Related papers: Landau-Zener type surface hopping algorithms
The Landau-Zener formula provides the probability of non-adiabatic transitions occuring when two energy levels are swept through an avoided crossing. The formula is derived here in a simple calculation that emphasizes the physics…
We consider nonadiabatic systems in which the classical Born-Oppenheimer approximation breaks down. We present a general theory that accurately captures the full transmitted wavepacket after multiple transitions through either a single or…
Surface hopping algorithms, as an important class of quantum dynamics simulation algorithms for non-adiabatic dynamics, are typically performed in the adiabatic representation, which can break down in the presence of ill-defined adiabatic…
The Landau--Zener (LZ) model describes a two-level quantum system that undergoes an avoided crossing. In the adiabatic limit, the transition probability vanishes. An auxiliary control field $H_\text{CD}$ can be reverse-engineered so that…
We study a two-level transition probability for a finite number of avoided crossings with a small interaction. Landau-Zener formula, which gives the transition probability for one avoided crossing as $e^{-\pi\frac{\varepsilon^{2}}{h}}$,…
The Landau--Zener (LZ) type classical-trajectory surface-hopping algorithm is applied to the nonadiabatic nuclear dynamics of the ammonia cation after photoionization of the ground-state neutral molecule to the excited states of the cation.…
Surface hopping algorithms are popular tools to study dynamics of the quantum-classical mixed systems. In this paper, we propose a surface hopping algorithm in diabatic representations, based on time dependent perturbation theory and…
This paper presents analytic formulas for various transition times in the Landau-Zener model. Considerable differences are found between the transition times in the diabatic and adiabatic bases, and between the jump time (the time for which…
Nonadiabatic molecular dynamics is a key technique for investigating a broad range of photochemical and photophysical processes. Among the established approaches, surface hopping schemes are widely used and can be easily integrated with…
We study the Landau-Zener Problem for a decaying two-level-system described by a non-hermitean Hamiltonian, depending analytically on time. Use of a super-adiabatic basis allows to calculate the non-adiabatic transition probability P in the…
Trajectory surface hopping (TSH) is one of the most widely used quantum-classical algorithms for nonadiabatic molecular dynamics. Despite its empirical effectiveness and popularity, a rigorous derivation of TSH as the classical limit of a…
The Landau-Zener formula describes the diabatic transition probability of a two-level system under linear driving. Its rigorous derivation typically relies on sophisticated mathematical tools, such as special functions, Laplace transforms,…
By the adiabatic theorem, the probability of non-adiabatic transitions in a time-dependent quantum system vanishes in the adiabatic limit. The Landau-Zener (LZ) formula gives the leading functional behavior of the probability close to this…
We examine the effect of nonlinearity at a level crossing on the probability for nonadiabatic transitions $P$. By using the Dykhne-Davis-Pechukas formula, we derive simple analytic estimates for $P$ for two types of nonlinear crossings. In…
A nonlinear Landau-Zener model was proposed recently to describe, among a number of applications, the nonadiabatic transition of a Bose-Einstein condensate between Bloch bands. Numerical analysis revealed a striking phenomenon that…
We investigate the Landau-Zener tunneling (LZT) of a self-interacting two-level system in which the coupling between the levels is nonreciprocal. In such a non-Hermitian system, when the energy bias between two levels is adjusted very…
We obtain the exact expression for the matrix of nonadiabatic transition probabilities in the model of three interacting states with a time-dependent Hamiltonian. Unlike other known solvable Landau-Zener-like problems, our solution is…
Three analytic solutions to the Schr\"{o}dinger equation for the time-dependent Landau-Zener Hamiltonian are presented. They correspond to specific finite-time driving paths in a bounded parameter space of a two-level system. Two of these…
Quantum computation by the adiabatic theorem requires a slowly varying Hamiltonian with respect to the spectral gap. We show that the Landau-Zener-St\"uckelberg oscillation phenomenon, that naturally occurs in quantum two level systems…
Non-adiabatic transitions are studied in a spin-boson model with multiple scattering points. In order to generalize the Landau-Zener formula, which describes the case of a single scattering point, we define an ``effective gap'' for a set of…