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Adsorption of surfactants to fluid interfaces occurs in daily-life and technological contexts like dish washing and oil spill remediation. The surfactant surface coverage $\Gamma$ governs interface characteristics like tension $\gamma$,…

Soft Condensed Matter · Physics 2025-12-01 Kay-Robert Dormann , Joshua Reed , Daniel Mitlewski , Matej Kanduč , Benno Liebchen , Emanuel Schneck

We review a new theoretical approach to the kinetics of surfactant adsorption at fluid-fluid interfaces. It yields a more complete description of the kinetics both in the aqueous solution and at the interface, deriving all equations from a…

Soft Condensed Matter · Physics 2012-07-19 H. Diamant , D. Andelman

We present a theory for the kinetics of surfactant adsorption at the interface between an aqueous solution and another fluid (air, oil) phase. The model relies on a free-energy formulation. It describes both the diffusive transport of…

Condensed Matter · Physics 2007-05-23 H. Diamant , D. Andelman

We present a model treating the kinetics of adsorption of soluble surface-active molecules at the interface between an aqueous solution and another fluid phase. The model accounts for both the diffusive transport inside the solution and the…

Soft Condensed Matter · Physics 2007-05-23 H. Diamant , D. Andelman

We develop a computational model to simulate the immediate post-impact spreading behaviour of surfactant-laden drops that impact a flat and solid surface. The model is built on the InterFoam solver (OpenFOAM software), which uses the…

An arbitrary Lagrangian--Eulerian (ALE) finite element scheme for computations of soluble surfactant droplet impingement on a horizontal surface is presented. The numerical scheme solves the time-dependent Navier--Stokes equations for the…

Fluid Dynamics · Physics 2016-09-19 Sashikumaar Ganesan

While the surface charge of solid particles is a direct consequence of their synthesis, the one of suspended oil drops depends on the adsorption equilibrium of the surrounding molecules. The presence of salt raises the polarity of the water…

Soft Condensed Matter · Physics 2020-07-23 Daniela Diaz , Kareem Rahn-Chique , German Urbina-Villalba

We investigated the effect of surfactants on an interface between two kinds of liquid by molecular dynamics simulation. We adopted the simple bead-spring model with two atoms as the surfactants. We controlled the interfacial tension of the…

Statistical Mechanics · Physics 2024-10-14 Shunta Kikuchi , Hiroshi Watanabe

Using a hydrodynamic lattice-gas model, we study interface growth in a binary fluid with various concentrations of surfactant. We find that the interface is smoothed by small concentrations of surfactant, while microemulsion droplets form…

Condensed Matter · Physics 2009-10-28 Francis W. Starr , Stephen T. Harrington , Bruce M. Boghosian , H. Eugene Stanley

We adapt and extend a formulation for soluble surfactant transport in multiphase flows recently presented by Muradoglu & Tryggvason (JCP 274 (2014) 737-757) to the context of the Level Contour Reconstruction Method (Shin et al. IJNMF 60…

Computational Engineering, Finance, and Science · Computer Science 2018-03-14 Seungwon Shin , Jalel Chergui , Damir Juric , Lyes Kahouadji , Omar K. Matar , Richard V. Craster

We present three-dimensional numerical simulations, employing the well-established lattice Boltzmann method, and investigate similarities and differences between surfactants and nanoparticles as additives at a fluid-fluid interface. We…

Soft Condensed Matter · Physics 2012-07-26 Stefan Frijters , Florian Günther , Jens Harting

Surfactant choice is key in starting the phenomena of artificial morphogenesis, the bottom-up growth of geometric particles from cooled emulsion droplets, as well as the bottom-up self-assembly of rechargeable microswimmer robots from…

The adsorption at the interface between an aqueous solution of several surface-active agents and another fluid (air or oil) phase is addressed theoretically. We derive the kinetic equations from a variation of the interfacial free energy,…

Soft Condensed Matter · Physics 2007-05-23 G. Ariel , H. Diamant , D. Andelman

Particles at fluid-fluid interfaces have a wide range of important applications in industry, technology and science. Questions remain about what governs adsorption dynamics and inter-particle interactions, and how mixtures -- both of…

Soft Condensed Matter · Physics 2025-07-10 Anne Y. Schumacher

The effects of surfactant coating on a deformable viscous drop under the combined action of a shear flow and a uniform electric field, are investigated by solving the coupled equations of electrostatics, fluid flow and surfactant transport.…

Fluid Dynamics · Physics 2019-10-30 Antarip Poddar , Shubhadeep Mandal , Aditya Bandopadhyay , Suman Chakraborty

The Gibbs adsorption equation is the thermodynamic cornerstone for the description and understanding of the surface tension in a surfactant solution. It relates the decrease in surface tension to an increased surfactant adsorption. In the…

Soft Condensed Matter · Physics 2025-09-25 Edgar M. Blokhuis

A systematically designed study has been conducted to understand and clearly demarcate the degree of contribution by the constituting elements to the surface tension of nanocolloids. The effects of elements such as surfactants, particles…

Soft Condensed Matter · Physics 2016-10-20 A R Harikrishnan , Purbarun Dhar , PK Agnihotri , Sateesh Gedupudi , Sarit K Das

Emulsion Stability Simulations (ESS) of deformable droplets are used to study the influence of the time-dependent adsorption on the coalescence time of a 200-$\mu$m drop of soybean oil pressed by buoyancy against a planar water/oil…

Soft Condensed Matter · Physics 2013-05-24 Clara Rojas , Maximo Garcia-Sucre , German Urbina-Villalba

The surfactant-driven spreading of droplets is an essential process in many applications ranging from coating flow technology to enhanced oil recovery. Despite the significant advancement in describing spreading processes in…

Fluid Dynamics · Physics 2019-09-04 Panagiotis E. Theodorakis , Edward R. Smith , Erich A. Müller

The three-phase contact line of a droplet on a smooth surface can be characterized by the Young-Dupr\'e equation. It relates the interfacial energies with the macroscopic contact angle $\theta_e$. On the mesoscale, wettability is modeled by…

Fluid Dynamics · Physics 2018-07-24 Uwe Thiele , Jacco H. Snoeijer , Sarah Trinschek , Karin John
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