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The directed self-assembly of colloidal nanoparticles (NPs) using external fields guides the formation of sophisticated hierarchical materials but becomes less effective with decreasing particle size. As an alternative, electron-beam-driven…

Soft Condensed Matter · Physics 2024-09-13 Jonathan G. Raybin , Ethan J. Dunsworth , Veronica Guo , Naomi S. Ginsberg

Nanoporous media exhibit structures significantly smaller than the wavelengths of visible light and can thus act as photonic metamaterials. Their optical functionality is not determined by the properties of the base materials, but rather by…

We describe a soft matter system of self-organized oblate micelles and plasmonic gold nanorods that exhibit a negative orientational order parameter. Because of anisotropic surface anchoring interactions, colloidal gold nanorods tend to…

Soft Condensed Matter · Physics 2016-12-30 Qingkun Liu , Bohdan Senyuk , Jianwei Tang , Taewoo Lee , Jun Qian , Sailing He , Ivan I. Smalyukh

We review theoretical explanation of mechanisms of control of uniformity in growth of nanosize particles and colloids. The nanoparticles are synthesized as nanocrystals, by burst nucleation from solution. The colloids are self-assembled by…

Statistical Mechanics · Physics 2010-09-22 Vladimir Privman

Realizing tunable functional materials with built-in nanoscale heat flow directionality represents a significant challenge that could advance thermal management strategies. Here we use spatiotemporally-resolved thermoreflectance to…

We present modeling approaches to explain mechanisms of control of uniformity (narrow distribution) of sizes and shapes in synthesis of nanosize crystals and micron-size colloids. We consider those situations when the nanocrystals are…

Soft Condensed Matter · Physics 2010-11-29 Vyacheslav Gorshkov , Vladimir Privman

Based on Monte Carlo (MC) computer simulations we study the structure formation of a system of magnetic nanorods. Our model particles consist of fused spheres with permanent magnetic dipole moments, as inspired by recent experiments. The…

Soft Condensed Matter · Physics 2012-03-22 Carlos E. Alvarez , Sabine H. L. Klapp

Nanocrystals (NCs) serve as versatile building blocks for the creation of functional materials, with NC self-assembly offering opportunities to enable novel material properties. Here, we demonstrate that PbS NCs functionalized with strongly…

The process of colloidal drying gives way to particle self-assembly in numerous elds including photonics or biotechnology. Yet, the mechanisms and conditions driving the nal particle arrangement in dry colloidal layers remain elusive. Here,…

Hierarchical self-assembly arranges nanostructures at different length scales. It gradually becomes an effective method of fabricating artificial metamaterials from composite nanostructures tailored for a particular response. Hierarchical…

An optimal control strategy is developed to construct nanostructures of desired geometry along line segments by means of directed self-assembly of charged particles. Such a control strategy determines the electric potentials of a set of…

Dynamical Systems · Mathematics 2016-03-02 Arash Komaee , Paul I. Barton

In metal nanoparticles (NPs) supracrystals, the metallic core provides some key properties, e.g. magnetization, plasmonic response or conductivity, with the ligand molecules giving rise to others like solubility, assembly or interaction…

Monodispersed magnetite (Fe3O4) nanoparticles were synthesized. Transmission electron microscopy study shows that the nanoparticles are in the shape of Wagner-Seitz crystals. The magnetite nanoparticles self-assemble into body-centered…

Materials Science · Physics 2007-05-23 R. K. Zheng , Hongwei Gu , Bing Xu , K. K. Fung , X. X. Zhang

Self-assembly processes allow us to design and create complex nanostructures using molecules as building blocks and surfaces as scaffolds. This autonomous driven construction is possible due to a complex thermodynamic balance of…

Mesoscale and Nanoscale Physics · Physics 2017-09-06 Sabrina Simoncelli , Yi Li , Emiliano Cortés , Stefan A. Maier

The ordering of nanoparticles into predetermined configurations is of importance to the design of advanced technologies. In this work, we moderate the surface anchoring against the bulk elasticity of liquid crystals to dynamically shape…

Soft Condensed Matter · Physics 2023-12-01 Lisa Tran , Hye-Na Kim , Ningwei Li , Shu Yang , Kathleen J. Stebe , Randall D. Kamien , Martin F. Haase

We investigate the self-assembly of two-dimensional dodecagonal quasicrystals driven by cyclic shear, effectively replacing thermal fluctuations with plastic rearrangements. Using particles interacting via a smoothed square-shoulder…

Soft Condensed Matter · Physics 2026-03-30 Raphaël Maire , Andrea Plati , Frank Smallenburg , Giuseppe Foffi

Nanoparticle self-assembly is an efficient bottom-up strategy for the creation of nanostructures. In the standard approach, ligands are grafted on the surfaces of nanoparticles to keep them separated and control interparticle interactions.…

Solution-phase bottom up self-assembly of nanocrystals into superstructures such as ordered superlattices is an attractive strategy to generate functional materials of increasing complexity, including very recent advances that incorporate…

Self-assembled dendronized CdS nanoparticles have been attracting considerable attention because of their photoluminescence properties depending on annealing treatments. In this study, their annealing-induced self-assembled structure was…

The assembly of nanometer-sized building blocks into complex morphologies is not only of fundamental interest but also plays a key role in material science and nanotechnology. We show that the shape of self-assembled superstructures formed…

Soft Condensed Matter · Physics 2020-05-08 Baeckkyoung Sung , Rik Wensink , Eric Grelet