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Instrumentation developments in electron energy-loss spectroscopy (EELS) in the scanning transmission electron microscope (STEM) one decade ago paved the way for combining milli-electronvolt energy resolution in spectroscopy with…

Mesoscale and Nanoscale Physics · Physics 2024-10-15 Benedikt Haas , Christoph T. Koch , Peter Rez

We develop a theory of momentum-resolved electron energy-loss spectra in the scanning transmission microscope (STEM-EELS) that captures the effects of coupled phonon and magnon excitations within a unified formalism, and apply it to…

High energy electron beams can now be routinely focused to 1-2 {\AA} and offer the ability to obtain vibrational information from materials using monochromated electron energy-loss spectroscopy (EELS) in a scanning transmission electron…

Materials Science · Physics 2021-07-13 Kartik Venkatraman , Peter A. Crozier

Atomic vibrations control all thermally activated processes in materials including diffusion, heat transport, phase transformations, and surface chemistry. Recent developments in monochromated, aberration-corrected scanning transmission…

Materials Science · Physics 2020-01-08 Kartik Venkatraman , Barnaby D. A. Levin , Katia March , Peter Rez , Peter A. Crozier

Electron energy-loss spectroscopy (EELS) can measure similar information to X-ray, UV-Vis, and IR spectroscopies but with atomic resolution and increased scattering cross sections. Recent advances in electron monochromators have expanded…

Chemical Physics · Physics 2024-04-26 Ye-Jin Kim , Levi D. Palmer , Wonseok Lee , Nicholas J. Heller , Scott K. Cushing

Phonon scattering at grain boundaries (GBs) is significant in controlling nanoscale device thermal conductivity. However, GBs could also act as waveguides for selected modes. To measure localized GB phonon modes, meV energy resolution is…

Mesoscale and Nanoscale Physics · Physics 2023-06-22 Benedikt Haas , Tara M. Boland , Christian Elsässer , Arunima K. Singh , Katia March , Juri Barthel , Christoph T. Koch , Peter Rez

Advances in atomic resolution in situ environmental transmission electron microscopy for direct probing of gas-solid reactions, including at very high temperatures are described. In addition, recent developments of dynamic real time in situ…

Chemical Physics · Physics 2017-05-17 Pratibha Gai , Edward Boyes

The performance of electron energy-loss spectrometers can often be limited by their electron-optical aberrations. Due to recent developments in high energy-resolution and momentum-resolved electron energy loss spectroscopy (EELS), there is…

Materials Science · Physics 2023-02-28 Yueming Guo , Andrew R. Lupini

Probing optical excitations with nanometer resolution is important for understanding their dynamics and interactions down to the atomic scale. Electron microscopes currently offer the unparalleled ability of rendering spatially-resolved…

Quantum Physics · Physics 2020-07-16 Valerio Di Giulio , Mathieu Kociak , F. Javier García de Abajo

The high beam current and sub-angstrom resolution of aberration-corrected scanning transmission electron microscopes has enabled electron energy loss spectroscopic (EELS) mapping with atomic resolution. These spectral maps are often…

Materials Science · Physics 2023-07-19 Paul Cueva , Robert Hovden , Julia A. Mundy , Huolin L. Xin , David A. Muller

Phonon resistance from dislocation scattering is often divided into short-range core interactions and long-range strain field interactions. Using electron energy-loss spectroscopy on a GaN dislocation, we report observations of vibrational…

The inelastic scattering of electrons is one route to study the vibrational and electronic properties of materials. Such experiments, also called electron energy-loss spectroscopy, are particularly useful for the investigation of the…

Materials Science · Physics 2014-06-24 Friedrich Roth , Andreas König , Jörg Fink , Bernd Büchner , Martin Knupfer

Functional nanomaterials, including 2D materials and their heterostructures are expected to impact fields ranging from catalysis, optoelectronics to nanophotonics. To realize their potential, novel experimental approaches need to be…

Mesoscale and Nanoscale Physics · Physics 2025-10-13 Cana Elgvin , Fredrik S. Hage , Khairi F. Elyas , Katja Höflich , Øystein Prytz , Christoph T. Koch , Hannah C. Nerl

Current advances in ultrafast electron microscopy make it possible to combine optical pumping of a nanostructure and electron beam probing with sub{\aa}ngstrom and femtosecond spatiotemporal resolution. We present a theory predicting that…

Recent developments in experiments with vibrational electron energy loss spectroscopy (EELS) have revealed spectral shape variations at spatial resolutions down to sub-atomic scale. Interpretation in terms of local phonon density of states…

Materials Science · Physics 2021-09-15 Paul M. Zeiger , Ján Rusz

In the past decade, the advent of time-resolved spectroscopic tools has provided a new ground to explore fundamental interactions in solids and to disentangle degrees of freedom whose coupling leads to broad structures in the frequency…

Fine structure analysis of core electron excitation spectra is a cornerstone characterization technique across the physical sciences. Spectra are most commonly measured with synchrotron radiation and X-ray spot sizes on the {\mu}m to mm…

Spectroscopic mapping by scanning transmission electron microscopy coupled with electron energy loss spectroscopy (STEM-EELS) is a powerful technique for determining the structure and chemistry of a wide range of materials and interfaces.…

Materials Science · Physics 2020-07-21 Berit H. Goodge , David J. Baek , Lena F. Kourkoutis

Ultrafast laser measurements probe the non-equilibrium dynamics of excited electrons in metals with increasing temporal resolution. Electronic structure calculations can provide a detailed microscopic understanding of hot electron dynamics,…

Computational Physics · Physics 2016-08-12 Ana M. Brown , Ravishankar Sundararaman , Prineha Narang , William A. Goddard , Harry A. Atwater

We provide a theoretical framework for the prediction and interpretation of momentum dependent phonon spectra due to coherent inelastic scattering of electrons. We complete the approach with first principles lattice dynamics using periodic…

Materials Science · Physics 2019-04-08 R. J. Nicholls , F. S. Hage , D. G. McCulloch , Q. M. Ramasse , K. Refson , J. R. Yates
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