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A quantum electrodynamic calculation of the interaction of an excited-state atom with a ground-state atom is performed. For an excited reference state and a lower-lying virtual state, the contribution to the interaction energy naturally…

Quantum Physics · Physics 2017-05-19 U. D. Jentschura , V. Debierre

We investigate the influence of the appearance of excitonic states on van der Waals interactions among two Rydberg atoms. The atoms are assumed to be in different Rydberg states, e.g., in the $|ns\rangle$ and $|np\rangle$ states. The…

Atomic Physics · Physics 2015-08-12 Hashem Zoubi

We present a time-dependent quantum calculation of the van der Waals interaction between a pair of dissimilar atoms, one of which is initially excited while the other one is in its ground state. For small detuning, the interaction is…

Quantum Physics · Physics 2015-09-15 Manuel Donaire , Romain Guérout , Astrid Lambrecht

We calculate the van der Waals dispersive interaction between a neutral but polarizable atom and a perfectly conducting isolated sphere in the nonretarded case. We make use of two separate models, one being the semiclassical…

Quantum Physics · Physics 2009-03-13 M. M. Taddei , T. N. C. Mendes , C. Farina

In some respects, a cluster consisting of many atoms may be regarded as a single large atom. Knowing the dielectric properties of such a cluster permits one to evaluate the form of the van der Waals (dispersion) interactions between two…

Soft Condensed Matter · Physics 2009-11-07 M. M. Calbi , S. M. Gatica , D. Velegol , M. W. Cole

Using a recently obtained (general) formula for the interaction energy between an excited and a ground-state atom (Sherkunov Y 2007 Phys. Rev. A 75 012705), we consider the interaction energy between two such atoms near the interface…

Quantum Physics · Physics 2008-04-10 Marin-Slobodan Tomas

In this work we improve upon previous results on the expansion of the interaction energy of two atoms. On the one hand we prove the van der Waals-London's law, assuming that only one of the ground state eigenspaces of the atoms is…

Mathematical Physics · Physics 2019-02-19 Ioannis Anapolitanos , Mathieu Lewin , Matthias Roth

We compute the conservative van-der-Waals forces between two atoms, one of which is initially excited, in the limit of identical atoms. Starting with the perturbative calculation of the interaction between two dissimilar atoms, we show that…

Quantum Physics · Physics 2021-12-08 J. Sánchez-Cánovas , M. Donaire

We analyze van der Waals interactions between two rigid polymers with sequence-specific, anisotropic polarizabilities along the polymer backbones, so that the dipole moments fluctuate parallel to the polymer backbones. Assuming that each…

Soft Condensed Matter · Physics 2020-10-01 Bing-Sui Lu , Ali Naji , Rudolf Podgornik

We studied the van der Waals interactions of two finite, solid, cylindrical rods at arbitrary angle and position with respect to each other. An analytic interpolative formula for the interaction potential energy is constructed, based on…

Soft Condensed Matter · Physics 2018-10-03 Jack A. Logan , Alexei V. Tkachenko

The long-range electrostatic interactions between molecules depend strongly on their relative orientation, which manifests as a rotational state dependence. Interactions between molecules in the same rotational quantum state are well-known…

Atomic Physics · Physics 2024-05-16 Etienne F. Walraven , Tijs Karman

Van der Waals interactions, as a result of the exchange of photons between particles, can be altered by modifying the environment through which these photons propagate. As a consequence, phenomena such as the Rydberg blockade mechanism…

Atomic Physics · Physics 2018-01-03 Johannes Block , Stefan Scheel

The structure and stability of atomic and molecular systems with van der Waals (vdW) bonding are often determined by the interplay between attractive dispersion interactions and repulsive interactions caused by electron confinement. Arising…

Chemical Physics · Physics 2022-02-17 Ornella Vaccarelli , Dmitry V. Fedorov , Martin Stöhr , Alexandre Tkatchenko

We investigate the van der Waals interaction between neutrons using the theory of Casimir and Polder, wherein the potential for asymptotically large separations falls off as the inverse seventh power, and compare it to the similar…

Nuclear Theory · Physics 2016-04-01 James F. Babb , Mahir S. Hussein

The origin of a chemical reaction between two reactant atoms is associated to the activation energy, with the assumption that, high-energy collisions between these atoms, are the ones that overcome the activation energy. Here, we (i) show…

General Physics · Physics 2014-05-20 Andrew Das Arulsamy

We extend a method (E. Canc\`es and L.R. Scott, SIAM J. Math. Anal., 50, 2018, 381--410) to compute more terms in the asymptotic expansion of the van der Waals attraction between two hydrogen atoms. These terms are obtained by solving a set…

Mathematical Physics · Physics 2020-07-09 Éric Cancès , Rafaël Coyaud , L. Ridgway Scott

The classical and quantum aspects of planar Coulomb interactions have been studied in detail. In the classical scenario, Action Angle Variables are introduced to handle relativistic corrections, in the scheme of time-independent…

High Energy Physics - Theory · Physics 2009-10-30 Subir Ghosh

We consider the resonant van der Waals interaction between two correlated identical two-level atoms (at least one of which being excited) within the framework of macroscopic cavity quantum electrodynamics in linear, dispersing and absorbing…

Quantum Physics · Physics 2018-05-09 Saeideh Esfandiarpour , Robert Bennett , Hassan Safari , Stefan Yoshi Buhmann

We consider the the van der Waals force involving excited atoms in general environments, constituted by magnetodielectric bodies. We develop a dynamical approach studying the dynamics of the atoms and the field, mutually coupled. When only…

Quantum Physics · Physics 2017-02-24 Pablo Barcellona , Roberto Passante , Lucia Rizzuto , Stefan Yoshi Buhmann

The van der Waals dispersion interaction between two chiral molecules in the presence of arbirary magnetoelectric media is derived using perturbation theory. To be general, the molecular polarisabilities are assumed to be of electric,…

Quantum Physics · Physics 2020-06-24 Hassan Safari , Pablo Barcellona , Stefan Yoshi Buhmann , Akbar Salam