Related papers: Entropy and relaxation time
A theory for the non-local shear stress correlations in supercooled liquids is derived from first principles. It captures the crossover from viscous to elastic dynamics at an idealized liquid to glass transition and explains the emergence…
The mixing of two different gases is one of the most common natural phenomena, with applications ranging from CO$_2$ capture to water purification. Traditionally, mixing is analyzed in the context of local thermal equilibrium, where systems…
In the context of a classical example of glass-formation in 3-dimensions we exemplify how to construct a statistical mechanical theory of the glass transition. At the heart of the approach is a simple criterion for verifying a proper choice…
We combine the swap Monte Carlo algorithm to long multi-CPU molecular dynamics simulations to analyse the equilibrium relaxation dynamics of model supercooled liquids over a time window covering ten orders of magnitude for temperatures down…
We present analytical results for the time-dependent information entropy in exactly solvable two-state (qubit) models. The first model describes dephasing (decoherence) in a qubit coupled to a bath of harmonic oscillators. The entropy…
Time-reversal symmetry breaking and entropy production are universal features of nonequilibrium phenomena. Despite its importance in the physics of active and living systems, the entropy production of systems with many degrees of freedom…
A hierarchy of timescales is ubiquitous in biological systems, where enzymatic reactions play an important role because they can hasten the relaxation to equilibrium. We introduced a statistical physics model of interacting spins that also…
Recent theories predict that when a supercooled liquid approaches the glass transition, particle clusters with a special "amorphous order" nucleate within the liquid, which lead to static correlations dictating the dramatic slowdown of…
We review a new form of entropy suggested by us, with origin in mixing of states of systems due to interactions and deformations of phase cells. It is demonstrated that this nonextensive form also leads to asymmetric maximal entropy…
We investigate the role of entropic concepts for the relaxation dynamics in granular systems. In these systems the existence of a geometrical frustration induces a drastic modification of the allowed phase space, which in its turn induces a…
In glass-forming liquids, structural dynamics are governed by configurational entropy and temperature, with dielectric relaxation time scaling alongside structural relaxation time as described by the Adam-Gibbs (AG) model. Under Edwards's…
Different notions of entropy play a fundamental role in the classical theory of dynamical systems. Unlike many other concepts used to analyze autonomous dynamics, both measure-theoretic and topological entropy can be extended quite…
Glass-forming liquids exhibit a dramatic dynamical slowdown as the temperature is lowered. This can be attributed to relaxation proceeding via large structural rearrangements whose characteristic size increases as the system cools. These…
The previous investigation on Rayleigh-B\'enard convection of a dilute classical gas [T. Kita: J. Phys. Soc. Jpn. {\bf 75} (2006) 124005] is extended to calculate entropy change of the convective transition with the rigid boundaries. We…
Computer simulations have been employed in recent years to evaluate the configurational entropy changes in model glass-forming liquids. We consider two methods, both of which involve the calculation of the `intra-basin' entropy as a means…
The principal theme of this paper is that anomalously slow, super-Arrhenius relaxations in glassy materials may be activated processes involving chains of molecular displacements. As pointed out in a preceding paper with A. Lemaitre, the…
We obtain bounds on fluctuations of two entropy estimators for a class of one-dimensional Gibbs measures on the full shift. They are the consequence of a general exponential inequality for Lipschitz functions of n variables. The first…
It has been known that the binary replica liquid theory (RLT) is inconsistent with its one-component counterpart; In the limit that all atoms are identical, the configurational entropy and thus the glass transition point calculated by the…
We study the role of elasticity-induced facilitation on the dynamics of glass-forming liquids by a coarse-grained two-dimensional model in which local relaxation events, taking place by thermal activation, can trigger new relaxations by…
Typical properties of glassy materials are shown to be captured by a mean-field free-volume theory. Relaxation processes are supposed to be free-volume activated, and different entropy barriers are associated with density relaxation and…