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We report a detailed theoretical study of the structural, vibrational, and optical properties of solid nitromethane using first principles density functional calculations. The ground state properties were calculated using a plane wave…

Materials Science · Physics 2015-06-17 S. Appalakondaiah , G. Vaitheeswaran , S. Lebegue

Structural stability and vibrational properties of KN$_3$ have been studied under pressure using the first principles calculations based on the density functional theory (DFT) as well as with semi empirical dispersion correction to the DFT…

Materials Science · Physics 2013-11-08 K. Ramesh Babu , G. Vaitheeswaran

We have performed {\it ab initio} calculations for a series of energetic solids to explore their structural and electronic properties. To evaluate the ground state volume of these molecular solids, different dispersion correction methods…

Materials Science · Physics 2015-09-29 S. Appalakondaiah , G. Vaitheeswaran , S. Lebègue

In this work, we study structural and vibrational properties of multilayer graphene using density-functional theory (DFT) with van der Waals (vdW) functionals. Initially, we analyze how different vdW functionals compare by evaluating the…

Mesoscale and Nanoscale Physics · Physics 2019-11-05 Rafael R. Del Grande , Marcos G. Menezes , Rodrigo B. Capaz

Understanding the fundamental processes of light-matter interaction is important for detection of explosives and other energetic materials, which are active in the infrared and terahertz (THz) region. We report a comprehensive study on…

The structural, dynamical, and thermodynamical properties of diamond, graphite and layered derivatives (graphene, rhombohedral graphite) are computed using a combination of density-functional theory (DFT) total-energy calculations and…

Materials Science · Physics 2009-11-10 Nicolas Mounet , Nicola Marzari

This study explores the pressure evolution of the double perovskite Ba$_2$NiTeO$_6$ by employing experimental and computational techniques. For the study of structural and vibrational properties, synchrotron X-ray diffraction (XRD) and…

We report a density-functional theory study of the structural and electronic properties of Cd2V2O7 under high-pressure conditions. The calculations have been performed by using first-principle calculations with the CRYSTAL program. The…

Materials Science · Physics 2022-05-23 Daniel Diaz-Anichtchenko , Daniel Errandonea

Intralayer deformation in van der Waals (vdW) heterostructures is generally assumed to be negligible due to the weak nature of the interactions between the layers, especially when the interfaces are found incoherent. In the present work,…

Materials Science · Physics 2018-07-18 Benoit Van Troeye , Aurélien Lherbier , Jean-Christophe Charlier , Xavier Gonze

We have investigated the structure of cyclohexene-2-ethanamine molecule both theoretically and experimantally. Theoretical investigation is based on a first principle technique Density Functional Theory (DFT) using plane wave basis sets and…

Materials Science · Physics 2009-11-13 T. Izgi , E. Akturk , O. Gulseren , M. Senyel

We present a multi-scale density functional theory (DFT) informed molecular dynamics and tight-binding (TB) approach to capture the interdependent atomic and electronic structures of twisted bilayer graphene. We calibrate the flat band…

Mesoscale and Nanoscale Physics · Physics 2022-03-17 Nicolas Leconte , Srivani Javvaji , Jiaqi An , Appalakondaiah Samudrala , Jeil Jung

The structural and vibrational properties of phenanthrene are measured at high pressures up to 30.2 GPa by Raman spectroscopy and synchrotron x-ray diffraction techniques. Two phase transitions are observed in raman spectra under pressures…

This paper reviews the theoretical work undertaken using density functional theory (DFT) to explore graphene's interactions with its surroundings. We look at the impact of substrates, gate dielectrics and edge effects on the properties of…

Mesoscale and Nanoscale Physics · Physics 2012-07-31 Priyamvada Jadaun , Bhagawan R. Sahu , Leonard F. Register , Sanjay K. Banerjee

We obtain the quasiparticle band structure of ABA and ABC-stacked graphene trilayers through ab initio density functional theory (DFT) and many-body quasiparticle calculations within the GW approximation. To interpret our results, we fit…

Mesoscale and Nanoscale Physics · Physics 2014-02-10 Marcos G. Menezes , Rodrigo B. Capaz , Steven G. Louie

First-principles density functional theory (DFT) calculations of Lu-H-N compounds reveal low-energy configurations of Fm$\overline{3}$m Lu$_{8}$H$_{23-x}$N structures that exhibit novel electronic properties such as flat bands, sharply…

Materials Science · Physics 2024-02-27 Adam Denchfield , Hyowon Park , Russell J. Hemley

We analyze the vibrational properties of diamondoid compounds via Raman spectroscopy. The compounds are interconnected with carbon-carbon single bonds that exhibit exceptionally large bond lengths up to 1.71 A. Attractive dispersion…

We investigate the equation of states of the $\beta$-polymorph of cyclotetramethylene tetranitramine (HMX) energetic molecular crystal using DFT-D2, a first-principles calculation based on density functional theory (DFT) with van der Waals…

Materials Science · Physics 2014-11-07 Qing Peng , Suvranu De

Effects of the structural distortion associated with the $\rm OsO_6$ octahedral rotation and tilting on the electronic band structure and magnetic anisotropy energy for the $5d^3$ compound NaOsO$_3$ are investigated using the density…

Strongly Correlated Electrons · Physics 2018-05-02 Shubhajyoti Mohapatra , Churna Bhandari , Sashi Satpathy , Avinash Singh

Equilibrium polyethylene crystal structure, cohesive energy, and elastic constants are calculated by density-functional theory applied with a recently proposed density functional (vdW-DF) for general geometries [Phys. Rev. Lett. 92, 246401…

Materials Science · Physics 2009-11-11 Jesper Kleis , Bengt I. Lundqvist , David C. Langreth , Elsebeth Schroder

We study the structural and vibrational properties of the high-temperature superconducting sulfur trihydride and trideuteride in the high-pressure $Im\bar{3}m$ and $R3m$ phases by first-principles density-functional-theory calculations. On…

Materials Science · Physics 2018-06-13 Raffaello Bianco , Ion Errea , Matteo Calandra , Francesco Mauri
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