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The problem of correlation between quantum states of four-atomic molecules in different geometrical configurations is reviewed in detail. A general, still simple rule is obtained which allows one to correlate states of a linear four-atomic…

Condensed Matter · Physics 2009-10-22 N. Manini , S. Oss

The realization of molecular-based electronic devices depends to a large extent on the ability to mechanically stabilize the involved molecular bonds, while making use of efficient resonant charge transport through the device. Resonant…

Mesoscale and Nanoscale Physics · Physics 2018-09-11 David Gelbwaser-Klimovsky , Alán Aspuru-Guzik , Michael Thoss , Uri Peskin

The generation of high harmonics in laser-irradiated light homonuclear diatomics (H2+, N2 and O2) compared to that in atomic counterparts (of nearly identical binding energy) is studied within the velocity gauge version of conventional…

Atomic Physics · Physics 2009-11-11 Vladimir I. Usachenko , Pavel E. Pyak , Shih-I Chu

An algebraic model taking into account the influence of the molecular rotation on the wave functions of vibrational-rotational states of the diatomic molecule using the formalism of the ladder operators and an expansion in a small parameter…

Atomic Physics · Physics 2011-12-30 S. A. Astashkevich

High-harmonic spectroscopy driven by circularly-polarized laser pulses and their counter-rotating second harmonic is a new branch of attosecond science which currently lacks quantitative interpretations. We extend this technique to the…

Atomic Physics · Physics 2019-09-04 Denitsa Baykusheva , Simon Brennecke , Manfred Lein , Hans Jakob Wörner

A rigorous quantum description of molecular dynamics with a particular emphasis on internal observables is developed accounting explicitly for kinetic couplings between nuclei and electrons. Rotational modes are treated in a genuinely…

Chemical Physics · Physics 2015-07-07 Sylvain D. Brechet , Francois A. Reuse , Klaus Maschke , Jean-Philippe Ansermet

We identify the molecular ion NH^+ as a potential candidate for probing variations in the fine structure constant alpha and electron-to-proton mass ratio mu. NH^+ has an anomalously low-lying excited Sigma state, being only a few hundred…

Atomic Physics · Physics 2012-09-07 K. Beloy , M. G. Kozlov , A. Borschevsky , A. W. Hauser , V. V. Flambaum , P. Schwerdtfeger

We experimentally obtained a direct image of the nuclear wave functions of {H_2}^+ by dissociating the molecule via electron attachment and determining the vibrational state using the COLTRIMS technique. Our experiment visualizes the nodal…

Atomic Physics · Physics 2012-02-20 L. Ph. H. Schmidt , T. Jahnke , A. Czasch , M. Schöffler , H. Schmidt-Böcking , R. Dörner

Conformational change of a DNA molecule is frequently observed in multiple biological processes and has been modelled using a chain of strongly coupled oscillators with a nonlinear bistable potential. While the mechanism and properties of…

Biological Physics · Physics 2020-08-07 Soumyadip Banerjee , Kushal Shah , Shaunak Sen

We present compelling evidence supporting the conjecture that the origin of the roton in Bose-condensed systems arises from strong correlations between the constituent particles. By studying the two dimensional bosonic dipole systems a…

Quantum Gases · Physics 2012-08-07 G. J. Kalman , P. Hartmann , K. I. Golden , A. Filinov , Z. Donko

Structural relaxation in hard-sphere colloidal glasses has been studied using confocal microscopy. The motion of individual particles is followed over long time scales to detect the rearranging regions in the system. We have used normal…

Soft Condensed Matter · Physics 2015-05-30 Antina Ghosh , Vijayakumar Chikkadi , Peter Schall , Daniel Bonn

We present a simple quantum mechanical model describing excited rotational states of molecules in superfluid helium nanodroplets, as recently studied in non-adiabatic molecular alignment experiments [Cherepanov et al., Phys. Rev. A 104,…

We report on the observation of coherent molecular vibrations launched by the breaking of a molecular bond. The methyl radical, which is produced by $267\,\mathrm{nm}$ photodissociation of methyl iodide, is excited to high levels in its…

Short intense laser pulses are routinely used to induce rotational wave packet dynamics of molecules. Ro-vibrational wave packet dynamics has been explored comparatively infrequently, focusing predominantly on extremely light and rigid…

Quantum Gases · Physics 2024-11-12 D. Blume , Q. Guan , J. Kruse , M. Kunitski , R. Doerner

Recent reports on intense-field pump-probe experiments for high harmonic generation from coherently rotating linear molecules, have revealed remarkable characteristic effects of the simultaneous variation of the polarization geometry and…

Atomic and Molecular Clusters · Physics 2009-11-13 F. H. M. Faisal , A. Abdurrouf

A simple phenomenological model for describing the conformational dynamics of biological macromolecules via the nonlinearity-induced instabilities is proposed. It is shown that the interaction between charges and bending degrees of freedom…

Soft Condensed Matter · Physics 2009-11-11 Yu. B. Gaididei , P. L. Christiansen , W. J. Zakrzewski

We introduce a novel method to investigate the stability of wave packet dynamics under perturbations of the Hamiltonian. Our approach relies on semiclassical approximations, but is non-perturbative. Two separate contributions to the quantum…

Chaotic Dynamics · Physics 2009-11-11 Jens Bolte , Tobias Schwaibold

We propose a model for a molecular junction with internal anharmonic torsional vibrations interacting with an electric current. The Wangsness-Bloch-Redfield master equation approach is used to determine the stationary reduced density matrix…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 Ivan A. Pshenichnyuk , Martin Čížek

The off-normal ion irradiation of semiconductor materials is seen to induce nanopatterning effects. Different theories are proposed to explain the mechanisms that drive self-reorganization of amorphisable surfaces. One of the prominent…

Materials Science · Physics 2022-11-24 A. Lopez-Cazalilla , F. Djurabekova , K. Nordlund

We suggest and implement an approach for the bottom-up description of systems undergoing large-scale structural changes and chemical transformations from dynamic atomically resolved imaging data, where only partial or uncertain data on…

Materials Science · Physics 2021-04-23 Sergei V. Kalinin , Ondrej Dyck , Stephen Jesse , Maxim Ziatdinov