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The discovery of superconductivity in alkali-ammonia co-intercalated FeSe has generated intensive interest because of their highest Tc (~ 45 K) among iron-chalcogenide superconductors with bulk form. Here, we report the phase diagrams of…

Superconductivity · Physics 2014-12-10 Hechang Lei , Jiangang Guo , Fumitaka Hayashi , Hideo Hosono

We probe the superconducting order parameter of the organic-ion-intercalated FeSe-based superconductor (tetrabutyl ammonium)$_{0.3}$FeSe [(TBA)$_{0.3}$FeSe] using muon-spin relaxation/rotation ($\mu$SR). Zero-field $\mu$SR measurements show…

High-pressure magnetization, structural and 57Fe M\"ossbauer studies were performed on superconducting Rb0.8Fe1.6Se2.0 with Tc = 32.4 K. The superconducting transition temperature gradually decreases on increasing pressure up to 5.0 GPa…

Superconducting iron chalcogenide FeSe has the simplest crystal structure among all the Fe-based superconductors. Unlike other iron pnictides, FeSe exhibits no long range magnetic order accompanying the tetragonal-to-orthorhombic structural…

FeSe is a unique member of the family of iron-based superconductors, not only because of the high values of $T_{c}$ in FeSe monolayer, but also because in bulk FeSe superconductivity emerges inside a nematic phase without competing with…

Superconductivity · Physics 2018-08-29 Jian Kang , Andrey V. Chubukov , Rafael M. Fernandes

FeSe-derived superconductors show some unique behaviors relative to iron-pnictide superconductors, which are very helpful to understand the mechanism of superconductivity in high-Tc iron-based superconductors. The low-energy electronic…

Superconductivity · Physics 2014-12-17 X. F. Lu , N. Z. Wang , H. Wu , Y. P. Wu , D. Zhao , X. Z. Zeng , X. G. Luo , T. Wu , W. Bao , G. H. Zhang , F. Q. Huang , Q. Z. Huang , X. H. Chen

With single crystal X-ray diffraction studies, we compare the structures of three sample showing optimal superconductivity, K0.774(4)Fe1.613(2)Se2, K0.738(6)Fe1.631(3)Se2 and Cs0.748(2)Fe1.626(1)Se2. All have an almost identical ordered…

Superconductivity · Physics 2015-05-27 P. Zavalij , Wei Bao , X. F. Wang , J. J. Ying , X. H. Chen , D. M. Wang , J. B. He , X. Q. Wang , G. F Chen , P-Y Hsieh , Q. Huang , M. A. Green

We studied the electrical transport on $\beta$-Fe$_{4+\delta}$Se$_{5}$ single-crystal nanowires, exhibiting $\sqrt{5}\times\sqrt{5}$ Fe-vacancy order and mixed valence of Fe. We observed a first-order metal-insulator transition of the…

Alkali-doped iron selenide is the latest member of high Tc superconductor family, and its peculiar characters have immediately attracted extensive attention. We prepared high-quality potassium-doped iron selenide (KxFe2-ySe2) thin films by…

Superconductivity · Physics 2015-05-30 Wei Li , Hao Ding , Peng Deng , Kai Chang , Canli Song , Ke He , Lili Wang , Xucun Ma , Jiang-Ping Hu , Xi Chen , Qi-Kun Xue

The FeSe superconductor and its related systems have attracted much attention in the iron-based superconductors owing to their simple crystal structure and peculiar electronic and physical properties. The bulk FeSe superconductor has a…

Superconductivity · Physics 2015-06-24 Xu Liu , Lin Zhao , Shaolong He , Junfeng He , Defa Liu , Daixiang Mou , Bing Shen , Yong Hu , Jianwei Huang , X. J. Zhou

New iron selenide superconductors by intercalating smaller-sized alkali metals (Li, Na) and alkaline earths using high-temperature routes have been pursued ever since the discovery of superconductivity at about 30 K in KFe2Se2, but all have…

Superconductivity · Physics 2012-05-30 T. P. Ying , X. L. Chen , G. Wang , S. F. Jin , T. T. Zhou , X. F. Lai , H. Zhang , W. Y. Wang

The Fe-vacancy ordering patterns in the superconducting KxFe2-ySe2 and non-superconducting Kx(Fe,Co)2-ySe2 samples have been investigated by electron diffraction and high angle annular dark field scanning transmission electron microscopy.…

The nature of the phase separation in KxFe2-ySe2 single crystals is not well understood. Here, temperature dependent SEM images provide compelling evidence that phase separation corresponds to a nucleation and growth process rather than a…

Superconductivity · Physics 2016-02-12 Yong Liu , Qingfeng Xing , Warren E. Straszheim , Jeff Marshman , Pal Pedersen , Thomas A. Lograsso

The discovery of high-temperature superconductivity in FeSe/SrTiO3 has sparked significant interests in exploring new superconducting systems with engineered interfaces. Here, using molecular beam epitaxy growth, we successfully fabricate…

Superconductivity · Physics 2025-02-20 Yunkai Guo , Xuanyu Long , Jingming Yan , Zheng Liu , Qi-Kun Xue , Wei Li

Fe1+xTe0.5Se0.5 is the archetypical iron-based superconductor. Here we show that the superconducting state is controlled by the stacking of its anti-PbO layers, such that homogeneous ordering hinders superconductivity and the highest volume…

Superconductivity · Physics 2011-06-30 Vikas Bhatia , Efrain E. Rodriguez , Nicholas P. Butch , Johnpierre Paglione , Mark A. Green

Emergent electronic phenomena in iron-based superconductors have been at the forefront of condensed matter physics for more than a decade. Much has been learned about the origin and intertwined roles of ordered phases, including nematicity,…

Superconductivity · Physics 2020-09-11 Andreas Kreisel , P. J. Hirschfeld , Brian M. Andersen

Two iron-chalcogenide superconductors Li(x)[C5H5N](y)Fe(2-z)Se2 and Cs(x)Fe(2-z)Se2 in the as-prepared and annealed state have been investigated by means of the Moessbauer spectroscopy versus temperature. Multi-component spectra are…

Superconductivity · Physics 2016-01-20 K. Komedera , A. K. Jasek , A. Blachowski , K. Ruebenbauer , J. Zukrowski , A. Krzton-Maziopa , K. Conder

We present a brief review of the present day situation with studies of high-temperature superconductivity in iron pnictides and chalcogenides. Recent discovery of superconductivity with T_c > 30 K in A_xFe_{2-x/2}Se_2 (A=K,Cs,Tl,...)…

Superconductivity · Physics 2012-08-14 M. V. Sadovskii , E. Z. Kuchinskii , I. A. Nekrasov

Superconductivity with transition temperature Tc above 40 K was observed in protonated FeSe (Hy-FeSe) previously with the ionic liquid of EMIM-BF4 used in the electrochemical process. However, the real superconducting phase is not clear…

Superconductivity · Physics 2021-11-23 Jinhua Wang , Qing Li , Wei Xie , Guanyu Chen , Xiyu Zhu , Hai-Hu Wen

Exploration of new superconductors has always been one of the research directions in condensed matter physics. We report here a new layered heterostructure of [(Fe,Al)(OH)2][FeSe]1.2, which is synthesized by the hydrothermal ion-exchange…