Related papers: Clausius vs. Boltzmann-Gibbs entropies
We study the behaviour of an ideal non-relativistic Bose gas in a three-dimensional space where one of the dimensions is compactified to form a circle. In this case there is no phase transition like that for the case of an infinite volume,…
A century ago, the foundations of equilibrium statistical mechanics were laid. For a system in equilibrium with a thermal bath, much is understood through the Boltzmann factor, exp{-H[C]/kT}, for the probability of finding the system in any…
Boltzmann introduced in the 1870's a logarithmic measure for the connection between the thermodynamical entropy and the probabilities of the microscopic configurations of the system. His entropic functional for classical systems was…
The physical impossibility of heat transfer under isothermal conditions implies that the classical expression for the entropy of the ideal gas may not be compatible with the internal energy of the gas itself. A corrected expression of the…
We consider a general lattice model of a finite protein in its environment and calculate its Boltzmann entropy SB(E) as a function of its energy E in a microcanonical ensemble, and Gibbs entropy SG(E) as a function of its average energy E…
We have investigated experimentally the finite-temperature properties of a Bose-Einstein condensed cloud of $^{87}$Rb atoms in a harmonic trap. Focusing primarily on condensed fraction and expansion energy, we measure unambiguous deviations…
We derive an exact recursion formula for the calculation of thermodynamic functions of finite systems obeying Bose-Einstein statistics. The formula is applicable for canonical systems where the particles can be treated as noninteracting in…
We develop a generalized theory of (meta)equilibrium statistical mechanics in the thermodynamic limit valid for both smooth and fractal phase spaces. In the former case, our approach leads naturally to Boltzmann-Gibbs standard…
Boltzmann's Principle S = k ln W was repeatedly criticized by Einstein since it lacked a proper dynamical foundation in view of the thermal motion of the particles, out of which a physical system consists. This suggests, in particular, that…
The realisation of Bose-Einstein condensation under grand-canonical conditions has provided the experimental evidence for the simultaneous occurrence of macroscopic fluctuations and phase coherence of the condensate. The observation of…
Steady nonequilibria dissipate energy and, when changing external parameters, an extra or excess heat accompanies the relaxation to the new nonequilibrium condition. For nonequilibrium systems in contact with a thermal bath, the heat…
In the weakly non-ideal gas model [1], the Bose-Einstein condensation at constant pressure is considered. The temperature of transition to the state with condensate is found. Temperature dependences of the total density and condensate…
The aim of this work is to analyze the entropy, entropy flux and entropy supply rate of granular fluids within the frameworks of the Boltzmann equation and continuum thermodynamics. It is shown that the entropy inequality for a granular gas…
Macroscopic nonextensive thermodynamics is studied without recourse to microscopic statistical mechanics. It is shown that if entropy is nonextensive, the concept of physical temperature introduced through the generalized zeroth law of…
We comment the recent manuscript by Vollmayr-Lee and Luijten [cond-mat/0009031] focusing on classical systems with nonintegrable interactions. The authors claim that they have proved that Boltzmann-Gibbs statistics suffices for describing…
Boltzmann's principle S(E,N,V...)=ln W(E,N,V...) allows the interpretation of Statistical Mechanics of a closed system as Pseudo-Riemannian geometry in the space of the conserved parameters E,N,V... (the conserved mechanical parameters in…
In this paper we present the construction of the equilibrium states at positive temperature in the presence of a condensation phase for a Gas of non relativistic Bose particles on an infinite space interacting through a localised two body…
This article presents a study of the grand canonical Bose-Einstein (BE) statistics for a finite number of particles in an arbitrary quantum system. The thermodynamical quantities that identify BE condensation -- namely, the fraction of…
The Boltzmann and Gibbs approaches to statistical mechanics have very different definitions of equilibrium and entropy. The problems associated with this are discussed and it is suggested that they can be resolved, to produce a version of…
We study the energy exchange between two bosonic systems that interact via bilinear transformations in the mode operators. The first mode is considered as the thermodynamic system, while the second is regarded as the bath. This work finds…