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Exploring the uncharacterized magnetic phases of Co$^{2+}$ chain compounds is critical for finding new low-dimensional magnets hosting quantized excitations. We map the unexplored magnetic phases of the Co$^{2+}$ chain compound…

Strongly Correlated Electrons · Physics 2023-10-18 Zachary W. Riedel , Zhihao Jiang , Maxim Avdeev , André Schleife , Daniel P. Shoemaker

Insulators containing chains of magnetic transition metal cations provide platforms for probing spin-$\frac{1}{2}$ dynamics and quantum critical behavior. Li$_2$CoCl$_4$ contains edge-sharing CoCl$_6$ octahedra that form chains along the…

Strongly Correlated Electrons · Physics 2025-09-08 Zachary W. Riedel , Mykhaylo Ozerov , Stuart Calder , Daniel P. Shoemaker

We investigate the existence of linear magnetism in the metal organic framework materials MOF-74-Fe, MOF-74-Co, and MOF-74-Ni, using first-principles density functional theory. MOF-74 displays regular quasi-linear chains of open-shell…

Materials Science · Physics 2013-03-08 Pieremanuele Canepa , Yves J. Chabal , T. Thonhauser

Single-crystal neutron diffraction has been used to determine the incommensurate magnetic structure of NaCu2O2, a compound built up of chains of edge-sharing CuO4 plaquettes. Magnetic structures compatible with the lattice symmetry were…

Strongly Correlated Electrons · Physics 2015-05-18 L. Capogna , M. Reehuis , A. Maljuk , R. K. Kremer , B. Ouladdiaf , M. Jansen , B. Keimer

We investigate the structural and magnetic properties of the new quantum magnet BaCuTe$_2$O$_6$. This compound is synthesized for the first time in powder and single crystal form. Synchrotron X-ray and neutron diffraction reveal a cubic…

Strongly Correlated Electrons · Physics 2021-03-17 A. Samartzis , D. Khalyavin , A. T. M. N. Islam , S. Chillal , K. Siemensmeyer , K. Prokes , D. J. Voneshen , A. Senyshyn , B. Lake

A detailed investigation of Ba$_2$MnGe$_2$O$_7$ was performed in its low-temperature magnetoelectric state combining neutron diffraction with magnetization measurements on single crystals. In the paramagnetic state at 10 K, polarized…

Strongly Correlated Electrons · Physics 2023-03-07 A. Sazonov , H. Thoma , R. Dutta , M. Meven , A. Gukasov , R. Fittipaldi , V. Granata , T. Masuda , B. Náfrádi , V. Hutanu

The magnetic properties of a novel cobalt-based hydrogen vanadate, Co13.5(OH)6(H0.5VO3.5)2(VO4)6, are reported. This new magnetic material was synthesized in single-crystal form using a conventional hydrothermal method. Its crystal…

The structural and magnetic properties of BaMn2Si2O7 have been investigated. The magnetic susceptibility and specific heat, measured using single crystals, suggest that the quasi-one-dimensional magnetism originating from the loosely…

Materials Science · Physics 2015-06-17 J. Ma , C. D. Dela Cruz , T. Hong , W. Tian , A. A. Aczel , Songxue Chi , J. -Q. Yan , Z. L. Dun , H. D. Zhou , M. Matsuda

CoSe$_2$O$_5$ has a crystal structure consisting of zig-zag chains of edge shared CoO$_6$ octahedra running along the c axis, with the chains separated by Se$_2$O$_5^{2-}$ units. Magnetic susceptibility measurements indicate a transition at…

Materials Science · Physics 2012-02-02 Brent C. Melot , Brian Paden , Ram Seshadri , Ambesh Dixit , Gavin Lawes , Emmanuelle Suard

The magnetic and chemical structure of metal/oxide interfaces were studied in cobalt/magnetite, $Fe_3O_4$, and cobalt/hematite, ${\alpha}-Fe_2O_3$, epitaxial heterostructures using the comprehensive selection of microscopic and…

Through analysis of single crystal neutron diffraction data, we present the magnetic structures of magnetoelectric Co4Nb2O9 under various magnetic fields. In zero-field, neutron diffraction experiments below TN=27 K reveal that the Co2+…

The magnetic and structural properties of polycrystalline Co$_{4-x}$ Ni$_x$ Nb$_2$ O$_9$ (x=1,2) have been investigated by neutron powder diffraction, magnetization and heat capacity measurements, and density functional theory (DFT)…

We have systematically studied the magnetic properties of Cu$_{4-x}$Zn$_x$(OH)$_6$FBr by the neutron diffraction and muon spin rotation and relaxation ($\mu$SR) techniques. Neutron-diffraction measurements suggest that the long-range…

Organic and molecule-based magnets are not easily attainable, because to introduce stable paramagnetic centers to pure organic systems is challenging. Crystalline covalent organic frameworks (COFs) with high designability and chemical…

Chemical Physics · Physics 2020-06-09 Hongde Yu , Dong Wang

Identifying and characterizing new magnetic systems with Co2+ ions can enhance our understanding of quantum behavior since Co2+ can host a pseudospin-1/2 magnetic ground state. Understanding the magnetic ground state and the phase diagrams…

A detailed analysis of the magnetic properties of a vanthoffite type mineral Na6Mn(SO4)4 basedon dc magnetization, low temperature neutron powder diffraction and theoretical calculations is reported. The mineral crystallizes in a monoclinic…

Low-dimensional quantum magnets are a versatile materials platform for studying the emergent many-body physics and collective excitations that can arise even in systems with only short-range interactions. Understanding their low-temperature…

Frustrated interactions in the Cu-based mineral rouaite with alternating antiferromagnetic and ferromagnetic spin chains, Cu$_2$(OH)$_3$NO$_3$, introduce non-trivial magnetic ground states and exotic excitations arising from them. We…

Results of magnetic field and temperature dependent neutron diffraction and magnetization measurements on oxy-arsenate Rb$_{2}$Fe$_{2}$O(AsO$_{4}$)$_{2}$ are reported. The crystal structure of this compound contains pseudo-one-dimensional…

Strongly Correlated Electrons · Physics 2015-06-18 V. O. Garlea , L. D. Sanjeewa , M. A. McGuire , P. Kumar , D. Sulejmanovic , J. He , S. -J Hwu

We present a detailed atomistic picture of the oxidation mechanism of Co nanoparticles and its impact on magnetism by experimentally following the evolution of the structure, chemical composition, and magnetism of individual, gas-phase…

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