Related papers: H2+ and HD+: candidates for a molecular clock
Highly charged ions of heavy actinides from uranium to einsteinium are studied theoretically to find optical transitions sensitive to the variation of the fine structure constant. A number of promising transitions have been found in ions…
Singly-ionized ytterbium, with ultra-narrow optical clock transitions at 467 nm and 436 nm, is a convenient system for the realization of optical atomic clocks and tests of present-day variation of fundamental constants. We present the…
Collisions between background gas particles and the trapped ion in an atomic clock can subtly shift the frequency of the clock transition. The uncertainty in the correction for this effect makes a significant contribution to the total…
Molecular hydrogen transitions in quasar spectra can be used to constrain variation in the proton-to-electron mass ratio, $\mu\equiv m_p/m_e$, at high redshifts ($z\gtrsim 2$). We present here an analysis of a new spectrum of the quasar…
We estimate the nuclear polarizability correction to atomic transition frequencies in various helium isotopes. This effect is non-negligible for high precision tests of quantum electrodynamics or accurate determination of the nuclear charge…
We experimentally investigate an optical frequency standard based on the 467 nm (642 THz) electric-octupole reference transition 2S1/2(F=0) -> F7/2(F=3) in a single trapped 171Yb+ ion. The extraordinary features of this transition result…
Spectroscopy of hydrogen can be used for a search into physics beyond the Standard Model. Differences between the absorption spectra of H$_2$ as observed at high redshift and those measured in the laboratory can be interpreted in terms of…
The recently reported precise experimental determination of the dipole polarizability of the H_2^+ molecular ion ground state [P.L. Jacobson, R.A. Komara, W.G. Sturrus, and S.R. Lundeen, Phys. Rev. A 62, 012509 (2000)] reveals a discrepancy…
The potential-energy and quadrupole-moment functions of the H$_2$ ground electronic state are well known in literature (Komasa et al., 2019; Wolniewicz et al., 1998), and the line list of the vibrational-rotational transitions was…
We perform calculations of the dependence of nuclear magnetic moments on quark masses and obtain limits on the variation of $(m_q/\Lambda_{QCD})$ from recent measurements of hydrogen hyperfine (21 cm) and molecular rotational transitions in…
We improve by a factor of 4-20 the energy accuracy of the strongest soft X-ray transitions of Fe XVII ions by resonantly exciting them in an electron beam ion trap with a monochromatic beam at the P04 beamline of the PETRA III synchrotron…
We report observations of the reactive molecular ions OH$^+$, H$_2$O$^+$, and H$_3$O$^+$ towards Orion KL with Herschel/HIFI. All three $N=1-0$ fine-structure transitions of OH$^+$ at 909, 971, and 1033GHz and both fine-structure components…
The frequency comb created by a femtosecond mode-locked laser and a microstructured fiber is used to phase coherently measure the frequencies of both the Hg^+ and Ca optical standards with respect to the SI second as realized at NIST. We…
Recent observation of several microwave transitions in H2O2 from the interstellar medium [Astron. Astrophys., 531, L8 (2011)] raised interest to this molecule as yet another sensitive probe of the tentative variation of the…
Optical molecular clocks promise unparalleled sensitivity to the temporal variation of the electron-to-proton mass ratio and insight into possible new physics beyond the Standard Model. We propose to realize a molecular clock with bosonic…
There are few good direct laboratory tests of boost invariance for electrons, because the experiments required often involve repeated precision measurements performed at different times of year. However, existing measurements and…
A calculation of the blackbody radiation shift of the B$^+$ clock transition is performed. The polarizabilities of the B$^+$ $2s^2$ $^1$S$^e$, $2s2p$ $^1$P$^o$, and $2s2p$ $^3$P$^o$ states are computed using the configuration interaction…
The singly-ionized lutetium has a number of fortuitous properties well suited for a design of an optical clock and corresponding applications. In this work, we study Lu+ properties relevant to a development of the clock using the…
We report the first operation of a Ra$^{+}$ optical clock, a promising high-performance clock candidate. The clock uses a single trapped $^{226}$Ra$^{+}$ ion and operates on the $7s\ ^2S_{1/2}\rightarrow$ $6d\ ^2D_{5/2}$ electric quadrupole…
The proton, deuteron and triton masses can be determined relative to the electron mass via rovibrational spectroscopy of molecular hydrogen ions. This has to occur via comparison of the experimentally measured transition frequencies and the…