ (A=Zn, Cd and Mg) spinels have been extensively studied for last 15 years. Besides of this, no systematic comparative study has been done for these compounds, where the material…

Strongly Correlated Electrons · Physics 2017-04-24 Sohan Lal , Sudhir K. Pandey

We present exemplary results of extensive studies of mechanical, electronic and transport properties of covalent functionalization of graphene monolayers (GML) with -NH2. We report new results of ab initio studies of covalent…

Materials Science · Physics 2014-01-24 Karolina Z. Milowska , Jacek A. Majewski

We investigated the structural, elastic, electronic, vibrational, optical, thermodynamic and a number of thermophysical properties of W2N3 in this study using DFT based formalisms. The mechanical and dynamical stabilities have been…

Materials Science · Physics 2024-02-26 Istiak Ahmed , F. Parvin , R. S. Islam , S. H. Naqib

In the present study we have investigated the structural properties, electronic band dispersion, elastic constants, acoustic behavior, phonon spectrum, optical properties, and a number of thermophysical parameters of binary topological…

Materials Science · Physics 2022-01-04 M. I. Naher , S. H. Naqib

The elastic, electronic and optical properties of MNNi3 (M= Zn, Sn and Cu) have been calculated using the plane-wave ultrasoft pseudopotential technique which is based on the first-principles density functional theory (DFT) with generalized…

Materials Science · Physics 2015-05-30 M. A. Helal , A. K. M. A. Islam

The electronic structure of high-quality van der Waals NiPS$_3$ crystals was studied using near-edge x-ray absorption spectroscopy (NEXAFS) and resonant photoelectron spectroscopy (ResPES) in combination with density functional theory (DFT)…

We report a series of calculations testing the predictions of the Tran-Blaha functional for the electronic structure and magnetic properties of condensed systems. We find a general improvement in the properties of semiconducting and…

Materials Science · Physics 2010-11-08 David J. Singh

The atomic and electronic structures of Pd3N, PdN and PdN2 were investigated using ab initio density-functional theory (DFT). We studied cohesive energy vs. volume equation of states (EOS) for a set of reported and hypothetical structures.…

Materials Science · Physics 2013-10-11 Mohammed S. H. Suleiman , Daniel P. Joubert
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