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Long-range charge-transfer excitations pose a major challenge for time-dependent density functional approximations. We show that spin-symmetry-breaking offers a simple solution for molecules composed of open-shell fragments, yielding…

Chemical Physics · Physics 2015-03-17 Johanna I. Fuks , Angel Rubio , Neepa T. Maitra

We investigate the use of orbital-optimized references in conjunction with single-reference coupled-cluster theory with single and double substitutions (CCSD) for the study of core excitations and ionizations of 18 small organic molecules,…

In first-principles calculations, hybrid functional is often used to improve accuracy from local exchange correlation functionals. A drawback is that evaluating the hybrid functional needs significantly more computing effort. When…

Materials Science · Physics 2018-02-05 Maoyuan Wang , Gui-Bin Liu , Hong Guo , Yugui Yao

Reduced-density-matrix-functional theory is applied to open-shell systems. We introduce a spin-restricted formulation by appropriately expressing approximate correlation-energy functionals in terms of spin-dependent occupation numbers and…

Strongly Correlated Electrons · Physics 2007-05-23 N. N. Lathiotakis , N. Helbig , E. K. U. Gross

In unparticle physics, operators of the conformal sector have self-interactions, and these are unsuppressed for strong coupling. The 3-point interactions are completely determined by conformal symmetry, up to a constant. We do not know of…

High Energy Physics - Phenomenology · Physics 2008-11-26 Jonathan L. Feng , Arvind Rajaraman , Huitzu Tu

Chiral induced spin selectivity (CISS) describes efficient spin filtering by chiral molecules. This phenomenon has led to nanoscale manipulation of quantum spins with promising applications to spintronics and quantum computing, since its…

Quantum Physics · Physics 2021-01-01 Xiaopeng Li , Jue Nan , Xiangcheng Pan

We theoretically investigate the dynamics of modulation instability (MI) in two-dimensional spin-orbit coupled Bose-Einstein condensates (BECs). The analysis is performed for equal densities of pseudo-spin components. Different combination…

Quantum Gases · Physics 2017-05-22 S. Bhuvaneswari , K. Nithyanandan , P. Muruganandam , K. Porsezian

In exotic atomic systems with hadronic constituent particles, it is notoriously difficult to estimate the strong-interaction correction to energy levels. It is well known that, due to the strength of the nuclear interaction, the problem…

Atomic Physics · Physics 2025-09-12 G. S. Adkins , U. D. Jentschura

A simulation study of measurements of neutral current structure functions of the nucleon at the future high-energy and high-luminosity polarized electron-ion collider (EIC) is presented. A new series of $\gamma-Z$ interference structure…

Nuclear Experiment · Physics 2017-06-20 Y. X. Zhao , A. Deshpande , J. Huang , K. S. Kumar , S. Riordan

We present a rigorous framework that combines single-particle Green's function theory with density functional theory based on a separation of electron-electron interactions into short-range and long-range components. Short-range…

Chemical Physics · Physics 2018-06-07 Alexei A. Kananenka , Dominika Zgid

Spin-currents and non-abelian gauge potentials in electronic systems can be treated by spin-current-density functional theory, whose main input is the exchange-correlation (xc) energy expressed as a functional of spin-currents. Constructing…

Materials Science · Physics 2010-03-30 Saeed H. Abedinpour , G. Vignale , I. V. Tokatly

Spin fluctuations have a substantial influence on the electron and lattice behaviors in magnetic materials, which, however, is difficult to be tracked properly by prevalent first-principles methods. We propose a versatile self-adaptive…

Materials Science · Physics 2023-02-14 Zefeng Cai , Ke Wang , Yong Xu , Su-Huai Wei , Ben Xu

We study the effects of inelastic dark matter self-interactions on the internal structure of a simulated Milky Way (MW)-size halo. Self-interacting dark matter (SIDM) is an alternative to collisionless cold dark matter (CDM) which offers a…

Astrophysics of Galaxies · Physics 2020-11-04 Kun Ting Eddie Chua , Karia Dibert , Mark Vogelsberger , Jesús Zavala

A new reference state for density functional theory, termed the independent atom ansatz, is introduced in this work. This ansatz allows for the exact representation of electron density in terms of non-interacting, atom-localized orbitals.…

Chemical Physics · Physics 2024-05-03 Alexander V. Mironenko

We study $N$ interacting massless Dirac fermions confined in a two-dimensional quantum dot. Physical realizations of this problem include a graphene monolayer and the surface state of a strong topological insulator. We consider both a…

Mesoscale and Nanoscale Physics · Physics 2011-02-15 Tomi Paananen , Reinhold Egger , Heinz Siedentop

The self-screening error in electronic structure theory is the part of the self-interaction error that would remain within the $GW$ approximation if the exact dynamically screened Coulomb interaction, $W$, were used, causing each electron…

Materials Science · Physics 2021-01-15 Jack Wetherell , Matthew Hodgson , Rex Godby

The topology of cosmic reionization, the sizes, shapes, and connectivity of ionized bubbles is a primary observable of next-generation 21\,cm experiments. We show that this topology is sensitive to the microphysics of dark matter.…

Cosmology and Nongalactic Astrophysics · Physics 2026-04-17 Zihan Wang

Ensemble density-functional theory (eDFT) suffers from the so-called "ghost interaction" error when approximate exchange-correlation functionals are used. In this work, we present a rigorous ghost interaction correction (GIC) scheme in the…

Chemical Physics · Physics 2016-07-21 Md. Mehboob Alam , Stefan Knecht , Emmanuel Fromager

An accurate description of the two-electron density, crucial for magnetic coupling in spin systems, provides in general a major challenge for density functional theory calculations. It affects, e.g., the calculated zero-field splitting…

Quantum Physics · Physics 2020-05-06 Timur Biktagirov , Wolf Gero Schmidt , Uwe Gerstmann

We present a novel route to constructing cost-efficient semi-empirical approximations for the non-additive kinetic energy in subsystem density functional theory. The developed methodology is based on the use of Slater determinants composed…

Chemical Physics · Physics 2025-01-13 Larissa Sophie Eitelhuber , Denis G. Artiukhin
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