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Model Hamiltonians offer a cost-effective way to capture the key physics of large $\pi$-conjugated systems. In this work, we combine the Pariser--Parr--Pople (PPP) model Hamiltonian with pair Coupled Cluster Doubles (pCCD)-based methods to…

Chemical Physics · Physics 2025-08-27 Zahra Karimi , Somayeh Ahmadkhani , Katharina Boguslawski , Paweł Tecmer

The recently introduced coupled cluster (CC) downfolding techniques for reducing the dimensionality of quantum many-body problems recast the CC formalism in the form of the renormalization procedure allowing, for the construction of…

Quantum Physics · Physics 2021-11-08 Nicholas P. Bauman , Karol Kowalski

The pairing Hamiltonian constitutes an important approximation in many- body systems, it is exactly soluble and quantum integrable. On the other hand, the continuum single particle level density (CSPLD) contains information about the…

Nuclear Theory · Physics 2012-04-13 R. Id Betan

Studies of pairing correlations in ultrasmall metallic grains have commonly been based on a simple reduced BCS-model describing the scattering of pairs of electrons between discrete energy levels that come in time-reversed pairs. This model…

Strongly Correlated Electrons · Physics 2007-05-23 Jan von Delft , Fabian Braun

The use of exactly-solvable Richardson-Gaudin (R-G) models to describe the physics of systems with strong pair correlations is reviewed. We begin with a brief discussion of Richardson's early work, which demonstrated the exact solvability…

Nuclear Theory · Physics 2008-11-26 J. Dukelsky , S. Pittel , G. Sierra

An efficiency of the Tucker decomposition of amplitude tensors within the single-reference relativistic coupled cluster method with single and double excitations (RCCSD) was studied in a series of benchmark calculations for (AuCl)$_n$…

Computational Physics · Physics 2025-07-29 Alexander V. Oleynichenko , Artem S. Rumiantsev , Andrei Zaitsevskii , Ephraim Eliav

Coupled cluster theory is an attractive tool to solve the quantum many-body problem because its singles and doubles (CCSD) approximation is computationally affordable and yields about 90% of the correlation energy. Capturing the remaining…

Nuclear Theory · Physics 2024-02-16 Z. H. Sun , C. A. Bell , G. Hagen , T. Papenbrock

Electrons in a multielectron bubble in helium form a spherical, two-dimensional system coupled to the ripplons at the bubble surface. The electron-ripplon coupling, known to lead to polaronic effects, is shown to give rise also to Cooper…

Superconductivity · Physics 2007-05-23 J. Tempere , V. N. Gladilin , I. F. Silvera , J. T. Devreese

The coupled cluster method (CCM) is a method of quantum many-body theory that may provide accurate results for the ground-state properties of lattice quantum spin systems even in the presence of strong frustration and for lattices of…

Strongly Correlated Electrons · Physics 2009-11-11 D. J. J. Farnell , J. Schulenburg , J. Richter , K. A. Gernoth

The analytic gradient theory for both iterative and non-iterative coupled-cluster approximations that include connected quadruple excitations is presented. These methods include, in particular, CCSDT(Q), which is an analog of the well-known…

Chemical Physics · Physics 2025-03-26 Devin A. Matthews

The two electrons of a Cooper pair in a conventional superconductor form a singlet and therefore a maximally entangled state. Recently, it was demonstrated that the two particles can be extracted from the superconductor into two spatially…

Mesoscale and Nanoscale Physics · Physics 2012-10-10 J. Schindele , A. Baumgartner , C. Schönenberger

Different steps leading to the new functional for pairing based on natural orbitals and occupancies proposed in ref. [D. Lacroix and G. Hupin, arXiv:1003.2860] are carefully analyzed. Properties of quasi-particle states projected onto good…

Nuclear Theory · Physics 2011-03-22 Guillaume Hupin , Denis Lacroix

The (T) and [T] perturbative corrections are derived for multicomponent coupled-cluster theory with single and double excitations (CCSD). Benchmarking shows that multicomponent CCSD methods that include the perturbative corrections are more…

Chemical Physics · Physics 2022-07-01 Dylan Fowler , Kurt R. Brorsen

A novel implementation of the coupled-cluster singles and doubles (CCSD) approach is presented that is specifically tailored for the treatment of large, symmetric systems. It fully exploits Abelian point-group symmetry and the use of the…

Chemical Physics · Physics 2023-12-07 Tommaso Nottoli , Jürgen Gauss , Filippo Lipparini

We analyze the accuracy of BCS-based approximations for calculating correlation energies and odd-even energy differences in 2-component fermionic systems with a small number of pairs. The analysis is focused on comparing BCS and projected…

Nuclear Theory · Physics 2009-01-16 N. Sandulescu , G. F. Bertsch

We use the variational cluster approximation to study the superconducting ground state in the two-dimensional attractive Hubbard model, putting particular emphasis on the significance of quantum fluctuations of the system. We first show…

Strongly Correlated Electrons · Physics 2014-01-22 Tatsuya Kaneko , Yukinori Ohta

The established approach of perturbative continuous unitary transformations (pCUTs) constructs effective quantum many-body Hamiltonians as perturbative series that conserve the number of one quasiparticle type. We extend the pCUT method to…

Strongly Correlated Electrons · Physics 2023-10-05 L. Lenke , A. Schellenberger , K. P. Schmidt

We propose an approach to approximately implement the variational coupled cluster (VCC) theory on quantum computers, which struggles with exponential scaling of computational costs on classical computers. To this end, we employ expanding…

Quantum Physics · Physics 2024-06-12 Luca Erhart , Yuichiro Yoshida , Viktor Khinevich , Wataru Mizukami

We derive coupled-cluster equations for three-body Hamiltonians. The equations for the one- and two-body cluster amplitudes are presented in a factorized form that leads to an efficient numerical implementation. We employ low-momentum two-…

Nuclear Theory · Physics 2008-11-26 G. Hagen , T. Papenbrock , D. J. Dean , A. Schwenk , A. Nogga , M. Wloch , P. Piecuch

For noncovalent interactions (NCIs), the CCSD(T) coupled cluster method is widely regarded as the `gold standard'. With localized orbital approximations, benchmarks for ever larger NCI complexes are being published; yet tantalizing evidence…

Chemical Physics · Physics 2025-03-13 Vladimir Fishman , Michał Lesiuk , Jan M. L. Martin , A. Daniel Boese
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