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We report on negative thermal expansion (NTE) in the high-field, half-magnetization plateau phase of the frustrated magnetic insulator CdCr2O4. Using dilatometry, we precisely map the phase diagram at fields of up to 30T, and identify a…

Strongly Correlated Electrons · Physics 2019-07-15 L. Rossi , A. Bobel , S. Wiedmann , R. Küchler , Y. Motome , K. Penc , N. Shannon , H. Ueda , B. Bryant

Magnetism-induced negative thermal expansion (NTE) observed in inverse perovskite antiferromagnets Mn3AN (A=Zn, Ga, etc.) is theoretically studied by a classical spin model with competing bond-length-dependent exchange interactions. We…

Strongly Correlated Electrons · Physics 2019-02-26 Masaya Kobayashi , Masahito Mochizuki

A detailed investigation of ZnCr2Se4 is presented which is dominated by strong ferromagnetic exchange but orders antiferromagnetically at T_N = 21 K. Specific heat C and thermal expansion Delta L/L exhibit sharp first-order anomalies at the…

Materials Science · Physics 2015-06-25 J. Hemberger , H. -A. Krug von Nidda , V. Tsurkan , A. Loidl

The discovery of unusual negative thermal expansion (NTE) provides the opportunity to control the common but much desired property of thermal expansion, which is valuable not only in scientific interests but also in practical applications.…

The physical properties of the spinel LiGaCr4S8 have been studied with neutron diffraction, X-ray diffraction, magnetic susceptibility and heat capacity measurements. The neutron diffraction and synchrotron X-ray diffraction data reveal…

Negative thermal expansion (NTE) describes the anomalous propensity of materials to shrink when heated. Since its discovery, the NTE effect has been found in a wide variety of materials with an array of magnetic, electronic and structural…

Materials Science · Physics 2018-11-09 Connor A. Occhialini , G. G. Guzmán-Verri , Sahan U. Handunkanda , Jason N. Hancock

The phenomenon of negative thermal expansion (NTE) deals with the increase of the lattice parameters and the volume of the unit cell when the material is thermally cooled. The NTE is typically associated with thermal phonons and anomalous…

Strongly Correlated Electrons · Physics 2023-03-10 Wojciech Brzezicki , Filomena Forte , Canio Noce , Mario Cuoco , Andrzej M. Oleś

We discovered unique uniaxial negative thermal expansion (NTE) behavior for a weak-itinerant-ferromagnetic phase of CoZr$_{2}$H$_{3.49}$. CoZr$_{2}$ is known as a superconductor exhibiting uniaxial NTE along the $c$-axis, which is called…

Materials Science · Physics 2025-09-26 Yuto Watanabe , Kota Suzuki , Takayoshi Katase , Akira Miura , Aichi Yamashita , Yoshikazu Mizuguchi

We have devised an isotropic interaction potential that gives rise to negative thermal expansion (NTE) behavior in equilibrium many-particle systems in both two and three dimensions over a wide temperature and pressure range (including zero…

Materials Science · Physics 2008-07-24 Mikael C. Rechtsman , Frank H. Stillinger , Salvatore Torquato

We have investigated temperature dependence of the lattice parameters and the unit cell volume of ZnF$_2$ by neutron diffraction and have discovered negative thermal expansion (NTE) at low temperature. To understand why this simple compound…

Materials Science · Physics 2012-07-03 Tapan Chatterji , Mohamed Zbiri , Thomas C. Hansen

We study negative thermal expansion (NTE) in model lattices with multiple atoms per cell and first- and second-nearest neighbor interactions using the (anharmonic) Morse potential. By exploring the phase space of neighbor distances and…

Materials Science · Physics 2016-06-15 Joseph T. Schick , Andrew M. Rappe

The negative thermal expansion (NTE) compound ZrW2O8 has been well-studied because it remains cubic with a nearly constant, isotropic NTE coefficient over a broad temperature range. However, its elastic constants seem just as strange as its…

Materials Science · Physics 2007-05-23 C. Pantea , A. Migliori , P. B. Littlewood , Y. Zhao , H. Ledbetter , T. Kimura , J. Van Duijn , G. R. Kowach

While most solids expand when heated, some materials show the opposite behavior: negative thermal expansion (NTE). In polymers and biomolecules, NTE originates from the entropic elasticity of an ideal, freely-jointed chain. The origin of…

Pressure and temperature dependence of the negative thermal expansion in Zn(CN)$_2$ is fully investigated using molecular dynamics simulations with a built potential model. The advantage of this study allows us to reproduce all the exotic…

Materials Science · Physics 2014-07-02 Hong Fang , Martin T. Dove , Leila H. N. Rimmer , Alston J. Misquitta

Ultrasound velocity measurements of magnesium chromite spinel MgCr$_2$O$_4$ reveal elastic anomalies in the paramagnetic phase that are characterized as due to geometrical frustration. The temperature dependence of the tetragonal shear…

Strongly Correlated Electrons · Physics 2012-10-24 Tadataka Watanabe , Shin-Ichi Ishikawa , Haruki Suzuki , Yusuke Kousaka , Keisuke Tomiyasu

Negative thermal expansion (NTE) is unusual but important property for control of thermal expansion. In the present study, the chemical modification is utilized to engineer controllable thermal expansion in cubic NTE ScF3. A broad window of…

Materials Science · Physics 2016-12-09 Xiaojian Wang , Jun Chen , Fei Han , Yang Ren , Tao Wang , Jinxia Deng , Xianran Xing

In this study, we report for the first time the occurrence and investigation of the negative thermal expansion (NTE) effect in rare-earth pyrochlores. It is found that the NTE originates from the migration of oxygen anions from 48f sites to…

Materials Science · Physics 2025-07-24 Yuxuan Wang , Guoqiang Lan , Jun Song

Inelastic neutron scattering technique is employed to investigate the paramagnetic spin dynamics in a single crystalline sample of the magnetocaloric compound MnFe$_4$Si$_3$. In the investigated temperature range, 1.033$\times T_{C}$ to…

Materials Science · Physics 2025-02-21 N. Biniskos , K. Schmalzl , J. Persson , S. Raymond

Negative thermal expansion in ZrW2O8 was investigated using a flexibility analysis of ab-initio phonons. It was shown that no previously proposed mechanism adequately describes the atomic-scale origin of negative thermal expansion in this…

Materials Science · Physics 2016-02-17 Leila H. N. Rimmer , Martin T. Dove , Keith Refson

We report the thermal expansion, critical behavior, magnetocaloric effect (MCE), and magnetoresistance ($MR$) on the polycrystalline Mn$_{1.4}$Fe$_{3.6}$Si$_{3}$ compound around the ferromagnetic transition. A large negative volume thermal…

Strongly Correlated Electrons · Physics 2021-08-11 Vikram Singh , R. Nath
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