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Related papers: Qualitative Features at the Glass Crossover

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The mode-coupling theory (MCT) of the glass transition ranks among the most successful first-principles kinetic theories to describe glassy dynamics. However, MCT does not fully account for crucial aspects of the dynamics near the glass…

Soft Condensed Matter · Physics 2024-08-22 Ilian Pihlajamaa , Liesbeth M. C. Janssen

Within the mode-coupling theory for ideal glass-transitions, the mean-squared displacement and the correlation function for density fluctuations are evaluated for a colloidal liquid of particles interacting with a square-well potential for…

Soft Condensed Matter · Physics 2007-05-23 M. Sperl

A unified treatment of structural relaxation in a deeply supercooled glassy liquid is developed which extends the existing mode coupling theory (MCT) by incorporating the effects of activated events by using the concepts from the random…

Disordered Systems and Neural Networks · Physics 2007-05-23 Sarika Maitra Bhattacharyya , Biman Bagchi , Peter G. Wolynes

$\beta$ and $\alpha$ relaxation processes are dynamical scaling regimes of glassy systems occurring on two separate time scales which both diverge as the glass state is approached. We study here the crossover scaling from $\beta$- to…

Statistical Mechanics · Physics 2015-12-17 Mauro Sellitto

We present an extensive treatment of the generalized mode-coupling theory (GMCT) of the glass transition, which seeks to describe the dynamics of glass-forming liquids using only static structural information as input. This theory amounts…

Statistical Mechanics · Physics 2016-07-05 Liesbeth M. C. Janssen , Peter Mayer , David R. Reichman

The equations of the mode-coupling theory (MCT) for ideal liquid-glass transitions are used for a discussion of the evolution of the density-fluctuation spectra of glass-forming systems for frequencies within the dynamical window between…

Soft Condensed Matter · Physics 2015-06-25 W. Gotze , M. R. Mayr

We develop a mode coupling theory(MCT) to study the nonequilibrium glass transition behavior of a mono-disperse mixture of active-passive hard-sphere particles. The MCT equations clearly demonstrate that the glass transition is shifted to…

Soft Condensed Matter · Physics 2015-06-10 Huai Ding , Mengkai Feng , Huijun Jiang , Zhonghuai Hou

We provide extended evidence that mode-coupling theory (MCT) of supercooled liquids for the ${\mathsf F}_{12}$ schematic model admits a microscopic realization based on facilitated spin models with tunable facilitation. Depending on the…

Disordered Systems and Neural Networks · Physics 2012-08-24 Jeferson J. Arenzon , Mauro Sellitto

We give a brief introduction to the mode-coupling theory of the glass transition, a theory which was proposed a while ago to describe the dynamics of supercooled liquids. After presenting the basic equations of the theory, we review some of…

Statistical Mechanics · Physics 2008-02-03 W. Kob

Collective motion over increasing length scales is a signature of the vitrification process of liquids. We demonstrate the emergence of distinct static and dynamic length scales probed near the free surface in fully equilibrated…

Statistical Mechanics · Physics 2022-11-28 Hailong Peng , Huashan Liu , Thomas Voigtmann

The following properties are in the present literature associated with the behavior of super-cooled glass-forming liquids: faster than exponential growth of the relaxation time, dynamical heterogeneities, growing point-to-set correlation…

Statistical Mechanics · Physics 2011-01-25 Florent Krzakala , Lenka Zdeborová

We study the equilibrium statistical properties of the potential energy landscape of several glass models in a temperature regime so far inaccessible to computer simulations. We show that unstable modes of the stationary points undergo a…

Statistical Mechanics · Physics 2019-12-11 Daniele Coslovich , Andrea Ninarello , Ludovic Berthier

We analyze the glassy dynamics of a binary mixtures of hard disks in two dimensions. Predictions of the Mode-Coupling theory(MCT) are tested with extensive Brownian dynamics simulations. Measuring the collective particle density correlation…

Soft Condensed Matter · Physics 2011-04-27 Fabian Weysser , David Hajnal

We review recent developments in structural-dynamical phase transitions in trajectory space. An open question is how the dynamic facilitation theory of the glass transition may be reconciled with thermodynamic theories that posit a…

Statistical Mechanics · Physics 2020-08-04 C. Patrick Royall , Francesco Turci , Thomas Speck

Glass-forming liquids are broadly classified as being fragile or strong, depending on the deviation from Arrhenius behavior of their relaxation times. A fragile to strong crossover is observed or inferred in liquids like water and silica,…

Soft Condensed Matter · Physics 2022-04-12 Pallai Das , Srikanth Sastry

Sticky hard spheres, i.e., hard particles decorated with a short-ranged attractive interaction potential, constitute a relatively simple model with highly non-trivial glassy dynamics. The mode-coupling theory of the glass transition (MCT)…

Soft Condensed Matter · Physics 2021-08-26 Chengjie Luo , Liesbeth M. C. Janssen

There exists a variety of theories of the glass transition and many more numerical models. But because the models need built-in complexity to prevent crystallization, comparisons with theory can be difficult. We study the dynamics of a…

Statistical Mechanics · Physics 2010-04-16 P. Charbonneau , A. Ikeda , J. A. van Meel , K. Miyazaki

The mode-coupling theory of the glass transition treats the dynamics of supercooled liquids in terms of two-point density correlation functions. Here we consider a generalized, hierarchical formulation of schematic mode-coupling equations…

Statistical Mechanics · Physics 2014-11-27 Liesbeth M. C. Janssen , Peter Mayer , David R. Reichman

Mode-coupling theory (MCT) is conjectured to be a mean-field description of dynamics of the structural glass transition and the replica theory to be its thermodynamic counterpart. However, the relationship between the two theories remains…

Soft Condensed Matter · Physics 2015-05-18 Atsushi Ikeda , Kunimasa Miyazaki

The interrelation of dynamic processes active on separated time-scales in glasses and viscous liquids is investigated using a model displaying two time-scale bifurcations both between fast and secondary relaxation and between secondary and…

Disordered Systems and Neural Networks · Physics 2015-03-19 Andrea Crisanti , Luca Leuzzi , Matteo Paoluzzi