Related papers: 'Coffee-ring' patterns of polymer droplets: chain …
Phase separation in passive systems leads to uncontrolled droplet growth, limiting structural control in soft materials and cells. We identify a generic mechanism to arrest coarsening based on chemical interconversion between molecular…
We investigate by exact optimization the geometrical properties of three-dimensional elastic line systems with point disorder and hard-core repulsion. The line 'forests' become entangled due to increasing line wandering as the system height…
The spatial correlations of entangled polymer dynamics are examined by molecular dynamics simulations and neutron spin-echo spectroscopy. Due to the soft nature of topological constraints, the initial spatial decays of intermediate…
Drying a droplet of colloidal dispersion can result in complex pattern formation due to both development and deformation of a skin at the drop surface. The present study focus on the drying process of droplets of colloidal dispersions in a…
We study the initial evolution of the coffee ring that is formed by the evaporation of a thin, axisymmetric, surface tension-dominated droplet containing a dilute solute. When the solutal P\'{e}clet number is large, we show that diffusion…
Watercolor or aquarelle is one of the oldest painting methods in which pigments suspended in an aqueous liquid are deposited over a substrate, typically an absorbing material such as paper. The physical processes which lead to pattern…
The motion of a water droplet on a single vertical sugar fiber is analyzed. The fiber is positioned vertically, with the droplet placed at its pending end. If the capillary force exceeds the weight of the droplet, the droplet remains…
The dynamics of many glassy systems are known to exhibit string-like hopping motions each consisting of a line of particles displacing one and other. By using molecular dynamics simulations of glassy polymers, we show that these motions…
Drying suspensions often leave behind complex patterns of particulates, as might be seen in the coffee stains on a table. Here we consider the dynamics of periodic band or uniform solid film formation on a vertical plate suspended partially…
We present the results of analytic calculations and numerical simulations of the behaviour of a new class of chain molecules which we call thick polymers. The concept of the thickness of such a polymer, viewed as a tube, is encapsulated by…
Single--photon which is initially uncorrelated with atom, will evolve to be entangled with the atom on their continuous kinetic variables in the process of resonant scattering. We find the relations between the entanglement and their…
Polymer melts undergoing large deformation by uniaxial elongation are studied by molecular dynamics simulations of bead-spring chains in melts. Applying a primitive path analysis to strongly deformed polymer melts, the role of topological…
Formation of coffee stain deposits under evaporation of droplets containing aqueous solution of salts placed on silicone-oil impregnated substrates was observed. The formation of ring-like deposits was registered for various molar…
The effects of polymer concentration and chain length on aggregation in associative polymer solutions, are studied using self-consistent field lattice model. Only two inhomogenous morphologies, i.e. microfluctuation homogenous (MFH) and…
Our numerical study aims to investigate particle deposit patterns from the evaporation of a sessile colloidal droplet. An in house finite volume code is developed to simulate the coupled phenomena of flow and heat and mass transfer with…
The size dependence of the equilibrium droplet contact angle is governed by line tension. In this work, we identify a contribution to line tension arising from gravitational effects and pressure-induced changes in volume-fraction-dependent…
We have developed a theory of polymer entanglement using an extended Cahn-Hilliard functional, with two extra terms. One is a nonlocal attractive term, operating over mesoscales, which is interpreted as giving rise to entanglement, and the…
Ring, or cyclic, polymers have unique properties compared to linear polymers, due to their topologically closed structure that has no beginning or end. Experimental measurements on molecular ring polymers are challenging due to their…
We consider the problem of an ideal polymer confined in a droplet. When the droplet radius is smaller than the (unconfined) polymer radius of gyration, the polymer entropy will depend on the droplet shape. We compute the resulting surface…
We report an experimental study on the dynamics of a thin film of polymer solution coating a vertical fiber. The liquid film has first a constant thickness and then undergoes the Rayleigh-Plateau instability which leads to the formation of…