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The van der Waals (VDW) equation of state is a simple and popular model to describe the pressure function in equilibrium systems of particles with both repulsive and attractive interactions. This equation predicts an existence of a…

Nuclear Theory · Physics 2015-06-29 V. Vovchenko , D. V. Anchishkin , M. I. Gorenstein

Linear fluctuating hydrodynamics is a useful and versatile tool for describing fluids, as well as other systems with conserved fields, on a mesoscopic scale. In one spatial dimension, however, transport is anomalous, which requires to…

Statistical Mechanics · Physics 2016-01-05 Herbert Spohn

This paper is devoted to analyzing the critical phenomenon and phase transition of quintessential Kerr-Newman-anti-de Sitter black hole in the framework of Maxwell equal-area law. For this purpose, we first derive thermodynamic quantities…

General Relativity and Quantum Cosmology · Physics 2020-10-08 M. Sharif , Qanitah Ama-Tul-Mughani

We formulate an approximate thermodynamic theory of the phase transition in driven lattice gases with attractive nearest-neighbor interactions. We construct the van der Waals equation of state for a driven system where a nonequilibrium…

Statistical Mechanics · Physics 2011-11-30 Punyabrata Pradhan , Udo Seifert

The behavior of fluids in the vicinity of the liquid-gas critical point is studied within the cell fluid model framework. The analytic method for deriving the equation of state of a cell fluid model in the low-temperature region (T<Tc) is…

Statistical Mechanics · Physics 2020-02-27 I. V. Pylyuk

It is generally agreed that the supercritical region of a liquid consists of one single state (supercritical fluid). On the other hand, we show here that liquids in this region exist in two qualitatively different states: "rigid" and…

Statistical Mechanics · Physics 2015-05-27 V. V. Brazhkin , Yu. D. Fomin , A. G. Lyapin , V. N. Ryzhov , Kostya Trachenko

The thermodynamic properties of the supercooled liquid state of the mW model of water show anomalous behavior. Like in real water, the heat capacity and compressibility sharply increase upon supercooling. One of the possible explanations of…

Chemical Physics · Physics 2013-05-02 Vincent Holten , David T. Limmer , Valeria Molinero , Mikhail A. Anisimov

Inspired by the recent developments in the study of the thermodynamics of van der Waals fluids via the theory of nonlinear conservation laws and the description of phase transitions in terms of classical (dissipative) shock waves, we…

Exactly Solvable and Integrable Systems · Physics 2016-08-24 Francesco Giglio , Giulio Landolfi , Antonio Moro

We study the statistical properties of two hard spheres in a two dimensional rectangular box. In this system, the relation like Van der Waals equation loop is obtained between the width of the box and the pressure working on side walls. The…

Condensed Matter · Physics 2009-10-31 Akinori Awazu

We investigate the geometric properties of the equilibrium manifold of a thermodynamic system determined by the van der Waals equations of state. We use the formalism of geometrothermodynamics to obtain results that are invariant under…

Mathematical Physics · Physics 2012-05-17 Hernando Quevedo , Antonio Ramirez

This work presents a pedagogical derivation of the thermodynamics of a van der Waals fluid by explicitly incorporating pairwise molecular interactions and the finite size of particles into the statistical-mechanical description. Starting…

Statistical Mechanics · Physics 2026-01-09 J. L. Cardoso , V. G. Ibarra-Sierra , J. C. Sandoval-Santana , A. Kunold

We study a singular-limit problem arising in the modelling of chemical reactions. At finite {\epsilon} > 0, the system is described by a Fokker-Planck convection-diffusion equation with a double-well convection potential. This potential is…

Analysis of PDEs · Mathematics 2014-09-16 Steffen Arnrich , Alexander Mielke , Mark A. Peletier , Giuseppe Savaré , Marco Veneroni

The following paper has been motivated from recent works of Kremer, G.M [1, 4], Vardiashvili, G [2], Jantsch, R.C [3], Capozziello, S [5] on Van-Der-Waals EOS cosmology. The main aim for this paper is to analyze the thermodynamics of a…

General Relativity and Quantum Cosmology · Physics 2021-10-27 Shouvik Sadhukhan , Alokananda Kar , Surajit Chattopadhyay

Recent research suggests that the supercritical state consists of liquidlike and gaslike states where particle dynamics and key system properties are qualitatively different. We report experimental evidence of the structural crossover in…

Materials Science · Physics 2017-05-17 C. Prescher , Yu. D. Fomin , V. B. Prakapenka , J. Stefanski , K. Trachenko , V. V. Brazhkin

We review the available experimental information on the thermodynamic properties of supercooled ordinary and heavy water and demonstrate the possibility of modeling these thermodynamic properties on a theoretical basis. We show that by…

Chemical Physics · Physics 2013-02-25 V. Holten , C. E. Bertrand , M. A. Anisimov , J. V. Sengers

Granular systems confined in vertically vibrated shallow horizontal boxes (quasi two-dimensional geometry) present a liquid to solid phase transition when the frequency of the periodic forcing is increased. An effective model, where grains…

Statistical Mechanics · Physics 2018-08-08 Dino Risso , Rodrigo Soto , Marcelo Guzman

The problem of a physical relevance (meaning) of percolation in supercritical fluids is addressed considering a primitive model of water. Two different criteria, physical and configurational, are used for the cluster definition in Monte…

Soft Condensed Matter · Physics 2012-07-16 J. Skvor , I. Nezbeda

In this paper we have studied Van-Der-Waals fluid system with the generalized EOS as as discussed in the recent works of Kremer, G.M [1, 4], Vardiashvili, G [2], Jantsch, R.C [3], Capozziello, S [5]. and are functions of energy density and…

General Relativity and Quantum Cosmology · Physics 2021-10-27 Alokananda Kar , Shouvik Sadhukhan , Surajit Chattopadhyay

In anisotropic or layered superconductors thermal fluctuations as well as impurities induce a van der Waals (vdW) attraction between flux lines, as has recently been shown by Blatter and Geshkenbein in the thermal case [Phys. Rev. Lett. 77,…

Superconductivity · Physics 2009-10-31 Andreas Volmer , Sutapa Mukherji , Thomas Nattermann

In the region close to the thermodynamic critical point and in the proximity of the pseudo-boiling (Widom) line, strong property variations substantially alter the growth of modal instabilities, as revealed in Ren et al. (J. Fluid Mech.,…