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In this report, we present Raman spectroscopy investigation of the thermal stability and dynamics of graphene edges. It was found that graphene edges (both armchair and zigzag) are not stable and undergo modifications even at temperature as…

Materials Science · Physics 2010-12-15 Ya Nan Xu , Da Zhan , Lei Liu , Hui Suo , Zhen Hua Ni , Thuong Thuong Nguyen , Chun Zhao , Ze Xiang Shen

Terrace-sized, single-orientation graphene can be grown on top of a carbon buffer layer on silicon carbide by thermal decomposition. Despite its homogeneous appearance, a surprisingly large variation in electron transport properties is…

Mesoscale and Nanoscale Physics · Physics 2023-03-21 Tobias A. de Jong , Luuk Visser , Johannes Jobst , Ruud M. Tromp , Sense Jan van der Molen

Raman spectroscopy, a fast and nondestructive imaging method, can be used to monitor the doping level in graphene devices. We fabricated chemical vapor deposition (CVD) grown graphene on atomically flat hexagonal boron nitride (hBN) flakes…

Materials Science · Physics 2013-12-09 Kanokporn Chattrakun , Shengqiang Huang , K. Watanabe , T. Taniguchi , A. Sandhu , B. J. LeRoy

The optical conductivities of graphene layers are strongly dependent on their stacking orders. Our first-principle calculations show that while the optical conductivities of single layer graphene (SLG) and bilayer graphene (BLG) with Bernal…

Materials Science · Physics 2010-11-04 Yingying Wang , Zhenhua Ni , Lei Liu , Yanhong Liu , Chunxiao Cong , Ting Yu , Xiaojun Wang , Dezhen Shen , Zexiang Shen

We have studied the phonon specific heat in single-layer, bilayer and twisted bilayer graphene. The calculations were performed using the Born-von Karman model of lattice dynamics for intralayer atomic interactions and spherically symmetric…

Materials Science · Physics 2015-06-19 Denis L. Nika , Alexandr I. Cocemasov , Alexander A. Balandin

Graphene layers placed on SrTiO3 single-crystal substrates were investigated using temperature-dependent confocal Raman spectroscopy. This approach successfully resolved distinct Raman modes of graphene that are often untraceable in…

Materials Science · Physics 2022-09-22 S. Shrestha , C. S. Chang , S. Lee , N. L. Kothalawala , D. Y. Kim , M. Minola , J. Kim , A. Seo

Graphene, as an atomic-thick ultrasoft membrane, almost has no resistance against out-of-plane deformations and, therefore, it is always wrinkled to a certain degree. Recently, corrugated structures and their effects on the electronic…

Mesoscale and Nanoscale Physics · Physics 2016-09-13 Si-Yu Li , Hua Jiang , Jiao-Jiao Zhou , Haiwen Liu , Fan Zhang , Lin He

The crystal structure of solid-state matter greatly affects its electronic properties. For example in multilayer graphene, precise knowledge of the lateral layer arrangement is crucial, since the most stable configurations, Bernal and…

The crystallographic stacking order in multilayer graphene plays an important role in determining its electronic structure. In trilayer graphene, rhombohedral stacking (ABC) is particularly intriguing, exhibiting a flat band with an…

Materials Science · Physics 2017-06-12 Changhua Bao , Wei Yao , Eryin Wang , Chaoyu Chen , José Avila , Maria C. Asensio , Shuyun Zhou

The scattering of lattice excitations (phonons) with the photoexcited charge carriers is of a major concern in optoelectronic devices. Here, the resonant Raman scattering will be utilized to study an exciton-phonon interaction in GaN…

The mechanical response of embedded ABA trilayer graphene flakes loaded in tension and compression on polymer beams is monitored by simultaneous Raman measurements through the strain sensitivity of the G or 2D peaks. A characteristic…

Materials Science · Physics 2016-07-19 G. Tsoukleri , J. Parthenios , C. Galiotis , K. Papagelis

Experiments on bilayer graphene unveiled a fascinating realization of stacking disorder where triangular domains with well-defined Bernal stacking are delimited by a hexagonal network of strain solitons. Here we show by means of numerical…

Mesoscale and Nanoscale Physics · Physics 2018-04-13 Fernando Gargiulo , Oleg V. Yazyev

Direct, tunable coupling between individually assembled graphene layers is a next step towards designer two-dimensional (2D) crystal systems, with relevance for fundamental studies and technological applications. Here we describe the…

The symmetry group analysis is applied to classify the phonon modes of $N$-stacked graphene layers (NSGL's) with AB- and AA-stacking, particularly their infra-red and Raman properties. The dispersions of various phonon modes are calculated…

Materials Science · Physics 2008-06-30 Jin-Wu Jiang , Hui Tang , Bing-Shen Wang , Zhao-Bin Su

We present an analysis of deep-UV Raman measurements of graphite, graphene and carbon nanotubes. For excitation energies above the strong optical absorption peak at the $M$ point in the Brillouin zone ($\approx 4.7\,\text{eV}$), we…

Materials Science · Physics 2015-08-03 Christoph Tyborski , Felix Herziger , Roland Gillen , Janina Maultzsch

For two decades, two-dimensional carbon species, including graphene, have been the core of research in pursuing next-generation logic applications beyond the silicon technology. Yet the opening of a gap in a controllable range of doping,…

Electronic properties of bilayer and multilayer graphene have generally been interpreted in terms of AB or Bernal stacking. However, it is known that many types of stacking defects can occur in natural and synthetic graphite; rotation of…

Materials Science · Physics 2011-11-09 J. M. B. Lopes dos Santos , N. M. R. Peres , A. H. Castro Neto

We investigated Raman spectra of single-layer and multi-layer graphene under ultraviolet laser excitation at the wavelength of 325 nm. It was found that while the G peak of graphene remains pronounced in UV Raman spectra, the 2D band…

Materials Science · Physics 2015-05-13 Irene Calizo , Igor Bejenari , Muhammad Rahman , Guanxiong Liu , Alexander A. Balandin

We probe electronic excitations between Landau levels in freestanding $N-$layer graphene over a broad energy range, with unprecedented spectral and spatial resolution, using micro-magneto Raman scattering spectroscopy. A characteristic…

Mesoscale and Nanoscale Physics · Physics 2014-10-03 Stéphane Berciaud , Marek Potemski , Clément Faugeras

Under homogeneous uniaxial strains, the Raman 2D band of graphene involving two-phonon double-resonance scattering processes splits into two peaks and they altogether redshift strongly depending on the direction and magnitude of the strain.…

Mesoscale and Nanoscale Physics · Physics 2015-03-19 Duhee Yoon , Young-Woo Son , Hyeonsik Cheong