Related papers: Exciton coupling induces vibronic hyperchromism in…
The prevalence of long-lasting oscillatory signals in the 2d echo-spectroscopy of light-harvesting complexes has led to a search for possible mechanisms. We investigate how two causes of oscillatory signals are intertwined: (i) electronic…
We explore the feasibility of coherent control of excitonic dynamics in light harvesting complexes, analyzing the limits imposed by the open nature of these quantum systems. We establish feasible targets for phase and phase/amplitude…
This article explores the excitation of different vibrational states in a spatially extended dynamical system through theory and experiment. As a prototypical example, we consider a one-dimensional packing of spherical particles (a…
Vibrational polaritons are formed by strong coupling of molecular vibrations and photon modes in an optical cavity. Experiments have demonstrated that vibrational strong coupling can change molecular properties and even affect chemical…
The Frenkel exciton Hamiltonian is at the heart of many simulations of excitation energy transfer in molecular aggregates. It separates the aggregate into Coulomb-coupled monomers. Here it is shown that the respective parameters, i.e.…
We propose that light-matter coupling can be used to realize synthetic lattices. In particular, we consider a one-dimensional chain of exciton-photon sites to create a comb lattice that exhibits a transition from a flat band to a finite…
Transport phenomena in organic, self-assembled molecular J-aggregates have long attracted a great deal of attention due to its potential role in designing novel organic photovoltaic devices. A large number of theoretical and experimental…
A vibronic-exciton model is applied to investigate the mechanism of enhancement of coherent oscillations due to mixing of electronic and nuclear degrees of freedom recently proposed as the origin of the long-lived oscillations in 2D spectra…
Using methods of condensed matter and statistical physics, we examine the transport of excitons through the Fenna-Matthews-Olson (FMO) complex from a receiving antenna to a reaction center. Writing the equations of motion for the exciton…
This study investigated spectral changes in the absorption cross-sections of single strong coupling systems composed of single silver nanoparticle dimers and a few dye molecules during the quenching of surface-enhanced resonant Raman…
An excitonic insulator phase is expected to arise from the spontaneous formation of electron-hole pairs (excitons) in semiconductors where the exciton binding energy exceeds the size of the electronic band gap. At low temperature, these…
This paper establishes the possibility of utilising energy harvesting from mechanical vibrations to estimate extreme value responses of the host structure and demonstrates the calibration of these estimates for excitation spectra typical to…
This work introduces a novel methodology to assess the performance of Piezoelectric Energy Harvesters (PEHs) in order to study auxetic enhancement possibilities. For this purpose, a new approach for evaluating the intrinsic effective…
Recent experiments have revealed the profound effect of strong light-matter interactions in optical cavities on the electronic ground state of molecular systems. This phenomenon, known as vibrational strong coupling (VSC), can modify…
A model of strongly disordered lattice system with long-range Coulomb interactions between localized charge carriers has been considered. The total electronic energy is characterized by the presence of multiple metastable minima (including…
We present a theory of the electronic structure and photophysics of 1:1 blends of derivatives of polyparaphenylenevinylene and fullerenes. Within the same Coulomb-correlated Hamiltonian applied previously to interacting chains of…
Strongly coupled plasmon-exciton systems offer promising applications in nanooptics. The classification of the coupling regime is currently debated both from experimental and theoretical perspectives. We present a method to unambiguously…
Photosynthesis is a plausible pathway for the sustenance of a substantial biosphere on an exoplanet. In fact, it is also anticipated to create distinctive biosignatures detectable by next-generation telescopes. In this work, we explore the…
Classical coupled harmonic oscillator models are capable of describing the optical and infrared response of nanophotonic systems where a cavity photon couples to dipolar matter excitations. The distinct forms of coupling adopted in these…
Raman spectra obtained by the inelastic scattering of light by crystalline solids contain contributions from first-order vibrational processes (e.g. the emission or absorption of one phonon, a quantum of vibration) as well as higher-order…