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A construction of node-less atomic orbitals and energy-dependent, node-reduced partial waves is presented, that contains the full information of the atomic eigenstates and that allows to represent the scattering properties in a transparent…

Chemical Physics · Physics 2012-10-23 Peter E. Blöchl , Clemens Först

The decomposition of electronic and nuclear motion presented in~[A. Abedi, N. T. Maitra, and E. K. U. Gross, Phys. Rev. Lett. 105, 123002 (2010)] yields a time-dependent potential that drives the nuclear motion and fully accounts for the…

Chemical Physics · Physics 2015-06-22 Federica Agostini , Ali Abedi , Yasumitsu Suzuki , Seung Kyu Min , Neepa T. Maitra , E. K. U. Gross

The spectra (rotational, rotation-vibrational or electronic) of diatomic molecules due to transitions involving only closed-shell ($^1\Sigma$) electronic states follow very regular, simple patterns and their theoretical analysis is usually…

Chemical Physics · Physics 2016-05-10 Jonathan Tennyson , Lorenzo Lodi , Laura K. McKemmish , Sergei N Yurchenko

The limit relations for the partial derivatives of the two-electron atomic wave functions at the two-particle coalescence lines have been obtained numerically using accurate CFHHM wave functions. The asymptotic solutions of the proper…

Atomic Physics · Physics 2009-11-11 E. Z. Liverts , M. Ya. Amusia , R. Krivec , V. B. Mandelzweig

In coupled cluster methods, the electronic states are biorthonormal in the sense that the left states are orthonormal to the right states. Here we present an extension of this formalism to a left and right total molecular wave function.…

Chemical Physics · Physics 2020-07-15 Eirik F. Kjønstad , Henrik Koch

Quantum stochastic methods based on effective wave functions form a framework for investigating the generally non-Markovian dynamics of a quantum-mechanical system coupled to a bath. They promise to be computationally superior to the…

Statistical Mechanics · Physics 2014-10-15 Robert Biele , Carsten Timm , Roberto D'Agosta

The two-dimensional cubic nonlinear Schr\"{o}dinger equation is used to describe the propagation of an intense laser beam through a medium with Kerr nonlinearity. The coupled two-dimensional cubic nonlinear Schr\"{o}dinger equations are…

Mathematical Physics · Physics 2008-07-01 Xiaoping Xu

Quantum stochastic differential equations have been used to describe the dynamics of an atom interacting with the electromagnetic field via absorption/emission processes. Here, by using the full quantum stochastic Schroedinger equation…

Quantum Physics · Physics 2009-10-31 Alberto Barchielli , Giancarlo Lupieri

Using perturbative methods, we analyse a nonlinear generalisation of Schrodinger's equation that had previously been obtained through information-theoretic arguments. We obtain analytical expressions for the leading correction, in terms of…

Quantum Physics · Physics 2008-11-26 R. Parwani , G. Tabia

Low-energy cross sections for elastic scattering and recoil of protons from $^4$He nuclei (also known as $\alpha$ particles) are calculated directly by solving the Schr\"odinger equation for five nucleons interacting through accurate two-…

Nuclear Theory · Physics 2014-12-17 Guillaume Hupin , Sofia Quaglioni , Petr Navrátil

We present an ab initio approach to solve the time-dependent Schr\"odinger equation to treat electron and photon impact multiple ionization of atoms or molecules. It combines the already known time scaled coordinate method with a new high…

We formulate a time-dependent density functional theory for the coupled dynamics of electrons and nuclei that goes beyond the Born-Oppenheimer (BO) approximation. We prove that the time-dependent marginal nuclear probability density…

Chemical Physics · Physics 2025-11-14 Chen Li , Ryan Requist , E. K. U. Gross

Various origins of linear and nonlinear Schrodinger equations are discussed in connection with diffusion, hydrodynamics, and fractal structure. The treatment is mainly expository, emphasizing the quantum potential, with a few new…

Quantum Physics · Physics 2007-05-23 Robert Carroll

The Schrodinger equation has been considered to be a postulate of quantum physics, but it is also perceived and derived heuristically as the quantum equivalent of the classical energy relation. We indicate that the Schrodinger equation…

Quantum Physics · Physics 2013-07-24 Spyros Efthimiades

The local conservation of a physical quantity whose distribution changes with time is mathematically described by the continuity equation. The corresponding time parameter, however, is defined with respect to an idealized classical clock.…

Chemical Physics · Physics 2018-11-21 Axel Schild

In this paper, we introduce a new scheme for the efficient numerical treatment of the electronic Schr\"odinger equation for molecules. It is based on the combination of a many-body expansion, which corresponds to the so-called bond order…

Numerical Analysis · Mathematics 2017-07-20 Sambasiva Rao Chinnamsetty , Michael Griebel , Jan Hamaekers

We introduce a new family of trial wave-functions based on deep neural networks to solve the many-electron Schr\"odinger equation. The Pauli exclusion principle is dealt with explicitly to ensure that the trial wave-functions are physical.…

Computational Physics · Physics 2020-07-21 Jiequn Han , Linfeng Zhang , Weinan E

We use the Bohr-Sommerfeld quantization approach in the context of constituent quark models. This method provides, for the Cornell potential, analytical formulae for the energy spectra which closely approximate numerical exact calculations…

High Energy Physics - Phenomenology · Physics 2007-05-23 Fabian Brau

The recently introduced scheme [20,21] is extended to propose an algebraic non-perturbative approach for the analytical treatment of Schr\"odinger equations with non-solvable potentials involving an exactly solvable potential form together…

Mathematical Physics · Physics 2016-07-12 B Gonul , Y Cancelik

Stochastic Schr\"odinger equations that govern the dynamics of open quantum systems are given by the equations for signal processing. In particular, the Brownian motion that drives the wave function of the system does not represent noise,…

Biological Physics · Physics 2022-09-28 Dorje C. Brody