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We examine the question of whether the formal expressions of equilibrium statistical mechanics can be applied to time independent non-dissipative systems that are not in true thermodynamic equilibrium and are nonergodic. By assuming the…

Statistical Mechanics · Physics 2007-11-09 Stephen R. Williams , Denis J. Evans

In this paper we consider a telegraph equation with time-dependent coefficients, governing the persistent random walk of a particle moving on the line with a time-varying velocity $c(t)$ and changing direction at instants distributed…

Probability · Mathematics 2020-01-09 Luca Angelani , Roberto Garra

We study the effect of an external harmonic trapping potential on an outcome of the non-adiabatic quantum phase transition from an antiferromagnetic to a phase-separated state in a spin-1 atomic condensate. Previously, we demonstrated that…

Quantum Gases · Physics 2016-11-02 Tomasz Świsłocki , Emilia Witkowska , Michał Matuszewski

In this comparative study we benchmark a recently developed non-adiabatic exchange-correlation potential within time-dependent density functional theory (TDDFT) (Phys.\ Rev.\ Lett.\ {\bf 120}, 157701 (2018)) by (a) validating the transient…

Statistical Mechanics · Physics 2019-02-20 Niklas Dittmann , Nicole Helbig , Dante M. Kennes

The dynamics of a closed quantum system is often studied with the direct evolution of the Schrodinger equation. In this paper, we propose that the gauge choice (i.e. degrees of freedom irrelevant to physical observables) of the Schrodinger…

Numerical Analysis · Mathematics 2020-02-20 Dong An , Lin Lin

In this paper, we analyze, by using a matrix approach, the dynamics of a non-relativistic particle in presence of a quaternionic potential barrier. The matrix method used to solve the quaternionic Schrodinger equation allows to obtain a…

Mathematical Physics · Physics 2015-05-20 Stefano De Leo , Gisele Ducati , Vinicius Leonardi , Kenia Pereira

We identify peak and valley structures in the exact exchange-correlation potential of time-dependent density functional theory that are crucial for time-resolved electron scattering in a model one-dimensional system. These structures are…

Chemical Physics · Physics 2018-01-03 Yasumitsu Suzuki , Lionel Lacombe , Kazuyuki Watanabe , Neepa T. Maitra

The validity of the adiabatic approach to spin-Peierls transitions is assessed. An alternative approach is developed which maps the initial magneto-elastic problem to an effective magnetic problem only. Thus the equivalence of…

Strongly Correlated Electrons · Physics 2009-10-31 Goetz S. Uhrig

We investigate the evolution of an electron undergoing coherent tunneling via adiabatic passage (CTAP) using the solution of the one-dimensional Schroedinger equation in both space and time for a triple well potential. We find the…

Mesoscale and Nanoscale Physics · Physics 2008-06-18 Jared H. Cole , Andrew D. Greentree , L. C. L. Hollenberg , S. Das Sarma

Multi-agent Markov Decision Processes (MMDPs) arise in a variety of applications including target tracking, control of multi-robot swarms, and multiplayer games. A key challenge in MMDPs occurs when the state and action spaces grow…

Multiagent Systems · Computer Science 2021-03-31 Dinuka Sahabandu , Luyao Niu , Andrew Clark , Radha Poovendran

We study the non-stationary Feller process with time varying coefficients. We obtain the exact probability distribution exemplified by its characteristic function and cumulants. In some particular cases we exactly invert the distribution…

Statistical Mechanics · Physics 2016-02-17 Jaume Masoliver

In this paper, a connection between bi-free probability and the theory of non-commutative stochastic processes is examined. Specifically it is demonstrated that the transition operators for non-commutative stochastic processes can be…

Operator Algebras · Mathematics 2022-04-26 Paul Skoufranis

We discuss systematically several possible inequivalent ways to describe the dynamics and the transition probabilities of a quantum system when its hamiltonian is not self-adjoint. In order to simplify the treatment, we mainly restrict our…

Mathematical Physics · Physics 2015-06-24 Fabio Bagarello

Quantum molecular dynamics requires an accurate representation of the molecular potential energy surface from a minimal number of electronic structure calculations, particularly for nonadiabatic dynamics where excited states are required.…

Chemical Physics · Physics 2016-08-24 Charles W. Heaps , David A. Mazziotti

We study the exact Time-Dependent Potential Energy Surface (TDPES) in the presence of strong non-adiabatic coupling between the electronic and nuclear motion. The concept of the TDPES emerges from the exact factorization of the full…

Chemical Physics · Physics 2013-02-07 Ali Abedi , Federica Agostini , Yasumitsu Suzuki , E. K. U. Gross

It has been noticed that when the waiting time distribution exhibits a transition from an intermediate time power law decay to a long-time exponential decay in the continuous time random walk model, a transition from anomalous diffusion to…

Analysis of PDEs · Mathematics 2023-05-23 Zhe Xue , Yuan Zhang , Zhennan Zhou , Min Tang

Chemical relaxation phenomena, including photochemistry and electron transfer processes, form a vigorous area of research in which nonadiabatic dynamics plays a fundamental role. Here, we show that for nonadiabatic dynamics with two…

Chemical Physics · Physics 2022-07-20 Yanze Wu , Xuezhi Bian , Jonathan Rawlinson , Robert G. Littlejohn , Joseph E. Subotnik

The interrelationship between energy and probability conservation is explored from the point of view of statistical physics and non-relativistic quantum mechanics. The simultaneous validity of the law of conservation of energy and the…

General Physics · Physics 2023-05-08 Victor Atanasov

The anomalous dynamical evolution and the crossing of nonadiabatic energy levels are investigated for exactly solvable time-dependent quantum systems through a reverse-engineering scheme. By exploiting a typical driven model, we elucidate…

Quantum Physics · Physics 2020-01-08 Hong Cao , Shao-Wu Yao , Li-Xiang Cen

We introduce an approach to scattering problems in theories with non-Hermitian Hamiltonian, usually known as PT-symmetric quantum theories, by means of the adiabatic switching of the interaction. The modifications of usual methods needed to…

Quantum Physics · Physics 2009-02-04 Hynek Bíla