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We combine density-functional theory with density-matrix functional theory to get the best of both worlds. This is achieved by range separation of the electronic interaction which permits to rigorously combine a short-range density…

Chemical Physics · Physics 2015-05-19 Daniel R. Rohr , Julien Toulouse , Katarzyna Pernal

The behavior of mesoscopic particles dissolved in a dilute solution of long, flexible, and nonadsorbing polymer chains is studied by field-theoretic methods. For spherical and cylindrical particles the solvation free energy for immersing a…

Soft Condensed Matter · Physics 2009-10-31 A. Hanke , E. Eisenriegler , S. Dietrich

The effective interaction energy of a colloidal sphere in a suspension containing small amounts of non-ionic polymers and a flat glass surface has been measured and calculated using total internal reflection microscopy (TIRM) and a novel…

Condensed Matter · Physics 2009-10-31 C. Bechinger , D. Rudhardt , P. Leiderer , R. Roth , S. Dietrich

The massive field theory approach in fixed space dimensions $d=3$ is applied to investigate a dilute solution of long-flexible polymer chains in a good solvent between two parallel repulsive walls, two inert walls and for the mixed case of…

Soft Condensed Matter · Physics 2009-10-08 D. Romeis , Z. Usatenko

A density functional theory of two-dimensional freezing is presented for a soft interaction potential that scales as inverse cube of particle distance. This repulsive potential between parallel, induced dipoles is realized for paramagnetic…

Soft Condensed Matter · Physics 2009-05-28 Sven van Teeffelen , Christos N. Likos , Norman Hoffmann , Hartmut Löwen

Depletion forces exerted by self-propelled particles on circular and elliptical passive objects are studied using numerical simulations. We show that a bath of active particles can induce repulsive and attractive forces which are sensitive…

Soft Condensed Matter · Physics 2016-12-05 L. R. Leite , D. Lucena , F. Q. Potiguar , W. P. Ferreira

After a brief review of previous work, two exactly solvable two-dimensional models of a finite Coulomb fluid in a disc are studied. The charge correlation function near the boundary circle is computed. When the disc radius is large compared…

Statistical Mechanics · Physics 2009-11-07 B. Jancovici

The interaction force between likely charged particles/surfaces is usually repulsive due to the Coulomb interaction. However, the counterintuitive like-charge attraction in electrolytes has been frequently observed in experiments, which has…

Soft Condensed Matter · Physics 2016-11-08 Pei Liu , Manman Ma , Zhenli Xu

We analytically study a one dimensional compaction model in the glassy regime. Both correlation and response functions are calculated exactly in the evolving dense and low tapping strength limit, where the density relaxes in a $1/\ln t$…

Statistical Mechanics · Physics 2009-11-10 Martin Depken , Robin Stinchcombe

In order to assess the accuracy of commonly used approximate exchange-correlation density functionals, we present a comparison of accurate exchange and correlation potentials, exchange energy densities and energy components with the…

Condensed Matter · Physics 2007-05-23 Claudia Filippi , Xavier Gonze , C. J. Umrigar

It is shown that the DFT exchange and correlation functionals satisfy an expression that couples exchange and correlation functionals and functional derivatives evaluated at three different densities and for two particle numbers. This…

Materials Science · Physics 2015-05-30 Daniel P. Joubert

Monte Carlo simulation using the Wang-Landau algorithm has been performed in an one-dimensional Lebwohl-Lasher model. Both one-dimensional and two-dimensional random walks have been carried out. The results are compared with the exact…

Statistical Mechanics · Physics 2009-11-13 Kisor Mukhopadhyay , Nababrata Ghoshal , Soumen Kumar Roy

In this paper, we study the truncated two-particle correlation function in particle systems with long range interactions. For Coulombian and soft potentials, we define and give well-posedness results for the equilibrium correlations. In the…

Mathematical Physics · Physics 2018-09-28 Juan J. L. Velázquez , Raphael Winter

Inclusions in mobile brushes experience apparent (depletion) attraction, which arises from a tendency to minimize the volume of depletion zones around the inclusions, thereby to maximize the entropy of the surrounding polymers. Here, we…

Soft Condensed Matter · Physics 2025-07-23 Ji Woong Yu , Daeseong Yong , Bae-Yeun Ha , Changbong Hyeon

Using the specific model of a system of like charged ions confined between two planar like charged surfaces, we compare the predictions for the energy and density profile of four simulation methods available to treat the long range Coulomb…

Statistical Mechanics · Physics 2007-05-23 M. Mazars , J-M. Caillol , J. -J. Weis , D. Levesque

We analyze a decomposition of the Coulomb electron-electron interaction into a long-range and a short-range part in the framework of density functional theory, deriving some scaling relations and the corresponding virial theorem. We study…

Chemical Physics · Physics 2015-06-26 Julien Toulouse , Paola Gori-Giorgi , Andreas Savin

While the density functional theory with integral equations techniques are very efficient tools in numerical analysis of complex fluids, an analytical insight into the phenomenon of effective interactions is still limited. In this paper we…

Soft Condensed Matter · Physics 2014-09-24 M. Majka , P. F. Góra

Most approximate exchange-correlation functionals used within density functional theory are constructed as the sum of two distinct contributions for exchange and correlation. Separating the exchange component from the entire functional is…

Condensed Matter · Physics 2009-10-28 Claudia Filippi , C. J. Umrigar , Xavier Gonze

We consider a random diffusion dynamics for an infinite system of hard spheres of two different sizes evolving in $\mathbb{R}^d$, its reversible probability measure, and its projection on the subset of the large spheres. The main feature is…

Probability · Mathematics 2024-03-05 Myriam Fradon , Julian Kern , Sylvie Roelly , Alexander Zass

Depletion-induced interactions between colloids in colloid-polymer mixtures depend in range and strength on size, shape, and concentration of depletants. Crowding by colloids in turn affects shapes of polymer coils, such as biopolymers in…

Soft Condensed Matter · Physics 2016-02-25 Wei Kang Lim , Alan R. Denton