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Charge transport in crystalline organic semiconductors is intrinsically limited by the presence of large thermal molecular motions, which are a direct consequence of the weak van der Waals inter-molecular interactions. These lead to an…

Materials Science · Physics 2018-06-18 S. Fratini , D. Mayou , S. Ciuchi

A relation derived from the Kubo formula shows that optical conductivity measurements below the gap frequency in doped semiconductors can be used to probe directly the time-dependent quantum dynamics of charge carriers. This allows to…

Materials Science · Physics 2015-03-17 S. Ciuchi , S. Fratini , D. Mayou

We explore the charge transport mechanism in organic semiconductors based on a model that accounts for the thermal intermolecular disorder at work in pure crystalline compounds, as well as extrinsic sources of disorder that are present in…

Materials Science · Physics 2012-12-10 S. Ciuchi , S. Fratini

Bloch-Boltzmann transport theory fails to describe the carrier diffusion in current crystalline organic semiconductors, where the presence of large-amplitude thermal molecular motions causes substantial dynamical disorder. The charge…

Materials Science · Physics 2020-01-08 S. Fratini , S. Ciuchi

We use first-principle Quantum Monte-Carlo (QMC) simulations and numerical exact diagonalization to analyze the low-frequency charge carrier mobility within a simple tight-binding model of molecular organic semiconductors on a…

Materials Science · Physics 2025-07-23 Pavel Buividovich , Johann Ostmeyer , Alessandro Troisi

Charge transport in organic semiconductors is notoriously extremely sensitive to the presence of disorder, both internal and external (i.e. related to the interactions with the dielectric layer), especially for n-type materials. Internal…

We continue to develop a new approach to description of charge kinetics in disordered semiconductors. It is based on fractional diffusion equations. This article is devoted to transient processes in structures under dispersive transport…

Disordered Systems and Neural Networks · Physics 2013-10-02 Renat T. Sibatov , Vladimir V. Uchaikin

Organic semiconductors are indispensable for today's display technologies in form of organic light emitting diodes (OLEDs) and further optoelectronic applications. However, organic materials do not reach the same charge carrier mobility as…

Soft Condensed Matter · Physics 2023-10-12 Patrick Reiser , Manuel Konrad , Artem Fediai , Salvador Léon , Wolfgang Wenzel , Pascal Friederich

The charge carrier drift mobility in disordered semiconductors is commonly graphically extracted from time-of-flight (ToF) photocurrent transients yielding a single transit time. However, the term transit time is ambiguously defined and…

Disordered Systems and Neural Networks · Physics 2014-05-23 Jens Lorrmann , Manuel Ruf , David Vocke , Vladimir Dyakonov , Carsten Deibel

Rapid progress in organic electronics demands new highly efficient organic semiconducting materials. Nevertheless, only few materials have been created so far that show reliable band-like transport with high charge mobilities, which…

Charge transport in organic semiconductors is notoriously extremely sensitive to the presence of disorder, both intrinsic and extrinsic, especially for n-type materials. Intrinsic dynamic disorder stems from large thermal fluctuations both…

Charge transport in disordered two-dimensional (2D) systems showcases a myriad of unique phenomenologies that highlight different aspects of the underlying quantum dynamics. Electrons in such systems undergo a crossover from ballistic…

Mesoscale and Nanoscale Physics · Physics 2025-11-18 H. P. Veiga , S. M. João , J. M. Alendouro Pinho , J. P. Santos Pires , J. M. Viana Parente Lopes

The nonlocal electron-phonon couplings in organic semiconductors responsible for the fluctuation of intermolecular transfer integrals has been the center of interest recently. Several irreconcilable scenarios coexist for the description of…

Materials Science · Physics 2021-08-04 Weitang Li , Jiajun Ren , Zhigang Shuai

Transport of charge carriers in mechanically soft semiconductors is mainly limited by their interaction with slow intermolecular phonons. Carrier motion exhibits a crossover from superdiffusive to subdiffusive, producing a distinct…

Strongly Correlated Electrons · Physics 2025-07-08 Veljko Janković

We present a model of charge transport in organic molecular semiconductors based on the effects of lattice fluctuations on the quantum coherence of the electronic state of the charge carrier. Thermal intermolecular phonons and librations…

Other Condensed Matter · Physics 2009-11-11 J. -D. Picon , M. N. Bussac , L. Zuppiroli

I present a theory of electron dynamics in semiconductors with slowly varying composition. I show that the frequency-dependent conductivity, required for the description of transport and optical properties, can be obtained from a knowledge…

Condensed Matter · Physics 2016-08-31 Michael R. Geller

We consider an electron interacting locally with two-level systems (TLSs) as an archetypal model for charge transport in the presence of inelastic scatterers. To assess the importance of quantum effects in the optical and d.c. conductivity…

Strongly Correlated Electrons · Physics 2025-09-25 Hadi Rammal , Sergio Ciuchi , Simone Fratini

Building on the recent success of a quantum-classical method for computing transport properties in the Holstein model with a single phonon mode [P. Mitri\'c et al., Phys. Rev. B ${\bf 111}$, L161105 (2025)], we now assess its reliability in…

Strongly Correlated Electrons · Physics 2026-04-08 Darko Tanasković , Maksim Makrushin , Petar Mitrić

The dynamic disorder model for charge carrier transport in organic semiconductors has been extensively studied in recent years. Although it is successful on determining the value of bandlike mobility in the organic crystalline materials,…

Materials Science · Physics 2012-06-21 Yao Yao , Wei Si , Xiaoyuan Hou , Chang-Qin Wu

Excitonic transport in static disordered one dimensional systems is studied in the presence of thermal fluctuations that are described by the Haken-Strobl-Reineker model. For short times, non-diffusive behavior is observed that can be…

Mesoscale and Nanoscale Physics · Physics 2015-05-05 Jeremy M. Moix , Michael Khasin , Jianshu Cao
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