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We demonstrate optical cycling and sub-Doppler laser cooling of a cryogenic buffer-gas beam of calcium monohydride (CaH) molecules. We measure vibrational branching ratios for laser cooling transitions for both excited electronic states A…

Atomic Physics · Physics 2022-08-24 S. F. Vázquez-Carson , Q. Sun , J. Dai , D. Mitra , T. Zelevinsky

Quantum gases of ultracold polar molecules have novel properties because of the strong dipolar forces between molecules. Current experiments shield the molecules from destructive collisions by engineering long-range repulsive interactions…

Quantum Gases · Physics 2025-09-26 Bijit Mukherjee , Luis Santos , Jeremy M. Hutson

We demonstrate the Doppler laser cooling of $^{40}$Ca$^+$ ions confined in a segmented linear Paul trap in the presence of a strong quadrupolar magnetic field generated by two permanent ring magnets. Magnetic field gradients of 800 to 1600…

Atomic Physics · Physics 2023-09-08 Christian Mangeng , Yanning Yin , Richard Karl , Stefan Willitsch

We review recent progress in the field of cold trapped molecular ions. A new generation of collision and cold chemistry experiments between atoms and ions has emerged, where cold atoms and ions are brought into contact in a controlled way…

Atomic Physics · Physics 2024-08-28 Markus Deiß , Stefan Willitsch , Johannes Hecker Denschlag

The dicarbon molecular anion is currently of interest as a candidate for laser cooling due to its electronic structure and favorable branching ratios to the ground electronic and vibrational states. Helium has been proposed as a buffer gas…

We demonstrate rotational cooling of the silicon monoxide cation via optical pumping by a spectrally filtered broadband laser. Compared with diatomic hydrides, SiO\+ is more challenging to cool because of its smaller rotational interval.…

Studying chemical reactions at very low temperatures is of importance for the understanding of fundamental physical and chemical processes. At very low energies, collisions are dominated by only a few partial waves. Thus, studies in this…

Chemical Physics · Physics 2017-03-30 Dongdong Zhang , Stefan Willitsch

Laser cooling on weak transitions is a useful technique for reaching ultracold temperatures in atoms with multiple valence electrons. However, for strongly magnetic atoms a conventional narrow-line magneto-optical trap (MOT) is destabilized…

Atomic Physics · Physics 2009-11-13 Andrew J. Berglund , James L. Hanssen , Jabez J. McClelland

Collisions between cold molecules are essential for studying fundamental aspects of quantum chemistry, and may enable formation of quantum degenerate molecular matter by evaporative cooling. However, collisions between trapped, naturally…

We consider the practical feasibility of using the direct, electric dipole-dipole interaction between co-trapped molecular ions for robust quantum logic without the need for static polarizing fields. The use of oscillating dipole moments,…

Atomic Physics · Physics 2018-10-31 Eric R. Hudson , Wesley C. Campbell

$Aims$: We revisit with new augmented accuracy the theoretical dynamics of basic isotope exchange reactions involved in the $^{12}$C/$^{13}$C, $^{16}$O/$^{18}$O, and $^{14}$N/$^{15}$N balance because these reactions have already been…

Astrophysics of Galaxies · Physics 2015-06-19 Mirjana Mladenović , Evelyne Roueff

Electrostatic cooling is known to occur in conductors and in porous electrodes in contact with aqueous electrolytes. Here we present for the first time evidence of electrostatic cooling at the junction of two electrolyte phases. These are,…

Chemical Physics · Physics 2019-12-24 S. Porada , H. V. M. Hamelers , P. M. Biesheuvel

We report direct laser cooling of a symmetric top molecule, reducing the transverse temperature of a beam of calcium monomethoxide (CaOCH$_3$) to $1.8\pm0.7$ mK while addressing two distinct nuclear spin isomers. These results open a path…

One limit to the fidelity of quantum logic operations on trapped ions arises from heating of the ions' collective modes of motion. Sympathetic cooling of the ions during the logic operations may eliminate this source of errors. We discuss…

It is shown that the dipole moment of polar (water, methanol, formamide, acetone and acetonitrile) molecules in the neighborhood of a cation is increased primarily by polarization from the bare electrostatic charge of the cation, although…

Chemical Physics · Physics 2021-03-31 Imre Bakó , Dániel Csókás , István Mayer , Szilvia Pothoczki , László Pusztai

We realize a continuous guided beam of cold deuterated ammonia with a flux of 3e11 ND3 molecules/s and a continuous free-space beam of cold potassium with a flux of 1e16 K atoms/s. A novel feature of the buffer gas source used to produce…

Atomic Physics · Physics 2015-05-13 David Patterson , Julia Rasmussen , John M. Doyle

We present first indications of sympathetic cooling between two neutral, optically trapped atomic species. Lithium and cesium atoms are simultaneously stored in an optical dipole trap formed by the focus of a CO$_2$ laser, and allowed to…

Atomic Physics · Physics 2017-08-23 S. Kraft , M. Mudrich , K. Singer , R. Grimm , A. Mosk , M. Weidemueller

We demonstrate the long-term ($<$ 1 minute) trapping of Stark-decelerated OH radicals in their $X~^{2}\Pi _{3/2}~(\nu = 0,~J = 3/2,~M_{J} = 3/2,~f)$ state in a permanent magnetic trap. The trap environment was cryogenically cooled to a…

Chemical Physics · Physics 2019-08-05 Dominik Haas , Claudio von Planta , Thomas Kierspel , Dongdong Zhang , Stefan Willitsch

We demonstrate simple and robust methods for Doppler cooling and obtaining high fluorescence from trapped 43Ca+ ions at a magnetic field of 146 Gauss. This field gives access to a magnetic-field-independent "atomic clock" qubit transition…

Hybrid ion-atom systems provide an excellent platform for studies of state-resolved quantum chemistry at low temperatures, where quantum effects may be prevalent. Here we study theoretically the process of vibrational relaxation of an…

Atomic Physics · Physics 2020-04-01 Krzysztof Jachymski , Florian Meinert