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In the quest of understanding significant variations in the physical, chemical and electronic properties of the novel functional materials, low temperature Synchrotron X-ray Diffraction (LT-SXRD) measurements on CTO (a type-II) and CMTO (a…

Materials Science · Physics 2016-08-09 Harishchandra Singh , A. K. Sinha , M. N. Singh , A. Upadhyay , Archna Sagdeo

We use a symmetry-motivated approach to analysing X-ray pair distribution functions to study the mechanism of negative thermal expansion in two ReO$_3$-like compounds; ScF$_3$ and CaZrF$_6$. Both average and local structure suggest that it…

Materials Science · Physics 2020-02-26 Tobias Bird , Jessica Woodland-Scott , Lei Hu , Michael Wharmby , Jun Chen , Andrew Goodwin , Mark Senn

The influence of zinc ions on the thermochromic properties of polycrystalline Cu$_{1-x}$Zn$_x$MoO$_4$ ($x$=0.10, 0.50, 0.90) solid solutions was studied by X-ray absorption spectroscopy at the Cu, Zn and Mo K-edges. Detailed structural…

Materials Science · Physics 2021-07-07 Inga Pudza , Andris Anspoks , Arturs Cintins , Aleksandr Kalinko , Edmund Welter , Alexei Kuzmin

We studied the crystal and magnetic structure of the La$_{1-x}$Ca$_{x}$MnO$_{3}$ compound for $x=0.8$ and $x=0.85$. At T=300 K both samples are paramagnetic with crystallographic symmetry $Pnma$. At low temperatures they undergo a…

Strongly Correlated Electrons · Physics 2016-08-16 M. Pissas , G. Kallias , M. Hofmann , D. M. Többens

We have studied the electronic structure of the diluted magnetic semiconductor Ga$_{1-x}$Mn$_{x}$N ($x$ = 0.0, 0.02 and 0.042) grown on Sn-doped $n$-type GaN using photoemission and soft x-ray absorption spectroscopy. Mn $L$-edge x-ray…

An earlier analysis of manganese oxides in various charge states indicated that free-atom term values and universal coupling gave a reasonable account of the cohesion. This approach is here extended to LaxSr(1-x)MnO3 in a perovskite…

Materials Science · Physics 2008-07-17 Walter A. Harrison

Materials with magnetoelectric coupling (MEC) between ferroic orders at room temperature are emerging field in modern technology and physics. BaTiO3 is a robust ferroelectric in which several doping has led to MEC. In Ca and Mn modified…

Structure, transport and magnetic properties have been investigated for layered NaCo1-xMnxO2 materials. With the increase of Mn-doping amount, measurements of x-ray diffraction indicate that the in-plane lattice parameter a decreases…

Strongly Correlated Electrons · Physics 2007-05-23 W. Y. Zhang , H. C. Yu , Y. G. Zhao , X. P. Zhang , Y. G. Shi , Z. H. Cheng , J. Q. Li

The crystalline structures of superionic high temperature copper selenides Cu$_{2-x}$Se ($0 \le x \le 0.25$) produced by Mechanical Alloying were investigated using X-ray diffraction (XRD) technique. The measured XRD patterns showed the…

A laboratory hard X-ray photoelectron spectroscopy (HXPS) system equipped with a monochromatic Cr K$\alpha$ ($h\nu = 5414.7$ eV) X-ray source was applied to an investigation of the core-level electronic structure of La$_{1-x}$Sr$_x$MnO$_3$.…

We use x-ray absorption spectroscopy to investigate the local structure and electronic properties of bulk La$_{1-y}$Sr$_{y}$Co$_{1-x}$Nb$_x$O$_3$ ($y=$ 2$x$ as LSCNO and $y=$ 0 as LCNO) samples. The x-ray absorption near-edge spectra…

Materials Science · Physics 2021-04-23 Rishabh Shukla , Ajay Kumar , Ravi Kumar , S. N. Jha , R. S. Dhaka

