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We present two efficient and intruder-free methods for treating dynamic correlation on top of general multi-configuration reference wave functions---including such as obtained by the density matrix renormalization group (DMRG) with large…

Chemical Physics · Physics 2016-09-13 Sandeep Sharma , Gerald Knizia , Sheng Guo , Ali Alavi

A strategy to enhance d-wave superconducting correlations is proposed based on our numerical study for correlated electron models for high-Tc cuprates. We observe that the pairing is enhanced when the single-electron level around (pi,0) is…

Superconductivity · Physics 2009-10-31 Hirokazu Tsunetsugu , Masatoshi Imada

An efficient perturbational treatment of spin-orbit coupling within the framework of high-level multi-reference techniques has been implemented in the most recent version of the COLUMBUS quantum chemistry package, extending the existing…

Valence energies for crystalline C, Si, Ge, and Sn with diamond structure have been determined using an ab-initio approach based on information from cluster calculations. Correlation contributions, in particular, have been evaluated in the…

Condensed Matter · Physics 2016-08-31 Beate Paulus , Peter Fulde , Hermann Stoll

We introduce a novel many body method which combines two powerful many body techniques, viz., quantum Monte Carlo and coupled cluster theory. Coupled cluster wave functions are introduced as importance functions in a Monte Carlo method…

Nuclear Theory · Physics 2013-12-04 Alessandro Roggero , Abhishek Mukherjee , Francesco Pederiva

We present a realistic study for electronic and magnetic properties in dilute magnetic semiconductor (Ga,Mn)As. A multi-orbital Haldane-Anderson model parameterized by density-functional calculations is presented and solved with the…

A relativistic version of the coupled-cluster single-double (CCSD) method is developed for atoms with a single valence electron. In earlier work, a linearized version of the CCSD method (with extensions to include a dominant class of triple…

Atomic Physics · Physics 2009-11-13 Rupsi Pal , M. S. Safronova , W. R. Johnson , Andrei Derevianko , Sergey G. Porsev

In this work we present a coupled-cluster theory for the propagation of multireference electronic systems initiating at general quantum mechanical states. Our formalism is based on the infinitesimal analysis of modified cluster operators,…

Chemical Physics · Physics 2025-05-09 Martín A. Mosquera

Correlations derived through single-particle approximations of the many-body problem frequently result in erroneously inflated or diminished physical properties. In the context of transition metals, the impact of correlations can be…

Materials Science · Physics 2025-08-05 Jacques R. Eone

Point defects are of interest for many applications, from quantum sensing to modifying bulk properties of materials. Because of their localized orbitals, the electronic states are often strongly correlated, which has led to a proliferation…

Strongly Correlated Electrons · Physics 2025-05-05 Kevin G. Kleiner , Sonali Joshi , Woncheol Lee , Alexander Hampel , Malte Rösner , Cyrus E. Dreyer , Lucas K. Wagner

A system of patchy colloidal particles interacting with a solute that can associate multiple times in any direction is a useful model for patchy colloidal mixtures. Despite the simplicity of the interaction, because of the presence of…

Soft Condensed Matter · Physics 2016-01-19 Artee Bansal , D. Asthagiri , K. R. Cox , Walter G. Chapman

Motivated by the recent discovery of superconductivity in square-planar nickelates as well as by longstanding puzzling experiments in heavy-fermion superconductors, we study Cooper pairing between correlated $d$-electrons coupled to a band…

Superconductivity · Physics 2021-01-04 Emilian M. Nica , Onur Erten

We investigate in detail antiferromagnetic (AF) and superconducting (SC) phases as well as their coexistence in the two-dimensional Kondo lattice model on a square lattice, which is a paradigmatic model for heavy fermion materials. The…

Strongly Correlated Electrons · Physics 2017-10-17 Benjamin Lenz , Riccardo Gezzi , Salvatore R. Manmana

Quantum Monte Carlo method is used to re-examine superconductivity in the single-band Hubbard model in two dimensions. Instead of the conventional pairing, we consider a `correlated pairing', $\langle \tilde{c}_{i\uparrow}…

Condensed Matter · Physics 2009-10-28 Kazuhiko Kuroki , Hideo Aoki , Takashi Hotta , Yasutami Takada

The spin-half XXZ model on the linear chain and the square lattice are examined with the extended coupled cluster method (ECCM) of quantum many-body theory. We are able to describe both the Ising-Heisenberg phase and the XY-Heisenberg…

Condensed Matter · Physics 2016-08-31 J. Rosenfeld , N. E. Ligterink , R. F. Bishop

This work present a new class of variational wave functions for fermi systems in any dimension. These wave functions introduce correlations between Cooper pairs in different momentum states and the relevant correlations can be computed…

Superconductivity · Physics 2009-10-31 B Sriram Shastry

Many-electron correlation methods offer a systematic approach to predicting material properties with high precision. However, practically attaining accurate ground-state properties for bulk metals presents significant challenges. In this…

Materials Science · Physics 2025-01-07 Tobias Schäfer

Wave functions based on electron-pair states provide inexpensive and reliable models to describe quantum many-body problems containing strongly-correlated electrons, given that broken-pair states have been appropriately accounted for by,…

Chemical Physics · Physics 2021-03-17 Artur Nowak , Ors Legeza , Katharina Boguslawski

A systematic method for determining correlated wavefunctions of extended systems in the ground and excited states is presented. It allows to fully exploit the power of quantum-chemical programs designed for correlation calculations of…

Other Condensed Matter · Physics 2007-05-23 V. Bezugly

We perform a systematic quantum Monte Carlo study of the pairing correlation in the $S_4$ symmetric microscopic model for iron-based superconductors. It is found that the pairing with an extensive s-wave symmetry robustly dominates over…

Strongly Correlated Electrons · Physics 2013-03-07 Tianxing Ma , Hai-Qing Lin , Jiangping Hu