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We report a detailed theoretical study of the structural, vibrational, and optical properties of solid nitromethane using first principles density functional calculations. The ground state properties were calculated using a plane wave…

Materials Science · Physics 2015-06-17 S. Appalakondaiah , G. Vaitheeswaran , S. Lebegue

We report a detailed first principles study on the structural, elastic, vibrational and thermodynamic properties of layered structure energetic alkali metal azides KN$_3$ and RbN$_3$. All the calculations were carried out by means of plane…

Materials Science · Physics 2013-11-07 K. Ramesh Babu , G. Vaitheeswaran

We have performed {\it ab initio} calculations for a series of energetic solids to explore their structural and electronic properties. To evaluate the ground state volume of these molecular solids, different dispersion correction methods…

Materials Science · Physics 2015-09-29 S. Appalakondaiah , G. Vaitheeswaran , S. Lebègue

We report density functional theory calculations on the crystal structure, elastic, lattice dynamics and electronic properties of iso-structural layered monoclinic alkali azides, LiN3 and NaN3. The effect of van der Waals interactions on…

Materials Science · Physics 2013-11-04 K. Ramesh Babu , G. Vaitheeswaran

We present a theoretical study of the structural, electronic and transport properties of bulk Bi2Te3 within density functional theory taking into account the van der Waals interactions (vdW) and the quasiparticle self-energy corrections. It…

Materials Science · Physics 2014-08-20 L. Cheng , H. J. Liu , J. Zhang , J. Wei , J. H. Liang , J. Shi , X. F. Tang

We study the structural and electronic properties of phase III of solid hydrogen using accurate many-electron theories and compare to state-of-the-art experimental findings. The atomic structures of phase III modelled by C2/c-24 crystals…

Materials Science · Physics 2021-02-24 Ke Liao , Tong Shen , Xin-Zheng Li , Ali Alavi , Andreas Grüneis

Structural stability and vibrational properties of KN$_3$ have been studied under pressure using the first principles calculations based on the density functional theory (DFT) as well as with semi empirical dispersion correction to the DFT…

Materials Science · Physics 2013-11-08 K. Ramesh Babu , G. Vaitheeswaran

Ab-initio, self-consistent electronic energy bands of rutile TiO2 are reported within the local density functional approximation (LDA). Our first principle, non-relativistic and ground state calculations employed a local density functional…

Materials Science · Physics 2012-03-23 C. E. Ekuma , D. Bagayoko

We present comprehensive measurements of the structural, magnetic and electronic properties of layered van-der-Waals ferromagnet VI$_3$ down to low temperatures. Despite belonging to a well studied family of transition metal trihalides,…

First-principles calculations using the plane-wave pseudopotential method within the generalized gradient approximation method were performed to study the pressure dependence of the structural, elastic, electronic and optical properties for…

Materials Science · Physics 2021-12-21 M. Radjai , A. Bouhemadou , D. Maouche

A GW calculation based on a truncated Coulomb interaction with an added small q limit was applied to 2D van der Waals heterolayered structures, and the Kane dispersion model was used to determine the accurate band gap edge. All ab initio…

Materials Science · Physics 2025-06-25 Eyasu Tadesse Muda , Tewodros Eyob Ada , Kenate Nemera Nigussa , Cecil N. M. Ouma

A detailed study of the high-pressure structural properties, lattice dynamics and band structures of perovskite structured fluorides KZnF3, CsCaF3 and BaLiF3 has been carried out by means of density functional theory. The calculated…

Materials Science · Physics 2016-09-05 Vaitheeswaran G , Kanchana V , Zhang X , Ma Y , Svane A , Christensen NE

We report a density-functional theory study of the structural and electronic properties of Cd2V2O7 under high-pressure conditions. The calculations have been performed by using first-principle calculations with the CRYSTAL program. The…

Materials Science · Physics 2022-05-23 Daniel Diaz-Anichtchenko , Daniel Errandonea

We study a newly predicted layered-ternary compound Ti4SiN3 in its {\alpha}- and {\beta}-phases. We calculate their mechanical, electronic and optical properties and then compare these with those of other compounds M4AX3 (M = V, Ti, Ta; A =…

Materials Science · Physics 2011-08-03 M. M. Hossain , M. S. Ali , A. K. M. A. Islam

We utilized a simple, robust, first principle method, based on basis set optimization with the BZW-EF method, to study the electronic and related properties of transition metal mono-nitrides: ScN and YN. We solved the KS system of equations…

Materials Science · Physics 2012-09-04 C. E. Ekuma , D. Bagayoko , M. Jarrell , J. Moreno

We study the relationship between the shape of the electronic band structure and the thermoelectric properties. In order to study the band shape dependence of the thermoelectric properties generally, we first adopt models with band…

Materials Science · Physics 2017-05-17 Hidetomo Usui , Kazuhiko Kuroki

We compute the electronic band structure and optical properties of boron arsenide using the relativistic quasiparticle self-consistent $GW$ approach, including electron-hole interactions through solution of the Bethe-Salpeter equation. We…

Materials Science · Physics 2019-06-07 John Buckeridge , David O. Scanlon

We use density functional theory and the van der Waals density functional (vdW-DF) method to determine the binding separation in bilayer and bulk graphane and study the changes in electronic band structure that arise with the multilayer…

Materials Science · Physics 2015-05-20 Jochen Rohrer , Per Hyldgaard

Bi2Se3 and Bi2Te3 are layered compounds of technological importance, being excellent thermoelectric materials as well as topological insulators. We report density functional theory calculations of the atomic, electronic and thermoelectric…

Materials Science · Physics 2013-08-08 Xin Luo , Michael B. Sullivan , Su Ying Quek

We present density functional theory calculations on the crystal structure, equation of state, vibrational properties and electronic structure of nitrogen-rich solid energetic material guanidinium 2-methyl-5-nitraminotetrazolate (G-MNAT).…

Materials Science · Physics 2015-06-18 K. Ramesh Babu , G. Vaitheeswaran
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