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An investigation of the mechanical, electronic, and optical properties of the recently reported material K4 phosphorus was made in this work. The K4 phosphorus has been proved to be mechanically and dynamically stable up to 7 GPa under…

Materials Science · Physics 2017-11-06 Qun Wei , Chenyang Zhao , Meiguang Zhang , Haiyan Yan , Quan Zhang , Yingjiao Zhou , Xuanmin Zhu

We present a first-principles approach to compute the transport properties of 2D materials in an accurate and automated framework. We use density-functional perturbation theory in the appropriate bidimensional setup with open-boundary…

Materials Science · Physics 2018-12-05 Thibault Sohier , Davide Campi , Nicola Marzari , Marco Gibertini

Phosphorene is a two-dimensional (2D) material exhibiting strong in-plane structural anisotropy. In this work, we investigate the influence of structural anisotropy on the optics, dynamics, and transport of excitons in phosphorene by…

Mesoscale and Nanoscale Physics · Physics 2025-09-04 Kai-Wei Chang , Joshua J. P. Thompson , Bartomeu Monserrat

Strain is prominent in fabricated samples of two-dimensional semiconductors and it also serves as an exploitable tool for engineering their properties. However, quantifying strain and characterizing its spatially inhomogeneous distribution…

Materials Science · Physics 2014-09-01 Ruixiang Fei , Li Yang

Two-dimensional (2D) metal-organic frameworks (MOFs) hold immense potential for various applications due to their distinctive intrinsic properties compared to their 3D analogues. Herein, we designed in silico a highly stable…

Materials Science · Physics 2023-07-31 Dong Fan , Aydin Ozcan , Pengbo Lyu , Guillaume Maurin

Black phosphorus has been revisited recently as a new two-dimensional material showing potential applications in electronics and optoelectronics. Here we report the anisotropic in-plane thermal conductivity of suspended few-layer black…

Mesoscale and Nanoscale Physics · Physics 2015-10-20 Zhe Luo , Jesse Maassen , Yexin Deng , Yuchen Du , Richard P. Garrelts , Mark S. Lundstrom , Peide D. Ye , Xianfan Xu

When a two-dimensional material, adhered onto a compliant substrate, is subjected to compression it can undertake a buckling instability yielding to a periodic rippling. Interestingly, when black phosphorus flakes are compressed along the…

Applied Physics · Physics 2019-07-18 Luis Vaquero-Garzon , Riccardo Frisenda , Andres Castellanos-Gomez

We report the influence of uniaxial tensile mechanical strain in the range 0-2.2% on the phonon spectra and bandstructures of monolayer and bilayer molybdenum disulfide (MoS2) two-dimensional crystals. First, we employ Raman spectroscopy to…

Mesoscale and Nanoscale Physics · Physics 2013-09-23 Hiram J. Conley , Bin Wang , Jed I. Ziegler , Richard F. Haglund , Sokrates T. Pantelides , Kirill I. Bolotin

A multi-scale approach for the theoretical description of deformed phosphorene is presented. This approach combines a valence-force model to relate macroscopic strain to microscopic displacements of atoms and a tight-binding model with…

Mesoscale and Nanoscale Physics · Physics 2022-02-25 Daniel Midtvedt , Caio H. Lewenkopf , Alexander Croy

Building two-dimensional (2D) van der Waals (vdW) heterostructures and enhancing their properties through strain engineering unlocks new applications for their constituent materials. In this study, we present a comprehensive…

Materials Science · Physics 2024-10-23 Sarga P K , Karthik H J , Swastibrata Bhattacharyya

Two dimensional (2D) materials such as graphene and transition metal dichalcogenides (TMDC) have received extensive research interests and investigations in the past decade. In this research, we report the first experimental measurement of…

Materials Science · Physics 2024-12-10 Jun Liu , Mengqi Fang , Eui-Hyeok Yang , Xian Zhang

Ab initio density functional theory has been used to analyze flexural modes, elastic constants, and atomic corrugations on single and bi-layer graphene. Frequencies of flexural modes are sensitive to compressive stress; its variation under…

Materials Science · Physics 2013-01-22 P. L. de Andres , F. Guinea , M. I. Katsnelson

In this work we develop a compact multi-orbital tight-binding model for phosphorene that accurately describes states near the main band gap. The model parameters are adjusted using as reference the band structure obtained by a…

Mesoscale and Nanoscale Physics · Physics 2016-10-26 Carlos J. Páez , Kursti DeLello , Duy Le , Ana L. C. Pereira , Eduardo R. Mucciolo

We study the mechanical and electronic properties of heterobilayers composed of black phosphorus (BP) on hexagonal boron nitride (hBN) and of blue phosphorus (\Pblue) on hBN by means of ab-intio density functional theory. Emphasis is put on…

Materials Science · Physics 2020-07-15 Baptiste Bienvenu , Hakim Amara , François Ducastelle , Lorenzo Sponza

It is shown here that fracture after a brief plastic strain, typically of a few percents, is a necessary consequence of the polycrystalline nature of the materials. The polycrystal undergoing plastic deformation is modeled as a flowing…

Materials Science · Physics 2018-08-28 Miguel Lagos , César Retamal , Rodrigo Valle

Phosphorene is a novel two-dimensional material that can be isolated through mechanical exfoliation from layered black phosphorus, but unlike graphene and silicene, monolayer phosphorene has a large band gap. It was thus unsuspected to…

Materials Science · Physics 2015-02-18 Qihang Liu , Xiuwen Zhang , L. B. Abdalla , A. Fazzio , Alex Zunger

Based on first-principles calculations, we study systematically the ideal tensile stress-strain relations of three monoatomic group-V monolayer two dimensional (2D) materials with buckled honeycomb lattices: blue phosphorene, arsenene, and…

Computational Physics · Physics 2019-05-02 Gang Liu , Zhibin Gao , Jian Zhou

There have been continuous efforts to seek for novel functional two-dimensional semiconductors with high performance for future applications in nanoelectronics and optoelectronics. In this work, we introduce a successful experimental…

Graphene is the extreme material for molecular sensory and hydrogen storage applications because of its two-dimensional geometry and unique structure-property relationship. In this Letter, hydrogenation of graphene is discussed in the…

Materials Science · Physics 2010-02-10 Zhiping Xu , Kun Xue

Graphyne is a porous two-dimensional carbon allotrope of graphene that possesses interesting physical properties, including non-null bandgap. It is composed of carbon hexagonal rings or carbon-carbon bonds connected by acetylenic chains.…

Materials Science · Physics 2025-01-20 Guilherme B. Kanegae , Alexandre F. Fonseca