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The behavior of an excess electron in a one, two and three dimensional classical liquid has been studied with the aid of Chandler, Singh and Richardson (CSR) theory [J. Chem. Phys. {\bf 81} 1975 (1984)] . The size or dispersion of the…

Statistical Mechanics · Physics 2007-05-23 Ashok Sethia , Eric R. Bittner , Fumio Hirata

We show that as an electron transfers between closed-shell molecular fragments at large separation, the exact correlation potential of time-dependent density functional theory gradually develops a step and peak structure in the bonding…

Chemical Physics · Physics 2014-02-11 Johanna I. Fuks , Peter Elliott , Angel Rubio , Neepa T. Maitra

A new kinetic instability which results in formation of charge density waves is proposed. The instability is of a purely classical nature. A spatial period of arising space-charge and field configuration is inversely proportional to…

Soft Condensed Matter · Physics 2009-11-07 V. Yu. Kachorovskii , I. S. Lioublinskii , L. D. Tsendin

Inhomogeneous charge distributions have important repercussions on electrostatic interactions in systems of charged particles but are often difficult to examine theoretically. We investigate how electrostatic interactions are influenced by…

Soft Condensed Matter · Physics 2013-02-25 Anze Losdorfer Bozic , Rudolf Podgornik

Based on the Thomas-Fermi solution for compressed electron gas around a giant nucleus, $Z\approx 10^6$, we study electric pulsations of electron number-density, pressure and electric fields, which could be caused by an external…

Plasma Physics · Physics 2015-06-16 Hendrik Ludwig , Remo Ruffini , She-Sheng Xue

The computational and theoretical analysis carried out in this article demonstrates the existence of a nontrivial mechanism for the compression of a submicron-sized gas bubble formed by a gas of classical ions and a gas of degenerate…

Open-shell non-rigid molecular systems exhibiting an internal rotation are likely candidates for a coupling between the spin angular momentum of the unpaired electron and the torsional motion. This electron spin-torsion coupling lacked both…

A new model of quantum mechanics, Classical Quantum Mechanics, is based on the (nearly heretical) postulate that electrons are physical objects that obey classical physical laws. Indeed, ionization energies, excitation energies etc. are…

Plasma Physics · Physics 2008-10-30 Jonathan Phillips

This is the second of two papers devoted to tight-binding electronic spectra on graphs with the topology of the sphere. We investigate the problem of an electron subject to a spin-orbit interaction generated by the radial electric field of…

Mesoscale and Nanoscale Physics · Physics 2008-06-13 Y. Avishai , J. M. Luck

Motivated by recent experiments on Al nanoparticles, we have studied the effects of fixed electron number and small size in nanoscale superconductors, by applying the canonical BCS theory for the attractive Hubbard model in two and three…

Superconductivity · Physics 2009-10-31 K. Tanaka , F. Marsiglio

An analysis is made within the quantum formalism of the probabilistic features of the electron spin correlation, with the purpose of clarifying the concepts of contextuality and measurement dependence. The quantum formulas for the spin…

Quantum Physics · Physics 2022-07-07 Ana María Cetto

We continue our study of the quantum optics of a single photon interacting with a system of two level atoms. In this work we investigate the case of a periodic arrangement of atoms. We provide a general structure theorem characterizing the…

Mathematical Physics · Physics 2023-11-22 Erik Orvehed Hiltunen , Joseph Kraisler , John C. Schotland , Michael I. Weinstein

Atomic nuclei can be spontaneously deformed into non-spherical shapes as many-nucleon systems. We discuss to what extent a similar deformation takes place in many-electron systems. To this end, we employ several many-body methods, such as…

Atomic Physics · Physics 2021-09-24 Tomoya Naito , Shimpei Endo , Kouichi Hagino , Yusuke Tanimura

By extrapolating the energies of non-relativistic atoms and their ions with up to 3000 electrons within Kohn-Sham density functional theory, we find that the ionization potential remains finite and increases across a row, even as…

Materials Science · Physics 2015-05-19 Lucian A. Constantin , John C. Snyder , John P. Perdew , Kieron Burke

Employing a local formula for the electron-electron interaction energy, we derive a self-consistent approximation for the total energy of a general $N$-electron system. Our scheme works as a local variant of the Thomas-Fermi approximation…

Chemical Physics · Physics 2013-10-31 E. Rasanen , A. Odriazola , I. Makkonen , A. Harju

The collinear QCD structure of the electron is studied within the Standard Model. The electron structure function is defined and calculated in leading logarithmic approximation. It shows important contribution from the interference of the…

High Energy Physics - Phenomenology · Physics 2007-05-23 Wojciech Slominski , Jerzy Szwed

In electronic structure calculations, the correlation energy is defined as the difference between the mean field and the exact solution of the non relativistic Schr\"odinger equation. Such an error in the different calculations is not…

Quantum Physics · Physics 2022-04-04 Kumar J. B. Ghosh , Sabre Kais , Dudley R. Herschbach

Closed shell molecular structures are under normal conditions time-reversal invariant. Experimental evidences point, however, towards that this invariance may be locally violated when the structure is in contact with a particle reservoir.…

Mesoscale and Nanoscale Physics · Physics 2023-12-27 M. Shiranzaei , S. Kalhöfer , J. Fransson

Shell effects reflects irregularities of physical quantities caused by a discrete energy spectrum. The theory of the shell effects by Kirzhnits and Shpatakovskaya is valid only at relatively low densities providing for oscillations of…

Plasma Physics · Physics 2016-08-30 Sergey Dyachkov , Pavel Levashov

Coulomb interactions that occur in electronic structure calculations are correlated by allowing basis function components of the interacting densities to polarize, thereby reducing the magnitude of the interaction. Exchange integrals of…

Chemical Physics · Physics 2022-05-16 Jerry L. Whitten