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Using the first seven known virial coefficients and forcing it to possess two branch-point singularities, a new equation of state for the hard-sphere fluid is proposed. This equation of state predicts accurate values of the higher virial…

Soft Condensed Matter · Physics 2009-06-26 Andrés Santos , Mariano López de Haro

The equation of state for five-dimensional hard hyperspheres arising as a weighted average of the Percus-Yevick compressibility (3/5) and virial (2/5) equations of state is considered. This Carnahan-Starling-like equation turns out to be…

Statistical Mechanics · Physics 2007-05-23 A. Santos

A simple recipe to derive the compressibility factor of a multicomponent mixture of d-dimensional additive hard spheres in terms of that of the one-component system is proposed. The recipe is based (i) on an exact condition that has to be…

Statistical Mechanics · Physics 2019-05-23 A. Santos , S. B. Yuste , M. Lopez de Haro

A new approach to the averaged two-particle distribution function of a crystalline phase is presented. It includes an indirect check of the merit of the Gaussian approximation for the local density and a new way to inferring values of the…

Condensed Matter · Physics 2009-10-28 C. Rascon , L. Mederos , G. Navascues

The equation of state of a hard sphere fluid at high density should exhibit a simple pole at the random close packing limit. Here we show that trying to obtain a compact semi-empirical equation of state simultaneously compatible with that…

Soft Condensed Matter · Physics 2019-08-14 Richard Bonneville

A new analytical approach to derive an approximate equation of state and the virial coefficients for simple fluids is presented. Starting from the usual expression of the partition function, we first perform a Fourier transformation, and…

General Physics · Physics 2017-06-30 Richard Bonneville

A new closed virial equation of state of hard-sphere fluids is proposed which reproduces the calculated or estimated values of the first sixteen virial coefficients at the same time as giving very good accuracy when compared with computer…

Chemical Physics · Physics 2016-07-14 Jianxiang Tian , Yuanxing Gui , Angel Mulero

We develop the Cauchy theory of the spatially homogeneous inelastic Boltzmann equation for hard spheres, for a general form of collision rate which includes in particular variable restitution coefficients depending on the kinetic energy and…

Analysis of PDEs · Mathematics 2016-08-16 Stéphane Mischler , Clément Mouhot , Mariano Rodriguez Ricard

The equation of state for a two-dimensional hard-sphere gas is difficult to calculate by usual methods. In this paper we develop an approach for calculating the equation of state of hard-sphere gases, both for two- and three-dimensional…

Statistical Mechanics · Physics 2009-11-11 Wu-Sheng Dai , Mi Xie

Based on the survey of the literatures on the new improvements on the equation of state (EOS) for the hard sphere fluids, we here compare lots of different EOSs and present a very accurate equation of state for this kind of fluids. The new…

Soft Condensed Matter · Physics 2025-12-08 Can Cui , Jianxiang Tian

We propose a new semi empirical expression of the virial coefficients for a hard sphere fluid which is valid in the disordered phase over the whole density range. The results are in good agreement with the numerical data and better than…

Statistical Mechanics · Physics 2016-03-15 Richard Bonneville

The well-known Carnahan-Starling (CS) equation of state (EoS) [1] for the hard sphere (HS) fluid was derived from a quadratic relation between the integer portions of the virial coefficients, Bn, and their orders, n. Here we extend the…

Soft Condensed Matter · Physics 2021-06-02 Hongqin Liu

In this work we present a numerical study, based on molecular dynamics simulations, to estimate the freezing point of hard spheres and hypersphere systems in dimension D = 4, 5, 6 and 7. We have studied the changes of the Radial…

Soft Condensed Matter · Physics 2015-03-13 C. D. Estrada , M. Robles

A recent proposal in which the equation of state of a polydisperse hard-sphere mixture is mapped onto that of the one-component fluid is extrapolated beyond the freezing point to estimate the jamming packing fraction $\phi_\text{J}$ of the…

Statistical Mechanics · Physics 2014-05-01 Andrés Santos , Santos B. Yuste , Mariano López de Haro , Gerardo Odriozola , Vitaliy Ogarko

Recent values for virial coefficients up to B12, when expressed in powers of density relative to maximum close packing,lead to a closed equation-of-state for the equilibrium fluid. The series obtained converges for all densities;it becomes…

Statistical Mechanics · Physics 2008-02-02 Leslie V. Woodcock

This manuscript investigates the following aspects of the one dimensional dissipative Boltzmann equation associated to variable hard-spheres kernel: (1) we show the optimal cooling rate of the model by a careful study of the system…

Analysis of PDEs · Mathematics 2015-05-28 Ricardo Alonso , Véronique Bagland , Yingda Cheng , Bertrand Lods

We evidence via a computation in the reciprocal space the asymptotic behaviour of the high order virial coefficients for a hard sphere system. These coefficients, if their order is high enough, are those of a geometric series. We thus are…

Statistical Mechanics · Physics 2015-03-23 Richard Bonneville

The scaling form of the critical equation of state is computed for $O(N)$-symmetric models. We employ a method based on an exact flow equation for a coarse grained free energy. A suitable truncation is solved numerically.

High Energy Physics - Theory · Physics 2009-10-28 J. Berges , N. Tetradis , C. Wetterich

The London ground-state energy formula as a function of number density for a system of identical boson hard spheres, corrected for the reduced mass of a pair of particles in a sphere-of-influence picture, and generalized to fermion…

Statistical Mechanics · Physics 2009-11-13 M. A. Solís , M. de Llano , J. W. Clark , George A. Baker

A recent paper [I. Klebanov et al. \emph{Mod. Phys. Lett. B} \textbf{22} (2008) 3153; arXiv:0712.0433] claims that the exact solution of the Percus-Yevick (PY) integral equation for a system of hard spheres plus a step potential is…

Soft Condensed Matter · Physics 2009-11-09 Andrés Santos
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