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We study the thermal diffusion coefficient DT of a charged colloid in a temperature gradient, and find that it is to a large extent determined by the thermoelectric response of the electrolyte solution. The thermally induced salinity…

Soft Condensed Matter · Physics 2014-01-30 Alois Würger

We propose a novel actuation mechanism for colloids, which is based on the Seebeck effect of the electrolyte solution: Laser heating of a nonionic particle accumulates in its vicinity a net charge Q, which is proportional to the excess…

Soft Condensed Matter · Physics 2014-01-30 Arghya Majee , Alois Würger

We report on the direct observation of the thermoelectric transport in a nondegenerate correlated electron system formed on the surface of liquid helium. We find that the microwave-induced excitation of the vertical transitions of electrons…

Other Condensed Matter · Physics 2021-11-10 Ivan Kostylev , A. A. Zadorozhko , M. Hatifi , Denis Konstantinov

The Seebeck effect describes the generation of an electric potential in a conducting solid exposed to a temperature gradient. Besides fundamental relevance in solid state physics, it serves as a key quantity to determine the performance of…

Dynamic processes in dispersions of charged spherical particles are of importance both in fundamental science, and in technical and bio-medical applications. There exists a large variety of charged-particles systems, ranging from…

Soft Condensed Matter · Physics 2013-11-25 G. Nägele , M. Heinen , A. J. Banchio , C. Contreras-Aburto

While thermoelectric transport theory is well established and widely applied, there remains some degree of confusion on the proper thermodynamic definition of the Seebeck coefficient (or thermoelectric power) which is a measure of the…

Materials Science · Physics 2016-04-05 Y. Apertet , H. Ouerdane , C. Goupil , Ph. Lecoeur

We discuss the peculiarities of the Seebeck effect in stabilized electrolytes containing the colloidal particles. Its unusual feature is the two-stage character, with the linear increase of differential thermopower as the function of…

Soft Condensed Matter · Physics 2021-02-24 Ioulia Chikina , Sawako Nakamae , Valeriy Shikin , Andrey Varlamov

We study the electrophoretic flow of suspensions of charged colloids with a mesoscopic method that allows to model generic experimental conditions. We show that for highly charged colloids their electrophoretic mobility increases…

Soft Condensed Matter · Physics 2015-05-28 Giovanni Giupponi , Ignacio Pagonabarraga

A systematic theoretical study of thermoelectric effect and temperature-gradient-driven electrokinetic flow of electrolyte solutions in charged nanocapillaries is presented. The study is based on a semianalytical model developed by…

Fluid Dynamics · Physics 2023-09-14 Wenyao Zhang , Qiuwang Wang , Min Zeng , Cunlu Zhao

Thermoelectric materials convert a temperature gradient into a voltage. This phenomenon is relatively well understood for inorganic materials, but much less so for organic semiconductors (OSs). These materials present a challenge because…

In this review article, we focus on collective motion in externally driven colloidal suspensions, as well as how these collective effects can be harnessed for use in microfluidic applications. We highlight the leading role of hydrodynamic…

Soft Condensed Matter · Physics 2018-11-01 Michelle Driscoll , Blaise Delmotte

We use a hydrodynamic reciprocal approach to phoretic motion to derive general expressions for the electrophoretic and thermophoretic mobility of weakly charged colloids in aqueous electrolyte solutions. Our approach shows that phoretic…

Soft Condensed Matter · Physics 2018-10-08 Jérôme Burelbach , Holger Stark

Thermally induced particle flow in a charged colloidal suspension is studied in a fluid-mechanical approach. The force density acting on the charged boundary layer is derived in detail. From Stokes' equation with no-slip boundary conditions…

Soft Condensed Matter · Physics 2014-01-31 S. Fayolle , T. Bickel , A. Würger

Electrostatic interactions play an important role in numerous self-assembly phenomena, including colloidal aggregation. Although colloids typically have a dielectric constant that differs from the surrounding solvent, the effective…

Soft Condensed Matter · Physics 2018-09-17 Kipton Barros , Erik Luijten

The Seebeck and Soret coefficients of ionically stabilized suspension of maghemite nanoparticles in dimethyl sulfoxide are experimentally studied as a function of nanoparticle volume fraction. In the presence of a temperature gradient, the…

The dominant modes of charge transport in variant polar liquid based nanoparticulate colloidal dispersions (dilute) have been theorized. Theories formulating electrical characteristics of colloids have often been found to over or under…

Soft Condensed Matter · Physics 2015-12-01 Purbarun Dhar , Arvind Pattamatta , Sarit K. Das

Research on conjugated polymers for thermoelectric applications has made tremendous progress in recent years, which is accompanied by surging interest in molecular doping as a means to achieve the high electrical conductivities that are…

Thermal gradients induce concentration gradients in alkali halide solutions, and the salt migrates towards hot or cold regions depending on the average temperature of the solution. This effect has been interpreted using the heat of…

Chemical Physics · Physics 2017-01-26 Silvia Di Lecce , Tim Albrecht , Fernando Bresme

We theoretically study the nonequilibrium thermoelectric transport properties of a strongly-correlated molecule (or quantum dot) embedded in a tunnel junction. Assuming that the coupling of the molecule to the contacts is asymmetric, we…

Mesoscale and Nanoscale Physics · Physics 2023-02-22 Anand Manaparambil , Ireneusz Weymann

We show that the huge Seebeck coefficients observed recently for ionic conductors, arise from a ratchet effect where activated jumps between neighbor sites are rectified by a temperature gradient, thus driving mobile ions towards the cold.…

Soft Condensed Matter · Physics 2021-02-17 Alois Würger
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