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Predicting practical rates of ion transport from atomistic descriptors enables the rational design of materials, devices, and processes, which is especially critical to developing low-carbon energy technologies such as rechargeable…

In the conventional theory of hopping transport the positions of localized electronic states are assumed to be fixed, and thermal fluctuations of atoms enter the theory only through the notion of phonons. On the other hand, in 1D and 2D…

Disordered Systems and Neural Networks · Physics 2009-11-11 A. V. Plyukhin

Diffusion is a central phenomenon in almost all fields of natural science revealing microscopic processes from the observation of macroscopic dynamics. Here, we consider the paradigmatic system of a single atom diffusing in a periodic…

Atomic diffusion is usually understood as a succession of random, independent displacements of an adatom over the surface's potential energy landscape. Nevertheless, an analysis of Molecular Dynamics simulations of self-diffusion on Cu(111)…

Other Condensed Matter · Physics 2016-08-16 J. Ferrón , L. Gómez , J. J. de Miguel , R. Miranda

An exact analytical theory is developed for calculating the diffusion coefficient of charge carriers in strongly anisotropic disordered solids with one-dimensional hopping transport mode for any dependence of the hopping rates on space and…

Disordered Systems and Neural Networks · Physics 2012-01-10 A. V. Nenashev , F. Jansson , S. D. Baranovskii , R. Österbacka , A. V. Dvurechenskii , F. Gebhard

A non-equilibrium steady state can be characterized by a nonzero but stationary flux driven by a static external force. Under a weak external force, the drift velocity is difficult to detect because the drift motion is feeble and submerged…

Statistical Mechanics · Physics 2015-06-22 Rui Shi , Yanting Wang

In low temperature supercooled liquid, below the ideal mode coupling theory transition temperature, hopping and continuous diffusion are seen to coexist. We present a theory which incorporates interaction between the two processes and shows…

Statistical Mechanics · Physics 2008-07-08 Sarika Maitra Bhattacharyya , Biman Bagchi , Peter G. Wolynes

The coefficient of diffusion of hydrogen in crystalline silicon is calculated using tight-binding molecular dynamics. Our results are in good quantitative agreement with an earlier study by Panzarini and Colombo [Phys. Rev. Lett. 73, 1636…

Materials Science · Physics 2009-10-31 Sabrina Bedard , Laurent J. Lewis

Amorphous oxyhalides have attracted significant attention due to their relatively high ionic conductivity ($>$1 mS cm$^{-1}$), excellent chemical stability, mechanical softness, and facile synthesis routes via standard solid-state…

Materials Science · Physics 2026-01-13 Luca Binci , KyuJung Jun , Bowen Deng , Gerbrand Ceder

Dynamical systems having many coexisting attractors present interesting properties from both fundamental theoretical and modelling points of view. When such dynamics is under bounded random perturbations, the basins of attraction are no…

In the previous paper [Nenashev et al., arXiv:0912.3161] an analytical theory confirmed by numerical simulations has been developed for the field-dependent hopping diffusion coefficient D(F) in one-dimensional systems with Gaussian…

Disordered Systems and Neural Networks · Physics 2012-01-10 A. V. Nenashev , F. Jansson , S. D. Baranovskii , R. Österbacka , A. V. Dvurechenskii , F. Gebhard

Li containing transition metal oxides are known as good ionic conductors. Performing classical molecular dynamics simulations, the diffusion behavior of Li ions is investigated in crystalline and amorphous phases with the stoichiometries…

Materials Science · Physics 2025-01-29 Daniel Mutter , Diego A. Pantano , Christian Elsässer , Daniel F. Urban

We consider the propagation of a single particle in a random chain, assisted by the coupling to dispersive bosons. Time evolution treated with rate equations for hopping between localized states reveals a qualitative difference between…

Strongly Correlated Electrons · Physics 2018-10-04 P. Prelovsek , J. Bonca , M. Mierzejewski

Thermal transport in solids changes its nature from phonon propagation that suffers from perturbative scattering to thermally activated hops between localized vibrational modes as the level of disorder increases. Models have been proposed…

Materials Science · Physics 2015-08-13 Yanlei Wang , Zhigong Song , Zhiping Xu

The self-diffusion constant D is expressed in terms of transitions among the local minima of the potential (inherent structure, IS) and their correlations. The formulae are evaluated and tested against simulation in the supercooled,…

Statistical Mechanics · Physics 2009-10-31 T. Keyes , J. Chowdhary

Particles confined to a single file, in a narrow quasi-one dimensional channel, exhibit a dynamic crossover from single file diffusion to Fickian diffusion as the channel radius increases and the particles can begin to pass each other. The…

Soft Condensed Matter · Physics 2017-04-27 Sheida Ahmadi , Richard K. Bowles

Drag and diffusion of mobile ions in solids are of interest for both purely theoretical and applied scientific communities. This article proposes a theoretical description of ion drag in solids that can be used to estimate ionic…

Mesoscale and Nanoscale Physics · Physics 2022-06-24 Aleksandr Rodin , Keian Noori , Alexandra Carvalho , Antonio Helio Castro Neto

Ion conduction in noncrystals (glasses, polymers, etc) has a number of properties in common. In fact, from a purely phenomenological point of view, these properties are even more widely observed: ion conduction behaves much like electronic…

Disordered Systems and Neural Networks · Physics 2007-05-23 Jeppe C. Dyre , Thomas B. Schroeder

The low-field electron diffusion, noise, and the conduction in amorphous chalcogenides are investigated by means of a Monte Carlo implementation of a full three- dimensional variable-range hopping transport model between localized states.…

Materials Science · Physics 2012-03-05 Fabrizio Buscemi , Enrico Piccinini , Rossella Brunetti , Massimo Rudan , Carlo Jacoboni

We expand on a recent study of a lattice model of interacting particles [Phys. Rev. Lett. 111, 110601 (2013)]. The adsorption isotherm and equilibrium fluctuations in particle number are discussed as a function of the interaction. Their…

Statistical Mechanics · Physics 2014-11-20 T. Becker , K. Nelissen , B. Cleuren , B. Partoens , C. Van den Broeck
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