Related papers: Simple Molecules and Clocks
Single molecules are nanoscale thermodynamic systems with few degrees of freedom. Thus, the knowledge of their entropy can reveal the presence of microscopic electron transfer dynamics, that are difficult to observe otherwise. Here, we…
The frequency comb created by a femtosecond mode-locked laser and a microstructured fiber is used to phase coherently measure the frequencies of both the Hg^+ and Ca optical standards with respect to the SI second as realized at NIST. We…
We compute an approximate set of longitudinal quasiparticle modes for a hydrogen condensate as produced in the MIT experiments. An expansion in quasiparticles using a simple one-dimensional Bogoliubov picture shows however that at the high…
The possibility of an atomic detection of gravitational waves on earth is considered. The combination of extremely high lifetimes and resulting small radiative transition probabilities with rapidly growing interaction strength for Rydberg…
We suggest universal expressions for the rates of charge transition between molecules in organic disordered semiconductors, which differ between electrons and holes. The donor and acceptor molecules (monomers) are represented in terms of…
Collisions with background gas can perturb the transition frequency of trapped ions in an optical atomic clock. We develop a non-perturbative framework based on a quantum channel description of the scattering process, and use it to derive a…
We have performed calculations of the size of the frequency shift induced by a static electric field on the clock transition frequencies of the hyperfine splitting in Yb+, Rb, Cs, Ba+, and Hg+. The calculations are used to find the…
We demonstrate the measurement and manipulation of the temperature of cold CO molecules in a microchip environment. Through the use of time-resolved spatial imaging, we are able to observe the phase-space distribution of the molecules, and…
We use quantum-logic spectroscopy (QLS) and interrogate rotational transitions of a single CaH+ ion with a highly coherent frequency comb, achieving a fractional statistical uncertainty for a transition line center of 4 x 10^-13. We also…
We investigate the leading systematic effects in ro-vibrational spectroscopy of the molecular hydrogen ions H2+ and HD+, in order to assess their potential for the realization of optical clocks that would be sensitive to possible variations…
An electronically variational approach to the calculation of atomic hyperfine structure transition energies under the influence of static external electric fields is presented. The method avoids the calculation of intermediate atomic states…
We demonstrate agreement between measurements and ab initio calculations of the frequency shifts caused by distributed cavity phase variations in the microwave cavity of a primary atomic fountain clock. Experimental verification of the…
The measurement of extremely small displacements is of utmost importance, both for fundamental studies [1-4], and practical applications [5-7]. One way to estimate a small displacement is to measure the Doppler shift generated in light…
We present absolute frequency measurement of the unperturbed P7 P7 O$_2$ B-band transition with relative standard uncertainty of $2\times10^{-11}$. We reached the level of accuracy typical for Doppler-free techniques, with Doppler-limited…
Our study is motivated by the prospect of several metastable states in the Sb$ ^{+} $, Au$ ^{+} $, and Hg$ ^{2+} $ ions being used as possible candidates for optical clocks. We calculate several atomic properties relevant to the development…
The frequencies of transitions between hyperfine levels of ground-state atoms can be measured with exquisite precision using magnetic-resonance techniques. This makes hyperfine transitions ideal probes of QED effects originating from the…
Demands from several areas of science and technology have lead to a worldwide search for accurate optical clocks with an uncertainty of 1 part in $10^{18}$, which is $10^{3}$ times more accurate than the present day cesium atomic clocks…
Optical clocks with unprecedented accuracy of 10^(-18) will lead to innovations in many research areas. All the applications of optical clocks rely on the ability of precisely converting the frequency from one optical clock to another, or…
We use the relativistic Hartree-Fock method, many-body perturbation theory and configuration-interaction method to calculate the dependence of atomic transition frequencies on the fine structure constant, alpha. The results of these…
We derive formulae connecting the frequency variations in the spectrum of solar oscillations to the dynamical quantities that are expected to change over the solar activity cycle. This is done for both centroids and the asymmetric part of…