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Related papers: Water Purification by Shock Electrodialysis: Deion…

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Shock electrodialysis (shock ED), an emerging electrokinetic process for water purification, leverages the new physics of deionization shock waves in porous media. In previous work, a simple leaky membrane model with surface conduction can…

Fluid Dynamics · Physics 2021-03-16 Huanhuan Tian , Mohammad A. Alkhadra , Martin Z. Bazant

Shock electrodialysis is a recently developed electrochemical water treatment method which shows promise for water deionization and ionic separations. Although simple models and scaling laws have been proposed, a predictive theory has not…

Fluid Dynamics · Physics 2021-04-21 Sven Schlumpberger , Raymond B. Smith , Huanhuan Tian , Ali Mani , Martin Z. Bazant

Water desalination by capacitive deionization (CDI) is performed via electrochemical cells consisting of two porous carbon electrodes. Upon transferring charge from one electrode to the other, ions are removed from the feedwater by…

Materials Science · Physics 2015-06-15 P. M. Biesheuvel , M. E. Suss , H. V. M. Hamelers

Most electrochemical processes, such as electrodialysis, are limited by diffusion, but in porous media, surface conduction and electro-osmotic flow also contribute to ionic fluxes. In this paper, we report experimental evidence for…

Electro-sorption (ES) is a research frontier in electrochemical separation, with proven potential applications in desalination, wastewater treatment, and selective resource extraction. However, due to the limited adsorption capacity of film…

Chemical Physics · Physics 2024-03-19 Weifan Liu , Longqian Xu , Zezhou Yang , Xudong Zhang , Shihong Lin

Salt transport in bulk electrolytes is limited by diffusion and convection, but in microstructures with charged surfaces (e.g. microfluidic devices, porous media, soils, or biological tissues) surface conduction and electro-osmotic flow…

Fluid Dynamics · Physics 2015-05-30 Ali Mani , Martin Z. Bazant

Capacitive deionization (CDI) is a fast-emerging water desalination technology in which a small cell voltage of ~1 V across porous carbon electrodes removes salt from feedwaters via electrosorption. In flow-through electrode (FTE) CDI cell…

Computational Engineering, Finance, and Science · Computer Science 2017-02-01 Eric N. Guyes , Amit N. Shocron , Anastasia Simanovski , P. M. Biesheuvel , Matthew E. Suss

Over the past decade, capacitive deionization (CDI) has realized a surge in attention in the field of water desalination and can now be considered as an important technology class, along with reverse osmosis and electrodialysis. While many…

Due to the low conductivity of pure water, using an electrolyte is common for achieving efficient water electrolysis. In this paper, we have broken through this common sense by using deep-sub-Debye-length nanogap electrochemical cells for…

Chemical Physics · Physics 2016-11-16 Yifei Wang , S. R. Narayanan , Wei Wu

Many industrial and agricultural applications require the treatment of water streams containing high concentrations of ionic species for closing material cycles. High concentration factors are often desired, but hard to achieve with…

Water desalination through nanopores has been shown to be a promising alternative to the currently water purification processes. In spite the results in this direction obtained by means of computational simulations were animating there are…

Nanoplastics are emerging contaminants that have now transformed into a worldwide environmental concern. It is a lesser-known fact that several emerging contaminants, such as bisphenol and perfluoro alkylates adsorbing on micro and…

Chemical Physics · Physics 2023-02-17 Vishal Singh Pawak , Vijay A. Loganathan , Manigandan Sabapathy

In a circular channel passing over-limiting current (faster than diffusion), transient vortices of bulk electroconvection are observed in salt-depleted region within the horizontal plane. The spatiotemporal evolution of the salt…

Fluid Dynamics · Physics 2020-08-25 Zhibo Gu , Bingrui Xu , Peng Huo , Shmuel M. Rubinstein , Martin Z. Bazant , Daosheng Deng

Reverse osmosis (RO) and electrodialysis (ED) are the two most important membrane technologies for water desalination and treatment. Their modes of operation and transport mechanisms are very different, but on a closer look also have many…

Chemical Physics · Physics 2025-07-08 P. M. Biesheuvel , S. Porada , L. Wang , R. Wang , M. Elimelech , J. E. Dykstra

Using porous electrodes containing nickel hexacyanoferrate (NiHCF) nanoparticles, we construct and test a device for capacitive deionization in a two flow-channel device where the intercalation electrodes are in direct contact with an…

Chemical Physics · Physics 2020-03-27 S. Porada , A. Shrivastava , P. Bukowska , P. M. Biesheuvel , K. C. Smith

Capacitive deionization (CDI) is a fast-emerging technology most commonly applied to brackish water desalination. In CDI, salt ions are removed from the feedwater and stored in electric double layers (EDLs) within micropores of electrically…

Chemical Physics · Physics 2017-10-11 Matthew E. Suss

Water scarcity is a dilemma facing much of the global population. Cation intercalation desalination (CID) cells, which use intercalation host compounds (IHCs) in combination with ion-exchange membranes (IEMs), could aid in addressing this…

Chemical Physics · Physics 2016-12-28 Kyle C. Smith

Several harmful or valuable ionic species present in sea, brackish and wastewaters are amphoteric, and thus their properties depend on the local water pH. Effective removal of these species can be challenging by conventional membrane…

In this review, we discuss disruptive decoupled water splitting schemes, in which the concurrent production of hydrogen and oxygen in close proximity to each other in conventional electrolysis is replaced by time- or space-separated…

Applied Physics · Physics 2020-07-28 Avigail Landman , Gideon S. Grader , Avner Rothschild

Faradaic deionization (FDI) is a promising technology for energy-efficient water desalination using porous electrodes containing redox-active materials. Herein, we demonstrate for the first time the capability of a symmetric FDI flow cell…

Chemical Physics · Physics 2023-06-09 Vu Q. Do , Erik R. Reale , Irwin C. Loud , Paul G. Rozzi , Haosen Tan , David A. Willis , Kyle C. Smith
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