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The internal photoeffect in polythiopentacene (PTP) films is investigated. It is discovered that, in capacitor cells, the spectral dependence of the frontal photo-emf Vf correlates with the PTP absorption spectrum, while that of the back…

Materials Science · Physics 2015-03-23 M. P. Gorishnyi

Optical absorption spectra of poly(thiophene vinylene) (PTV) conjugated polymers have been studied at room temperature in the spectral range of 450 to 800 nm. A dominant peak located at 577 nm and a prominent shoulder at 619 nm are…

Chemical Physics · Physics 2008-02-06 A. V. Gavrilenko , T. D. Matos , C. E. Bonner , S. -S. Sun , C. Zhang , V. I. Gavrilenko

We present optical absorption spectra of mixed films of pentacene (PEN) and perfluoropentacene (PFP) grown on SiO2. We investigated the influence of intermolecular coupling between PEN and PFP on the optical spectra by analyzing samples…

Materials Science · Physics 2011-06-22 K. Broch , U. Heinemeyer , A. Hinderhofer , F. Anger , R. Scholz , A. Gerlach , F. Schreiber

The influence of solubilizing substitutional groups on the electronic and optical properties of functionalized pentacene molecules and crystals have been investigated. Density functional theory is used to calculate the electronic and…

Materials Science · Physics 2013-11-15 Y. Saeed , K. Zhao , N. Singh , R. Li , J. E. Anthony , A. Amassian , U. Schwingenschlögl

Heterostructures composed of pentacene (PEN) molecules and transition metal dichalchogenides (TMDs) are promising materials for small, flexible and lightweight photovoltaic devices and various other optoelectronic applications. The effects…

Materials Science · Physics 2023-12-21 Edward Black , Juliana Morbec

Diketopyrrolopyrroles are a popular class of electron-withdrawing unit in optoelectronic materials. When combined with electron donating side-chain functional groups such as thiophenes, they form a very broad class of donor-acceptor…

The optical properties of pentacene (PEN) and perfluoropentacene(PFP) thin films on various SiO2 substrates were studied using variable angle spectroscopic ellipsometry. Structural characterization was performed using X-ray reflectivity and…

The electronic structure of pentacene decorated with dipole groups (d-pentacene) and adsorbed onto a graphene substrate has been studied within the density functional theory. Three reference configurations have been considered, namely the…

Materials Science · Physics 2017-01-02 M. Wawrzyniak-Adamczewska , M. Wierzbowska , J. J. Melendez

We report detailed temperature dependent photoluminescence (PL) spectra of pentacene (PEN), perfluoropentacene (PFP), and PEN:PFP mixed thin films grown on SiO2. PEN and PFP are particularly suitable for this study, since they are…

Materials Science · Physics 2012-01-20 F. Anger , J. O. Ossó , U. Heinemeyer , K. Broch , R. Scholz , A. Gerlach , F. Schreiber

Here we present a structural study of pentacene (Pn) thin films on vicinal Ag(111) surfaces by He atom diffraction measurements and density functional theory (DFT) calculations supplemented with van der Waals (vdW) interactions. Our He atom…

Strongly Correlated Electrons · Physics 2012-11-19 E. Mete , I. Demiroglu , E. Albayrak , G. Bracco , S. Ellialtioglu , M. F. Danisman

The great majority of electronic and optoelectronic devices depends on interfaces between n-type and p-type semiconductors. Finding such matching donor-acceptor systems in molecular crystals remains a challenging endeavor. Structurally…

We present a comparative study of ultrafast photo-conversion dynamics in tetracene (Tc) and pentacene (Pc) single crystals and Pc films using optical pump-probe spectroscopy. Photo-induced absorption in Tc and Pc crystals is activated and…

Using first-principles calculations based on density-functional theory, we investigated the adsorption of pentacene molecules on monolayer two-dimensional transition metal dichalcogenides (TMD). We considered the four most popular TMDs,…

Materials Science · Physics 2023-11-13 E. Black , P. Kratzer , J. M. Morbec

The broad use of organic semiconductors for optoelectronic applications relies on quantitative understanding and control of their spectroscopic properties. Of paramount importance are the transport gap - the difference between ionization…

Materials Science · Physics 2012-10-10 Sahar Sharifzadeh , Ariel Biller , Leeor Kronik , Jeffrey B. Neaton

We theoretically and experimentally investigate the optical absorption properties of heterostructures composed of graphene films and truncated photonic crystals (PCs) in the visible range. The experimental results show that the absorption…

Optics · Physics 2016-03-01 Yiping Liu , Lei Du , Yunyun Dai , Yuyu Xia , Guiqiang Du , Guang Lu , Fen Liu , Lei Shi , Jian Zi

The magnetic field dependence of photoabsorption provides direct insights into the band structure of semiconductors. It is perhaps surprising that there is a large discrepancy between electron, hole, and reduced mass reported in the recent…

Mesoscale and Nanoscale Physics · Physics 2025-01-22 Jack N. Engdahl , Harley D. Scammell , Dmitry K. Efimkin , Oleg P. Sushkov

The electronic structure of ZnPc, from sub-monolayers to thick films, on bare and iodated Pt(111) is studied by means of X-ray photoelectron spectroscopy (XPS), X-ray absorption spectroscopy (XAS) and scanning tunneling microscopy (STM).…

Materials Science · Physics 2014-05-01 S. Ahmadi , B. Agnarsson , I. Bidermane , B. M. Wojek , Q. Noël , C. H. Sun , M. Göthelid

Field-effect transistors coupled to integrated antennas (TeraFETs) are photodetectors being actively developed for the THz frequency range ($\sim$ 100 GHz - 10 THz). Among them, Graphene TeraFETs (G-TeraFETs) have demonstrated distinctive…

Mesoscale and Nanoscale Physics · Physics 2024-03-29 Florian Ludwig , Andrey Generalov , Jakob Holstein , Anton Murros , Klaara Viisanen , Mika Prunnila , Hartmut G. Roskos

Recent synthetic studies on the organic molecules tetracene and pentacene have found certain dimers and oligomers to exhibit an intense absorption in the visible region of the spectrum which is not present in the monomer or many…

Van der Waals heterojunctions between two-dimensional (2D) layered materials and nanomaterials of different dimensions present unique opportunities for gate-tunable optoelectronic devices. Mixed dimensional p-n heterojunction diodes, such…

Mesoscale and Nanoscale Physics · Physics 2017-03-09 Stephanie Bettis Homan , Vinod K. Sangwan , Itamar Balla , Hadallia Bergeron , Emily A. Weiss , Mark C. Hersam
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