Related papers: The Thermodynamic Covariance Principle
We describe the Lie group and the group representations associated to the nonlinear Thermodynamic Coordinate Transformations (TCT). The TCT guarantee the validity of the Thermodynamic Covariance Principle (TCP) : {\it The nonlinear closure…
The objective of this work is to determine the nonlinear flux-force relations for systems out of Onsager's region that respect the existing thermodynamic theorems for systems far from equilibrium. To this aim, a thermodynamic theory for…
A new formulation of the thermodynamic field theory (TFT) is presented. In this new version, one of the basic restriction in the old theory, namely a closed-form solution for the thermodynamic field strength, has been removed. In addition,…
A manifestly covariant, coordinate independent reformulation of the Thermodynamic Field Theory (TFT) is presented. The TFT is a covariant field theory that describes the evolution of a thermodynamic system, extending the near-equilibrium…
Two different physical systems are said to be thermodynamically equiv- alent if one of the thermodynamic potentials of the first system is pro- portional to the corresponding potential of the second system after expressing the state…
A decade ago, a macroscopic theory for closure relations has been proposed for systems out of Onsager's region. This theory is referred to as the "Thermodynamic Field Theory" (TFT). The aim of the work was to determine the nonlinear…
Time directions are not invariant in conventional thermodynamics. We broadly follow ideas of Ludwig Boltzmann and investigate implications of postulating time-directional invariance in thermodynamics. In this investigation, we require that…
In the present paper, the theory of cross phenomena (TCP) proposed by the present author is revised by starting from the first law of thermodynamics instead of the combined law of thermodynamics in the previous publication because the…
Conventional thermodynamics, which is formulated for our world populated by radiation and matter, can be extended to describe physical properties of antimatter in two mutually exclusive ways: CP-invariant or CPT-invariant. Here we refer to…
A variant of continuous nonequilibrium thermodynamic theory based on the postulate of the scale invariance of the local relation between generalized fluxes and forces has been proposed. This single postulate replaces the assumptions on…
The zeroth law of thermodynamics involves a transitivity relation (pairwise between three objects) expressed either in terms of `equal temperature' (ET), or `in equilibrium' (EQ) conditions. In conventional thermodynamics conditional on…
The speed-gradient variational principle (SG-principle) is formulated and applied to thermodynamical systems. It is shown that Prigogine's principle of minimum entropy production and Onsager's symmetry relations can be interpreted in terms…
This review presents a thermodynamic perspective on quantum coupled transport processes in nanoscale systems. Our analysis is formulated within the framework of entropy production rate, the central quantity governing non-equilibrium…
We derive a universal thermodynamic bound constraining directional transport in both discrete and continuous nonequilibrium systems. For continuous-time Markov jump processes and overdamped diffusions governed by Fokker--Planck equations,…
We critically revisit the definition of thermal equilibrium, in its operational formulation, provided by standard thermodynamics. We show that it refers to experimental conditions which break the covariance of the theory at a fundamental…
The Trajectory Class Fluctuation Theorem (TCFT) substantially strengthens the Second Law of Thermodynamics -- that, in point of fact, can be a rather weak bound on resource fluxes. Practically, it improves empirical estimates of free…
Thermodynamics is a science concerning the state of a system, whether it is stable, metastable, or unstable. The combined law of thermodynamics derived by Gibbs about 150 years ago laid the foundation of thermodynamics. In Gibbs combined…
The energy conversion efficiency of far-from-equilibrium systems is generally limited by irreversible thermodynamic fluxes that make contact with different heat baths. For complex systems, the states of the maximum efficiency and the…
In a thermodynamical process, the dissipation or production of entropy can only be positive or zero according to the second law of thermodynamics. However the laws of thermodynamics are applicable to large systems in the thermodynamic…
The Clausius-Clapeyron relation and its analogs in other first-order phase transitions, such as type-I superconductors, are derived using very elementary methods, without appealing to the more advanced concepts of entropy or Gibbs free…