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The limit relations for the partial derivatives of the two-electron atomic wave functions at the two-particle coalescence lines have been obtained numerically using accurate CFHHM wave functions. The asymptotic solutions of the proper…

Atomic Physics · Physics 2009-11-11 E. Z. Liverts , M. Ya. Amusia , R. Krivec , V. B. Mandelzweig

The static dipole polarizabibility for the $1s\sigma$ electron state of the $\mathrm{H}_{2}^{+}$ hydrogen molecular ion is calculated within Born-Oppenheimer approximation. The variational expansion with randomly chosen exponents has been…

Atomic Physics · Physics 2010-07-27 Ts. Tsogbayar

The polynomial solution of the Schrodinger equation for the Pseudoharmonic potential is found for any arbitrary angular momentum $l$. The exact bound-state energy eigenvalues and the corresponding eigen functions are analytically…

Quantum Physics · Physics 2007-05-23 Sameer M. Ikhdair , Ramazan Sever

The single excitation subspace (SES) method for universal quantum simulation is investigated for a number of diatomic molecular collision complexes. Assuming a system of $n$ tunably-coupled, and fully-connected superconducting qubits,…

Quantum Physics · Physics 2016-02-02 P. C. Stancil , H. You , A. Cook , A. T. Sornborger , M. R. Geller

The intrinsic and dynamic kinetic energies, and the potential energies of electron states in the hydrogen atom, were determined using the operator formalism in the Schrodinger nonrelativistic equation. Intrinsic energies were determined…

Quantum Physics · Physics 2025-05-12 Jacek Mroczkowski

We present quantum algorithms for simulating the dynamics of a broad class of classical oscillator systems containing $2^n$ coupled oscillators (Eg: $2^n$ masses coupled by springs), including those with time-dependent forces, time-varying…

Quantum Physics · Physics 2025-05-26 Abhinav Muraleedharan , Nathan Wiebe

Path integral Monte Carlo approach is used to study the coupled quantum dynamics of the electron and nuclei in hydrogen molecule ion. The coupling effects are demonstrated by comparing differences in adiabatic Born--Oppenheimer and…

Chemical Physics · Physics 2008-12-29 I. Kylänpää , M. Leino , T. T. Rantala

We extend the usual Kustaanheimo-Stiefel $4D\to 3D$ mapping to study and discuss a constrained super-Wigner oscillator in four dimensions. We show that the physical hydrogen atom is the system that emerges in the bosonic sector of the…

Mathematical Physics · Physics 2009-08-24 R. de Lima Rodrigues

We expose the Schr\"odinger quantum mechanics with traditional applications to Hydrogen atom. We discuss carefully the experimental and theoretical background for the introduction of the Schr\"odinger, Pauli and Dirac equations, as well as…

Mathematical Physics · Physics 2007-05-23 A. Komech

Solving the electronic Schr\"odinger equation for changing nuclear coordinates provides access to the Born-Oppenheimer potential energy surface. This surface is the key starting point for almost all theoretical studies of chemical processes…

Chemical Physics · Physics 2022-01-14 Markus Reiher

Potential energy surfaces of the hydrogen molecular ion H$_2^+$ in the Born-Oppenheimer approximation are computed by means of the Riccati-Pad\'e method (RPM). The convergence properties of the method are analyzed for different states. The…

Chemical Physics · Physics 2022-10-25 Francisco Marcelo Fernández , Javier Garcia

Three quantum particles with on-site repulsion and nearest-neighbour attraction on a one-dimensional lattice are considered. The three-body Schroedinger equation is reduced to a set of single-variable integral equations. Energies of…

Strongly Correlated Electrons · Physics 2015-06-16 Pavel E. Kornilovitch

Using the technique of tridiagonal representation approach; for the first time, we extend this method to study quantum systems with literally perturbed Hamiltonians. Specifically, we consider a quantum system in a 3D spherical oscillator…

Quantum Physics · Physics 2022-12-12 Tunde Joseph Taiwo

We formulate the Schr\"odinger equation as the equation of motion of a small external influence which serves as the initial boundary condition of a physical system in classical laboratory space. The Hilbert space of possible external…

Quantum Physics · Physics 2011-04-12 R. Schuster

Quantum simulators are controllable quantum systems that can reproduce the dynamics of the system of interest, which are unfeasible for classical computers. Recent developments in quantum technology enable the precise control of individual…

Quantum Physics · Physics 2015-05-19 Xiao-song Ma , Borivoje Dakic , William Naylor , Anton Zeilinger , Philip Walther

The three-body scattering problem in Coulombic systems is widespread, however yet unresolved problem by the mathematically rigorous methods. In this work this long term challenge has been undertaken by combining distorted waves and…

Quantum Physics · Physics 2017-03-08 R. Lazauskas

The Schroedinger equation is solved for an A-nucleon system using an expansion of the wave function in nonsymmetrized hyperspherical harmonics. Our approach is both an extension and a modification of the formalism developed by Gattobigio et…

Nuclear Theory · Physics 2015-06-12 Sergio Deflorian , Nir Barnea , Winfried Leidemann , Giuseppina Orlandini

We use the "tridiagonal representation approach" to solve the time-independent Schr\"odinger equation for bound states in a basis set of finite size. We obtain two classes of solutions written as finite series of square integrable functions…

Quantum Physics · Physics 2022-08-22 A. D. Alhaidari

The oscillator bases expansion stands as an efficient approximation method for the time-independent Schr\"odinger equation. The method, originally formulated with one non-linear variational parameter, can be extended to incorporate two such…

Quantum Physics · Physics 2024-09-24 Cyrille Chevalier , Selma Youcef Khodja

The nonrelativistic energies of the homonuclear ion T$_2^+$ are calculated for the ground state using the Lagrange-mesh method as was done for the isotopomers H$_2^+$ and D$_2^+$ ({\it J. Phys. B: At. Mol. Opt. Phys.} {\bf 45} 065101 and…

Atomic and Molecular Clusters · Physics 2015-06-19 Horacio Olivares Pilón