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We describe a first-order phase transition of a simple system in a process where the volume is kept constant. We show that, unlike what happens when the pressure is constant, (i) the transformation extends over a finite temperature (and…

Classical Physics · Physics 2022-01-12 V. F. Correa , F. J. Castro

From a new rigorous formulation of the general axiomatic foundations of thermodynamics we derive an operational definition of entropy that responds to the emergent need in many technological frameworks to understand and deploy thermodynamic…

Mathematical Physics · Physics 2014-11-21 Gian Paolo Beretta , Enzo Zanchini

Maximum-entropy ensembles are key primitives in statistical mechanics from which thermodynamic properties can be derived. Over the decades, several approaches have been put forward in order to justify from minimal assumptions the use of…

Quantum Physics · Physics 2018-03-13 Paul Boes , Henrik Wilming , Jens Eisert , Rodrigo Gallego

In the theory of superfluidity and superconductivity, a jump of the free energy was discovered theoretically and was naturally called a {\it zeroth-order phase transition}. We present an example of an exactly solvable problem in which such…

Superconductivity · Physics 2016-08-31 V. P. Maslov

Entropy and order parameter are two key concepts in phase transition theory. This paper proposes an unified method to both find order parameter and estimate entropy automatically with unsupervised learning. The contributions of this paper…

Disordered Systems and Neural Networks · Physics 2017-12-18 Kun Huang

Many physicists think that the maximum entropy formalism is a straightforward application of Bayesian statistical ideas to statistical mechanics. Some even say that statistical mechanics is just the general Bayesian logic of inductive…

Statistical Mechanics · Physics 2007-05-23 Cosma Rohilla Shalizi

A new point of view about the deep origin of thermodynamic phase transitions is sketched. The main idea is to link the appearance of phase transitions to some major topology change of suitable submanifolds of phase space instead of linking…

Statistical Mechanics · Physics 2017-08-23 Marco Pettini , Roberto Franzosi , Lionel Spinelli

This article characterizes phase transitions in temperature within a specific space of H\"older continuous potentials, distinguished by their regularity and asymptotic behavior at zero. We also characterize the phase transitions in…

Dynamical Systems · Mathematics 2025-04-03 Daniel Coronel , Juan Rivera-Letelier

Liquid-liquid phase separation has recently emerged as an important topic in the context of cellular organization. Within this context, there are multiple poorly understood features; for instance hints of critical behavior in the plasma…

Statistical Mechanics · Physics 2024-06-25 Felix Herrmann , Burkhard Dünweg , Martin Girard

The set of solutions inferred by the generic maximum entropy (MaxEnt) or maximum relative entropy (MaxREnt) principles of Jaynes - considered as a function of the moment constraints or their conjugate Lagrangian multipliers - is endowed…

Statistical Mechanics · Physics 2017-08-23 Robert K. Niven , Bjarne Andresen

First-order phase transitions produce gravitational waves and primordial black holes. They always occur in field theories where symmetries are radiatively broken and masses are correspondingly generated. These theories predict a period of…

High Energy Physics - Phenomenology · Physics 2026-05-19 Alberto Salvio

This work presents a general unifying theoretical framework for quantum non-equilibrium systems. It is based on a re-statement of the dynamical problem as one of inferring the distribution of collision events that move a system toward…

Quantum Physics · Physics 2015-03-30 David M. Rogers

Phase transitions in nuclei, small atomic clusters and self-gravitating systems demand the extension of thermo-statistics to ``Small'' systems. The main obstacle is the thermodynamic limit. It is shown how the original definition of the…

Statistical Mechanics · Physics 2017-08-23 D. H. E. Gross

Entropy might be a not well defined concept if the system can undergo transformations involving stationary nonequilibria. It might be analogous to the heat content (once called ``caloric'') in transformations that are not isochoric (i.e.…

Statistical Mechanics · Physics 2007-05-23 Giovanni Gallavotti

We consider first-order phase transitions of the Universe in the radiation-dominated era. We argue that in general the velocity of interfaces is non-relativistic due to the interaction with the plasma and the release of latent heat. We…

High Energy Physics - Phenomenology · Physics 2014-11-17 Ariel Megevand

Nuclear thermodynamics studies evidenced the existence of a first order phase transition, namely of the liquid-gas type, without paying attention to the isospin degree of freedom. On the other hand, only few results with the introduction of…

Nuclear Experiment · Physics 2017-04-26 B. Borderie

New exact results about the nonequilibrium thermodynamics of open quantum systems at arbitrary timescales are obtained by considering all possible variations of initial conditions of a system, its environment, and correlations between them.…

Statistical Mechanics · Physics 2021-05-05 Paul M. Riechers , Mile Gu

We systematically explore and show the existence of finite-temperature continuous quantum phase transition (CTQPT) at a critical point, namely, during solidification or melting such that the first-order thermal phase transition is a special…

Strongly Correlated Electrons · Physics 2014-05-20 Andrew Das Arulsamy

Developing a thermodynamic theory of computation is a challenging task at the interface of non-equilibrium thermodynamics and computer science. In particular, this task requires dealing with difficulties such as stochastic halting times,…

Statistical Mechanics · Physics 2024-05-14 Gonzalo Manzano , Gülce Kardeş , Édgar Roldán , David Wolpert

Recently, dynamical phase transitions have been identified based on the non-analytic behavior of the Loschmidt echo in the thermodynamic limit [Heyl et al., Phys.~Rev.~Lett.~{\bf 110}, 135704 (2013)]. By introducing conditional probability…

Strongly Correlated Electrons · Physics 2015-01-09 Elena Canovi , Philipp Werner , Martin Eckstein
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