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This article reviews the new developments in Tip-enhanced Raman scattering (TERS). The fundamental mechanisms underlying the Raman enhancement are discussed, including the role of the plasmonic character of the metallic tips, the nature of…

Chemical Physics · Physics 2008-04-01 Catalin C. Neacsu , Samuel Berweger , Markus B. Raschke

Using the electrostatic approximation, we analyze electromagnetic fields scattered by sharp conical metal tips, which are illuminated with light polarized along the tip axis. We establish scaling relations for the scattered field amplitude…

We present a detailed calculation of intensities of two-phonon and four-phonon Raman peaks in graphene. Writing the low-energy hamiltonian of the interaction of electrons with the crystal vibrations and the electromagnetic field from pure…

Materials Science · Physics 2009-11-13 D. M. Basko

Raman scattering on phonon--plasmon coupled modes in high magnetic fields is considered theoretically. The calculations of the dielectric function were performed in the long-wave approximation for the semiclassical and ultra-quantum…

Materials Science · Physics 2007-05-23 L. A. Falkovsky

We review the different results obtained in the last decade in the field of Raman scattering of graphene based systems, with an applied magnetic field. Electronic properties of graphene based systems with an applied magnetic field will…

Mesoscale and Nanoscale Physics · Physics 2018-02-14 C. Faugeras , M. Orlita , M. Potemski

In this work we study the behavior of the optical phonon modes in bilayer graphene devices by applying top gate voltage, using Raman scattering. We observe the splitting of the Raman G band as we tune the Fermi level of the sample, which is…

Mesoscale and Nanoscale Physics · Physics 2012-06-07 D. L. Mafra , P. Gava , L. M. Malard , R. S. Borges , G. G. Silva , J. A. Leon , F. Plentz , F. Mauri , M. A. Pimenta

The scattering of lattice excitations (phonons) with the photoexcited charge carriers is of a major concern in optoelectronic devices. Here, the resonant Raman scattering will be utilized to study an exciton-phonon interaction in GaN…

We develop a theoretical framework for probing moir\'e phonon modes using Raman spectroscopy, and illustrate it with the example of twisted bilayer graphene (TBG). These moir\'e phonons arise from interlayer sliding motion in twisted 2D…

Strongly Correlated Electrons · Physics 2025-06-24 Vitor Dantas , Héctor Ochoa , Rafael M. Fernandes , Natalia B. Perkins

In spite of their importance for understanding phonon transport phenomena in thin films and polycrystalline solids, the effects of boundary roughness scattering on phonon specularity and coherence are poorly understood because there is no…

Mesoscale and Nanoscale Physics · Physics 2020-05-08 Zhun-Yong Ong , Georg Schusteritsch , Chris J. Pickard

We present a systematic experimental and theoretical study of the two-phonon (2D) Raman scattering in graphene under uniaxial tension. The external perturbation unveils that the 2D mode excited with 785nm has a complex line-shape mainly due…

We theoretically investigate multiphonons resonance Raman scattering between the Landau levels in graphene on the polar substrate using the Huang-Rhys's model. We not only present the single and multiple surface optical (SO) phonons…

Mesoscale and Nanoscale Physics · Physics 2017-12-01 Zi-Wu Wang , Zhi-Qing Li

We present a computational study of the two-phonon Raman spectra of silicene and graphene within a density-functional non-orthogonal tight-binding model. Due to the presence of linear bands close to the Fermi energy in the electronic…

Mesoscale and Nanoscale Physics · Physics 2016-04-29 Valentin N. Popov , Philippe Lambin

The symmetry group analysis is applied to classify the phonon modes of $N$-stacked graphene layers (NSGL's) with AB- and AA-stacking, particularly their infra-red and Raman properties. The dispersions of various phonon modes are calculated…

Materials Science · Physics 2008-06-30 Jin-Wu Jiang , Hui Tang , Bing-Shen Wang , Zhao-Bin Su

This paper addresses recent experimental findings about luminescence of a gold tip in near-field interaction with a gold surface. Our electrochemically etched gold tips show a typical, intrinsic luminescence that we exploit to track the…

Materials Science · Physics 2016-01-05 A. Merlen , J. Plathier , A. Ruediger

We study Raman scattering in active media placed in proximity of different types of metal nanostructures, at wavelengths that display either Fabry-Perot or plasmonic resonances, or a combination of both. We use a semi-classical approach to…

Optics · Physics 2015-06-05 M. Scalora , M. A. Vincenti , D. de Ceglia , M. Grande , J. W. Haus

The experimental Raman spectra of graphene exhibit a few intense two-phonon bands, which are enhanced through double-resonant scattering processes. Though there are many theoretical papers on this topic, none of them predicts the spectra…

Mesoscale and Nanoscale Physics · Physics 2014-12-17 Valentin N. Popov , Philippe Lambin

Tip-Enhanced Raman Spectroscopy (TERS) can be used to make nanoscale spatial measurements of 2D materials, such as graphene and transition metal dichalcogenides (TMDs). The TERS theory introduced in [Phys. Rev. X 4, 031054 (2014)], however,…

Optics · Physics 2026-05-12 Raul Corrêa , Luiz G. Cançado , Ado Jorio

We report a detailed study of the strong near-field Raman scattering enhancement which takes place in tip-enhanced Raman scattering (TERS) in indium nitride. In addition to the well-known first-order optical phonons of indium nitride,…

We investigate the far-field optical resonances of individual dimer nanoantennas using confocal scattering spectroscopy. Experiments on a single-antenna array with varying arm lengths and interparticle gap sizes show large spectral shifts…

Materials Science · Physics 2009-11-11 O. L. Muskens , J. Gomez Rivas , V. Giannini , J. A. Sanchez-Gil

We theoretically investigate the double-resonance Raman spectrum of monolayer graphene down to infrared laser excitation energies. By using first-principles density functional theory calculations, we improve upon previous theoretical…

Mesoscale and Nanoscale Physics · Physics 2025-05-21 Lorenzo Graziotto , Francesco Macheda , Thibault Sohier , Matteo Calandra , Francesco Mauri
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