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Correct defect quantification in graphene samples is crucial both for fundamental and applied re-search. Raman spectroscopy represents the most widely used tool to identify defects in graphene. However, despite its extreme importance the…

Materials Science · Physics 2021-07-22 Sara D. Costa , Johan Ek Weis , Otakar Frank , Martin Kalbac

The most important bands for the evaluation of strain in graphene (the 2D and 2D prime modes) are investigated. It is shown that for Bernal-stacked bilayers, the two-phonon Raman features have three different components that can be assigned…

Materials Science · Physics 2021-07-27 Sara D Costa , Johan Ek Weis , Otakar Frank , Michaela Fridrichová , Martin Kalbac

We present the first Raman spectroscopic study of Bernal bilayer graphene flakes under uniaxial tension. Apart from a purely mechanical behavior in flake regions where both layers are strained evenly, certain effects stem from inhomogeneous…

Graphene has many unique properties that make it an ideal material for fundamental studies as well as for potential applications. Here we review the recent results on the Raman spectroscopy and imaging of graphene. Raman spectroscopy and…

Materials Science · Physics 2008-10-17 Zhen hua Ni , Ying ying Wang , Ting Yu , Ze xiang Shen

The Raman shift, broadening, and relative Raman intensities of bilayer graphene are computed as functions of the electron concentration. We include dynamic effects for the phonon frequencies and we consider the gap induced in the band…

Materials Science · Physics 2009-09-11 Paola Gava , Michele Lazzeri , A. Marco Saitta , Francesco Mauri

The electronic structure of bilayer graphene is investigated from a resonant Raman study using different laser excitation energies. The values of the parameters of the Slonczewski-Weiss-McClure model for graphite are measured experimentally…

Materials Science · Physics 2009-11-13 L. M. Malard , J. Nilsson , D. C. Elias , J. C. Brant , F. Plentz , E. S. Alves , A. H. Castro Neto , M. A. Pimenta

We compare the main feature of the measured Raman scattering spectra from single layer graphene with a bilayer in which the two layers are arbitrarily misoriented. The profiles of the 2D bands are very similar having only one component,…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Philippe Poncharal , Anthony Ayari , Thierry Michel , Jean-Louis Sauvajol

The stacking faults (deviates from Bernal) will break the translational symmetry of multilayer graphenes and modify their electronic and optical behaviors to the extent depending on the interlayer coupling strength. This paper addresses the…

Materials Science · Physics 2015-05-13 Zhenhua Ni , Lei Liu , Yingying Wang , Zhe Zheng , Lain-Jong Li , Ting Yu , Zexiang Shen

The in-plane optical phonons around 200 meV in few-layer graphene are investigated utilizing infrared absorption spectroscopy. The phonon spectra exhibit unusual asymmetric features characteristic of Fano resonances, which depend critically…

Mesoscale and Nanoscale Physics · Physics 2015-05-30 Zhiqiang Li , Chun Hung Lui , Emmanuele Cappelluti , Lara Benfatto , Kin Fai Mak , G. Larry Carr , Jie Shan , Tony F. Heinz

There has been a lot of excitement around the observation of superconductivity in twisted bilayer graphene, associated to flat bands close to the Fermi level. Such correlated electronic states also occur in multilayer rhombohedral stacked…

Materials Science · Physics 2021-02-26 Jean Paul Nery , Matteo Calandra , Francesco Mauri

Graphene and few-layer graphene at high bias expose a wealth of phenomena due to the high temperatures reached. With in-situ transmission electron microscopy (TEM) we observe directly how the current modifies the structure, and vice versa.…

Mesoscale and Nanoscale Physics · Physics 2013-01-30 Amelia Barreiro , Felix Boerrnert , Mark H. Ruemmeli , Bernd Buechner , Lieven M. K. Vandersypen

Graphite occurs in a range of metastable stacking orders characterized by both the number and direction of shifts between adjacent layers by the length of a single carbon-carbon bond. At the extremes are Bernal (or ``ABAB...'') stacking,…

We present a mainly analytical study of the entanglement spectrum of Bernal-stacked graphene bilayers in the presence of trigonal warping in the energy spectrum. Upon tracing out one layer, the entanglement spectrum shows qualitative…

Mesoscale and Nanoscale Physics · Physics 2016-03-07 Sonja Predin , Paul Wenk , John Schliemann

We describe Raman spectroscopy based method of measuring thermal conductivity of thin films, and review significant results achieved with this technique pertinent to graphene and other two-dimensional materials. The optothermal Raman method…

Mesoscale and Nanoscale Physics · Physics 2019-03-18 Hoda Malekpour , Alexander A. Balandin

Stackings in graphene have a pivotal role in properties to be discussed in the future, as seen in the recently found superconductivity of twisted bilayer graphene. Beyond bilayer graphene, the stacking order of multilayer graphene can be…

Mesoscale and Nanoscale Physics · Physics 2022-12-12 Raúl Guerrero-Avilés , Marta Pelc , Fabian Geisenhof , Thomas Weitz , Andrés Ayuela

Raman spectroscopy of graphene is reviewed from a theoretical perspective. After an introduction of the building blocks (electronic band structure, phonon dispersion, electron-phonon interaction, electron-light coupling), Raman intensities…

Mesoscale and Nanoscale Physics · Physics 2017-03-23 Sven Reichardt , Ludger Wirtz

We examine the quantum Hall effect in bilayer graphene grown on Cu substrates by chemical vapor deposition. Spatially resolved Raman spectroscopy suggests a mixture of Bernal (A-B) stacked and rotationally faulted (twisted) domains.…

Mesoscale and Nanoscale Physics · Physics 2012-05-21 Babak Fallahazad , Yufeng Hao , Kayoung Lee , Seyoung Kim , R. S. Ruoff , E. Tutuc

Two-dimensional (2D) materials have attracted significant interest due to their tunable physical properties when stacked into homo- and hetero-structures. Twisting adjacent layers introduces moir\'{e} patterns that strongly influence the…

In this work we study the behavior of the optical phonon modes in bilayer graphene devices by applying top gate voltage, using Raman scattering. We observe the splitting of the Raman G band as we tune the Fermi level of the sample, which is…

Mesoscale and Nanoscale Physics · Physics 2012-06-07 D. L. Mafra , P. Gava , L. M. Malard , R. S. Borges , G. G. Silva , J. A. Leon , F. Plentz , F. Mauri , M. A. Pimenta

Detection of infrared light is central to diverse applications in security, medicine, astronomy, materials science, and biology. Often different materials and detection mechanisms are employed to optimize performance in different spectral…

Mesoscale and Nanoscale Physics · Physics 2012-07-03 J. Yan , M. -H. Kim , J. A. Elle , A. B. Sushkov , G. S. Jenkins , H. M. Milchberg , M. S. Fuhrer , H. D. Drew
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