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An equation describing the irreversible evolution of the local density of a continuous medium without involving any statistical hypotheses and assumptions is derived. The derivation is based on the smoothing of the microscopic dynamic…

Statistical Mechanics · Physics 2018-10-02 Victor V. Zubkov

We study the equilibrium fluctuations for a gradient exclusion process with conductances in random environments, which can be viewed as a central limit theorem for the empirical distribution of particles when the system starts from an…

Probability · Mathematics 2011-04-08 Jonathan Farfan , Alexandre B. Simas , Fabio J. Valentim

It will be shown, how the Boltzmannian ideas on statistical physics can be naturally applied to nonequilibrium thermodynamics. A similar approach for treating nonequilibrium phenomena has been successfully used by Einstein and Smoluchowski…

Statistical Mechanics · Physics 2007-05-23 W. Pietsch

We show for Markov diffusion processes that the quadratic entropic bound, recently derived for the rate functions of nonequilibrium currents, can be seen as being produced by an effective process that creates current fluctuations in a…

Statistical Mechanics · Physics 2023-03-30 Cesare Nardini , Hugo Touchette

Quantum uncertainty relations are formulated in terms of relative entropy between distributions of measurement outcomes and suitable reference distributions with maximum entropy. This type of entropic uncertainty relation can be applied…

Quantum Physics · Physics 2021-06-07 Stefan Floerchinger , Tobias Haas , Ben Hoeber

In a recent work by Cuetara et al. (Phys. Rev. E 89, 052119 (2014)), the authors claimed that if a system is prepared under suitable initial conditions, then the total entropy production (EP) for the system and reservoirs can be expressed…

Statistical Mechanics · Physics 2016-01-19 Jae Sung Lee , Sourabh Lahiri , Chulan Kwon

From the perspective of quantum thermodynamics, realisable measurements cost work and result in measurement devices that are not perfectly correlated with the measured systems. We investigate the consequences for the estimation of work in…

Quantum Physics · Physics 2019-11-05 Tiago Debarba , Gonzalo Manzano , Yelena Guryanova , Marcus Huber , Nicolai Friis

For a certain class of isolated quantum systems, we report the existence of irreversible processes in which the energy is not dissipated. After a closed cycle in which the initial energy distribution is fully recovered, the expectation…

Quantum Physics · Physics 2015-09-30 Ricardo Puebla , Armando Relaño

Evaluating the entropy production (EP) along a stochastic trajectory requires the knowledge of the system probability distribution, an ensemble quantity notoriously difficult to measure. In this paper, we show that the EP of nonautonomous…

Statistical Mechanics · Physics 2015-06-18 Gregory Bulnes Cuetara , Massimiliano Esposito , Alberto Imparato

Systems coupled to multiple thermodynamic reservoirs can exhibit nonequilibrium dynamics, breaking detailed balance to generate currents. To power these currents, the entropy of the reservoirs increases. The rate of entropy production, or…

Statistical Mechanics · Physics 2019-04-16 Junang Li , Jordan M. Horowitz , Todd R. Gingrich , Nikta Fakhri

Thermodynamics of quantum coherence has attracted growing attention recently, where the thermodynamic advantage of quantum superposition is characterized in terms of quantum thermodynamics. We investigate thermodynamic effects of quantum…

Statistical Mechanics · Physics 2017-10-25 Yûto Murashita , Zongping Gong , Yuto Ashida , Masahito Ueda

Fluctuation theorems establish that thermodynamic processes at the microscale can occasionally result in negative entropy production. At the microscale, another distinct possibility becomes more likely: processes in which no entropy is…

Statistical Mechanics · Physics 2026-03-11 Abhaya S. Hegde , André M. Timpanaro , Gabriel T. Landi

Through extended consideration of two wide classes of case studies -- dilute gases and linear systems -- I explore the ways in which assumptions of probability and irreversibility occur in contemporary statistical mechanics, where the…

Statistical Mechanics · Physics 2021-04-23 David Wallace

The appealing theoretical measure of irreversibility in a stochastic process, as the ratio of the probabilities of a trajectory and its time reversal, cannot be accessed directly in experiment since the probability of a single trajectory is…

Statistical Mechanics · Physics 2022-04-14 Julian Kappler , Ronojoy Adhikari

The rate of entropy production by a stochastic process quantifies how far it is from thermodynamic equilibrium. Equivalently, entropy production captures the degree to which detailed balance and time-reversal symmetry are broken. Despite…

Statistical Mechanics · Physics 2020-12-02 Luca Cocconi , Rosalba Garcia-Millan , Zigan Zhen , Bianca Buturca , Gunnar Pruessner

Isometric fluctuation relations are deduced for the fluctuations of the order parameter in equilibrium systems of condensed-matter physics with broken discrete or continuous symmetries. These relations are similar to their analogues…

Statistical Mechanics · Physics 2016-12-14 David Lacoste , Pierre Gaspard

Typically, the entropy of an isolated system in equilibrium is calculated by counting the number of accessible microstates, or in more general cases by using the Gibbs formula. In irreversible processes entropy spontaneously increases and…

Statistical Mechanics · Physics 2020-04-16 Taha A Malik , Rafael Lopez-Mobilia

Understanding nonequilibrium systems and the consequences of irreversibility for the system's behavior as compared to the equilibrium case, is a fundamental question in statistical physics. Here, we investigate two types of nonequilbrium…

Statistical Mechanics · Physics 2020-10-26 Thomas Martynec , Sabine H. L. Klapp , Sarah A. M. Loos

Exponential averages that appear in integral fluctuation theorems can be recast as a sum over moments of thermodynamic observables. We use two examples to show that such moment series can exhibit non-uniform convergence in certain singular…

Statistical Mechanics · Physics 2022-05-31 Hila Katznelson , Saar Rahav

The impossibility of attaining equilibrium for cyclic chemical reaction networks with irreversible steps is apparently due to a divergent entropy production rate. A deeper reason seems to be the violation of the detailed balance condition.…

Chemical Physics · Physics 2013-09-05 Kinshuk Banerjee , Kamal Bhattacharyya