Related papers: 'Coffee-ring' patterns of polymer droplets: chain …
Polymer-related materials exhibit rich glassy behaviors at different length scales due to their various molecular structures and topological constraints. Recent studies have identified transient interpenetration of the long-chain rings…
The presence of a very small amount of high molecular weight polymer significantly delays the pinch-off singularity of a drop of water falling from a faucet, and leads to the formation of a long-lived cylindrical filament. In this paper we…
In our daily lives, after shaking a salad dressing, we see the coarsening of oil droplets suspended in vinegar. Such a demixing process is observed everywhere in nature and also of technological importance. For a case of high droplet…
Presenting theoretical arguments and numerical results we demonstrate long-range intrachain correlations in concentrated solutions and melts of long flexible polymers which cause a systematic swelling of short chain segments. They can be…
We use a version of the density functional theory to study the changes in the height of the tethered layer of chains built of jointed spherical segments with the change of the length and surface density of chains. For the model in which the…
Ring polymers are characterized by topology-specific entanglements called threadings. In the limit of large rings, it is conjectured that a "topological glass" should emerge due to the proliferation of threadings. In this study, we used…
The shape of a polymer plays an important role in determining its interactions with other molecules and with the environment, and is in turn affected by both of them. As a consequence, in the literature the shape properties of a chain in…
Plants and insects use slender conical structures to transport and collect small droplets, which are propelled along the conical structures due to capillary action. These droplets can deposit a fluid film during their motion, but despite…
In this study, we experimentally study the dried pattern droplets of coffee with and without sugar. We statistically analyze the rough surface formed after the stain becomes dried. The amount of sugar is controlled by the mass $m$. Along…
The amount of information propagated by an intermediate heavy particle exhibits characteristic features in inelastic scatterings with $n\geq 3$ final particles. As the total energy increases, the entanglement entropy, between its decay…
Polymer fibers consist of macromolecules oriented along the fiber axis. Better alignment of chains leads to an increased strength of the fiber. It is believed that the key factor preventing formation of a perfectly oriented fiber is…
The field of synthetic active matter has, thus far, been led by efforts to create point-like, isolated (yet interacting) self-propelled objects (\emph{e.g.} colloids, droplets, microrobots) and understanding their collective dynamics. The…
Drying complex fluids is a common phenomenon where a liquid phase transforms into a dense or porous solid. This transformation involves several physical processes, such as the diffusion of liquid molecules into the surrounding atmosphere…
We report simulation results on melts of entangled linear polymers confined in a free-standing thin film. We study how the geometric constraints imposed by the confinement alter the entanglement state of the system compared to the…
We consider the effect of droplet geometry on the early-stages of coffee ring formation during the evaporation of a thin droplet with an arbitrary simple, smooth, pinned contact line. We perform a systematic matched asymptotic analysis of…
The effects of line tension on the morphology of a lens-shaped droplet and bubble placed on the inner wall of a spherical cavity are studied. The contact angle between the lens-shaped droplet and the concave spherical substrate is expressed…
A thin polymeric film in contact with a fluid body may leach low-molecular-weight compounds into the fluid. If this fluid is a small droplet, the compound concentration within the liquid increases due to ongoing leaching in combination with…
The transport coefficients of dense polymeric fluids are approximately calculated from the microscopic intermolecular forces. The following finite molecular weight effects are discussed within the Polymer-Mode-Coupling theory (PMC) and…
Here, we study the coalescence of two droplets that are moving in the same direction on a soft surface; the motion of the droplets is caused by a gradient in the surface stiffness. As reference, stationary coalescence of the same droplets…
I develop a kinetic mechanism to explain chain folding in polymer crystallization which is based on the competition between the formation of stems, which is due to frequent occupations of trans states along the chains in the supercooled…