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Transition-metal oxides with an ABO$_3$ perovskite structure exhibit strongly entangled structural and electronic degrees of freedom and thus, one expects to unveil exotic phases and properties by acting on the lattice through various…

High quality epitaxial thin-films of EuTiO3 have been grown on the (001) surface of SrTiO3 using pulsed laser deposition. In situ x-ray reflectivity measurements reveal that the growth is two-dimensional and enable real-time monitoring of…

Materials Science · Physics 2007-05-23 Huan-Hua Wang , Aaron Fleet , Darren Dale , Yuri Suzuki , J. D. Brock

Epitaxial strain in 4d ferromagnet SrRuO3 films is directly linked to the physical properties through the strong coupling between lattices, electrons, and spins. It provides an excellent opportunity to tune the functionalities of SrRuO3 in…

PbTiO$_3$ is a simple but very important ferroelectric oxide that has been extensively studied and widely used in various technological applications. However, most previous studies and applications were based on the bulk material or the…

Materials Science · Physics 2015-11-11 Huimin Zhang , Ming An , Xiaoyan Yao , Shuai Dong

Surface morphology of the substrate and bottom layers plays a critical role in the epitaxial growth of oxide thin films. Here, we report on the self-organized formation of a step-terrace structure in SrRuO3 (SRO) thin films grown using…

We have grown lead iron niobate thin films with composition Pb(Fe1/2Nb1/2)O3 (PFN) on (0 0 1) SrTiO3 substrates by pulsed laser deposition. The influence of the deposition conditions on the phase purity was studied. Due to similar…

Materials Science · Physics 2009-03-02 W. Peng , N. Lemée , J Holc , M. Kosec , R. Blinc , M. G. Karkut

A uniform one-unit-cell-high step on the SrTiO3 substrate is a prerequisite for growing high-quality epitaxial oxide heterostructures. However, it is inevitable that defects induced by mixed substrate surface termination exist at the…

We report on the synthesis of high quality La$_{1/3}$Sr$_{2/3}$FeO$_3$ (LSFO) thin films using the pulsed laser deposition technique on both SrTiO$_3$ (STO) and LaAlO$_3$ (LAO) substrates (100)-oriented. From X-Ray diffraction (XRD)…

Materials Science · Physics 2009-11-07 W. Prellier , B. Mercey

The structure and interface characteristics of (LaVO3)6m(SrVO3)m superlattices deposited on (100)-SrTiO3 (STO) substrate were studied using Transmission Electron Microscopy (TEM). Cross-section TEM studies revealed that both LaVO3 (LVO) and…

Materials Science · Physics 2015-05-20 P. Boullay , A. David , W. C. Sheets , U. Lüders , W. Prellier , H. Tan , J. Verbeeck , G. Van Tendeloo , C. Gatel , G. Vincze , Z. Radi

The structural evolution of epitaxial mono-oriented (i.e. with the c-axis perpendicular to the interface) ferroelectric Pb(Zr0.2,Ti0.8)O3 thin film has been investigated, using high resolution, temperature dependent, X-ray diffraction. The…

Materials Science · Physics 2009-11-13 Pierre-Eymeric Janolin , Bernard Fraisse , Francoise Le Marrec , Brahim Dkhil

Transition-metal oxides with an ABO$_3$ perovskite structure exhibit significant coupling between spin, orbital, and lattice degrees of freedom, highlighting the crucial role of lattice distortion in tuning the electronic and magnetic…

Materials Science · Physics 2025-02-26 M. Martirosyan , A. Gudima , J. Varignon , J. Ghanbaja , S. Migot , A. David , M. Guennou , O. Copie

High-quality YTiO3 thin films were grown on LaAlO3 (110) substrates at low oxygen pressures (<10-8 Torr) using pulsed laser deposition. The in-plane asymmetric atomic arrangements at the substrate surface allowed us to grow epitaxial YTiO3…

Materials Science · Physics 2009-11-11 S. C. Chae , Y. J. Chang , S. S. A. Seo , T. W. Noh , D. -W. Kim , C. U. Jung

Strong spin-orbit coupled 5d transition metal based ABO3 oxides, especially iridates, allow tuning parameters in the phase diagram and may demonstrate important functionalities, for example, by means of strain effects and symmetry-breaking,…

Strongly Correlated Electrons · Physics 2015-05-22 Abhijit Biswas , Yoon Hee Jeong

Obtaining high-quality thin films of 5d transition metal oxides is essential to explore the exotic semimetallic and topological phases predicted to arise from the combination of strong electron correlations and spin-orbit coupling. Here, we…

Strongly Correlated Electrons · Physics 2016-08-08 D. J. Groenendijk , N. Manca , G. Mattoni , L. Kootstra , S. Gariglio , Y. Huang , E. van Heumen , A. D. Caviglia

Comparison between single- and the poly-crystalline structures provides essential information on the role of long-range translational symmetry and grain boundaries. In particular, by comparing single- and poly-crystalline transition metal…

High entropy oxides (HEOs) are a class of materials, containing equimolar portions of five or more transition metal and/or rare-earth elements. We report here about the layer-by-layer growth of HEO…

Strongly Correlated Electrons · Physics 2020-02-24 Ranjan Kumar Patel , Shashank Kumar Ojha , Siddharth Kumar , Akash Saha , Prithwijit Mandal , J. W. Freeland , S. Middey

SrVO3 and SrNbO3 are perovskite-type transition-metal oxides with the same d1 electronic configuration. Although SrNbO3 (4d1) has a larger d orbital than SrVO3 (3d1), the reported electrical resistivity of SrNbO3 is much higher than that of…

Materials Science · Physics 2015-12-14 Daichi Oka , Yasushi Hirose , Shoichiro Nakao , Tomoteru Fukumura , Tetsuya Hasegawa

A structural transition in an ABO$_{3}$ perovskite thin film involving the change of the BO$_{6}$ octahedral rotation pattern can be hidden under the global lattice symmetry imposed by the substrate and often easily overlooked. We carried…

Strongly Correlated Electrons · Physics 2019-11-04 W. T. Jin , H. Gretarsson , S. Y. Jang , Chang-Yong Kim , T. W. Noh , Young-june Kim

Using an extension of a first-principles method developed by King-Smith and Vanderbilt [Phys. Rev. B {\bf 49}, 5828 (1994)], we investigate the effects of in-plane epitaxial strain on the ground-state structure and polarization of eight…

Materials Science · Physics 2009-12-22 Oswaldo Dieguez , Karin M. Rabe , David Vanderbilt

The properties of single-crystal SrTiO$_{3}$ substrates and homoepitaxial SrTiO$_{3}$ films grown by pulsed laser deposition have been compared, in order to understand the loss of interfacial conductivity when more than a critical thickness…