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We report on a theoretical study of the electronic structures of the [111]-oriented, free-standing, zincblende InAs and InP nanowires with hexagonal cross sections by means of an atomistic $sp^{3}s^{*} $, spin-orbit interaction included,…

Mesoscale and Nanoscale Physics · Physics 2016-03-09 Gaohua Liao , Ning Luo , Ke-Qiu Chen , H. Q. Xu

We perform comprehensive density-functional theory calculations on strained two-dimensional phosphorus (P), arsenic (As) and antimony (Sb) in the monolayer, bilayer, and bulk $\alpha$-phase, from which we compute the key mechanical and…

Materials Science · Physics 2018-01-26 Glenn Moynihan , Stefano Sanvito , David D. O'Regan

The paper discusses a model of Van der Waals crystals in which band-gap structures do not form. An effect of strong and chaotic electron-electron repulsion, which was excluded from consideration in the traditional approach, is taken into…

Superconductivity · Physics 2007-05-23 V. N. Bogomolov

Phonon density of states calculation shows that a new TiO2 polymorph with tridymite structure is mechanically stable. Enthalpies of 9 TiO2 polymorphs under different pressure are presented to study the relative stability of the TiO2…

Materials Science · Physics 2014-06-11 Tong Zhu , Shang-Peng Gao

The growing families of two-dimensional crystals derived from naturally occurring van der Waals materials offer an unprecedented platform to investigate elusive physical phenomena and could be of use in a diverse range of devices. Of…

Using density functional theory calculations, many researchers have predicted that various tungsten-nitride compounds WN$_x$ ($x$ > 1) will be "ultra-compressible" or "superhard", $i.e.$ as hard as or harder than diamond. These compounds…

Materials Science · Physics 2015-06-11 Michael J. Mehl , Daniel Finkenstadt , Christian Dane , Gus L. W. Hart , Stefano Curtarolo

We propose accurate computable error bounds for quantities of interest in plane-wave electronic structure calculations, in particular ground-state density matrices and energies, and interatomic forces. These bounds are based on an…

Numerical Analysis · Mathematics 2022-10-20 Eric Cancès , Geneviève Dusson , Gaspard Kemlin , Antoine Levitt

The increasing interest of nanowhiskers for technological applications has led to the observation of the zinc-blend/wurtzite polytypism. Polytypic nanowhiskers could also play, by their characteristics, an important role on the design of…

Mesoscale and Nanoscale Physics · Physics 2015-03-17 Paulo Eduardo de Faria Junior , Guilherme Matos Sipahi

We propose a new layered-ternary Ta4SiC3 with two different stacking sequences ({\alpha}- and {\beta}-phases) of the metal atoms along c axis and study their structural stability. The mechanical, electronic and optical properties are then…

Materials Science · Physics 2015-05-19 M. S. Islam , A. K. M. A. Islam

Silicon carbide is widely used in electronics, ceramics, and renewable energy due to its exceptional hardness and resistance. In this study, we investigate the effects of hydrostatic and uniaxial pressure (both compressive and tensile) on…

Materials Science · Physics 2025-09-03 Carlos P. Herrero , Eduardo R. Hernandez , Gabriela Herrero-Saboya , Rafael Ramirez

The electronic band structures and optical properties of cubic, tetragonal, and monoclinic phases of HfO2 are calculated using the first-principles linear augmented plane-wave method, within the density functional theory and generalized…

We report an ab initio molecular dynamics simulation study of several static and dynamic properties of the liquid 3d transition metals. The calculated static structure factors show qualitative agreement with the available experimental data,…

Soft Condensed Matter · Physics 2020-05-27 B. G. del Rio , C. Pascual , O. Rodriguez , L. E. González , D. J. González

We investigate the elastic properties of selected zincblende III-V semiconductors. Using hybrid functional density functional theory we calculate the second and third order elastic constants, and first and second-order internal strain…

Computational Physics · Physics 2018-12-12 Daniel S. P. Tanner , Miguel A. Caro , Stefan Schulz , Eoin P. O'Reilly

The quasiparticle band structures of 3d transition metals, ferromagnetic Fe, Ni and paramagnetic Cu, are calculated by the GW approximation. The width of occupied 3d valence band, which is overestimated in the LSDA, is in good agreement…

Materials Science · Physics 2009-11-07 Atsushi Yamasaki , Takeo Fujiwara

Two-dimensional (2D) transition-metal dichalcogenide (TMD) MX$_2$ (M = Mo, W; X= S, Se, Te) possess unique properties and novel applications. In this work, we perform first-principles calculations on the van der Waals (vdW) stacked MX$_2$…

We present a detailed quantum mechanical non empirical DFT investigation of the energy-optimized geometries, phase stabilities and electronic properties of bulk Pt3N, PtN and PtN2 in a set of twenty different crystal structures. Structural…

Materials Science · Physics 2013-01-24 Mohammed S. H. Suleiman , Daniel P. Joubert

Motivated by the successful synthesis of isolated ZrS2 and HfS2 transition metal dichalcogenide (TMD) monolayers and inspired by their nearly identical lattice constants, we construct and investigate a vertical ZrS2/HfS2 van der Waals (vdW)…

Materials Science · Physics 2025-12-23 Mohammad Ali Mohebpour , Carmine Autieri , Meysam Bagheri Tagani

Ternary semiconductor CuYS2 is studied by using the first-principles methods in the density functional theory (DFT) framework. The structural, electronic, optical and elastic properties were calculated at the ambient and elevated…

Materials Science · Physics 2013-09-13 M. G. Brik

In the present work we have studied the structural and electronic properties of recently synthesized elusive free standing triangulene using density functional theory. Triangulene, which is a type of graphene quantum dot, is a molecule with…

Mesoscale and Nanoscale Physics · Physics 2017-12-11 Vaishali Sharma , Som Narayan , Shweta D Dabhi , Prafulla K Jha

Ferromagnetic van der Waals (vdW) insulators are of great scientific interest for their promising applications in spintronics. It has been indicated that in the two materials within this class, CrI$_3$ and VI$_3$, the magnetic ground state,…

Strongly Correlated Electrons · Physics 2020-12-15 Asish K. Kundu , Yu Liu , C. Petrovic , T. Valla