We have investigated 3d electronic states of doped transition metals in II-VI diluted magnetic semiconductors, Zn1-xMxSe (M = Mn, Fe, Co) and Zn1-xMnxY (Y = Se, Te), using the transition-metal L2,3-edge X-ray absorption spectroscopy (XAS)…

Strongly Correlated Electrons · Physics 2009-10-31 Kwanghyun Cho , Hoon Koh , S. -J. Oh , Hyeong-Do Kim , Moonsup Han , J. -H. Park , C. T. Chen , Y. D. Kim , J. -S. Kim , B. T. Jonker

Density functional theory (DFT) calculations are used to study the magnetic and ferroelectric properties of Sr$_{1-x}$Ba$_{x}$MnO$_3$, with focus on $x=0.5$, under isotropic volume expansion/compression and biaxial strain. Our results…

Materials Science · Physics 2020-11-11 Alexander Edström , Claude Ederer

The Mn L_2,L_3 x-ray spectra of the Cu_2MnAl and Co_2MnZ (Z=Al,Ga, Sn, Sb) Heusler alloys have been investigated by the Resonant X-ray Emission Spectroscopy (RXES) using linearly polarized monochromatic synchrotron radiation for. The…

Strongly Correlated Electrons · Physics 2007-05-23 M. V. Yablonskikh , Yu. M. Yarmoshenko , I. V. Solovyev , L. Gridneva , T. Schmitt , M. Magnuson , L. -C. Duda , E. Z. Kurmaev , J. Nordgren

The crystal and magnetic structure of polycrystalline $La{}_{0.5-x}Nd{}_{x}Ca_{0.5}MnO{}_{3}$ (0.0 \ensuremath{\le} x \ensuremath{\le} 0.5) samples have been investigated using magnetization, resistivity, transmission electron microscope,…

Materials Science · Physics 2010-11-01 Indu Dhiman , A. Das , P. K. Mishra , N. P. Lalla , A. Kumar

The effects of the cooperative Jahn-Teller effect on the crystal structure and the stability of the charge ordered (CO) state were studied by measurements of powder X-ray diffraction, resistivity, and ultrasound for Pr1-xCaxMnO3…

Strongly Correlated Electrons · Physics 2009-11-10 R. K. Zheng , G. Li , Y. Yang , A. N. Tang , W. Wang , T. Qian , X. G. Li

Synchrotron x-ray scattering measurements of the low-temperature structure of the single-layer manganese oxide La$_{1-x}$Sr$_{1+x}$MnO$_4$, over the doping range $0.33 \le x \le 0.67$, indicate the existence of three distinct regions: a…

Strongly Correlated Electrons · Physics 2009-11-07 S. Larochelle , A. Mehta , N. Kaneko , P. K. Mang , A. F. Panchula , L. Zhou , J. Arthur , M. Greven

TM-doped IrTe2(TM=Mn, Fe, Co, Ni) compounds were synthesized by solid state reaction. Single crystal x-ray diffraction experiments indicate that part of the doped TM ions (TM=Fe, Co, and Ni) substitute for Ir, and the rest intercalate into…

Superconductivity · Physics 2013-10-18 J. -Q. Yan , B. Saparov , A. S. Sefat , H. Yang , H. B. Cao , H. D. Zhou , B. C. Sales , D. G. Mandrus

Films of cerium-doped LaMnO$_3$, which has been intensively discussed as an electron-doped counterpart to hole-doped mixed-valence lanthanum manganites during the past decade, were analyzed by x-ray photoemission spectroscopy with respect…

The effects of Cu-doping on the structural, magnetic, and transport properties of La0.7Sr0.3Mn1-xCuxO3 (0 < x < 0.20) have been studied using neutron diffraction, magnetization and magnetoresistance (MR) measurements. All samples show the…

Materials Science · Physics 2009-11-11 M. S. Kim , J. B. Yang , Q. Cai , X. D. Zhou , W. J. James , W. B. Yelon , P. E. Parris , D. Buddhikot , S. K. Malik