Related papers: OH+ in Diffuse Molecular Clouds
Observations of W51 with the Submillimeter Wave Astronomy Satellite (SWAS) have yielded the first detection of water vapor in a diffuse molecular cloud. The water vapor lies in a foreground cloud that gives rise to an absorption feature at…
We investigate the chemical evolution of a forming molecular cloud behind an interstellar shock wave. We conduct three-dimensional magnetohydrodynamics simulations of the converging flow of atomic gas, including a simple chemical network…
Hydrides are simple compounds containing one or a few hydrogen atoms bonded to a heavier atom. They are fundamental precursor molecules in cosmic chemistry and many hydride ions have become observable in high quality for the first time…
We have obtained OH spectra of four transitions in the $^2\Pi_{3/2}$ ground state, at 1612, 1665, 1667, and 1720 MHz, toward 51 sightlines that were observed in the Herschel project Galactic Observations of Terahertz C+. The observations…
We have conducted OH 18 cm survey toward 141 molecular clouds in various environments, including 33 optical dark clouds, 98 Planck Galactic cold clumps (PGCCs) and 10 Spitzer dark clouds with the Arecibo telescope. The deviations from local…
The formation of CH+ in the interstellar medium has long been an outstanding problem in chemical models. In order to probe the physical conditions of the ISM in which CH+ forms, we propose the use of CH3+ observations. The pathway to…
I review recent observations of molecular gas in the halo of the Milky Way and in the Magellanic Clouds. Far-ultraviolet absorption line studies of molecular hydrogen (H_2) with ORFEUS and FUSE have unveiled the presence of a diffuse…
The cosmic-ray ionization rate (CRIR, $\zeta_2$) is one of the key parameters controlling the formation and destruction of various molecules in molecular clouds. However, the current most commonly used CRIR tracers, such as H$_3^+$, OH$^+$,…
We report the detection of absorption lines by the reactive ions OH+, H2O+ and H3O+ along the line of sight to the submillimeter continuum source G10.6$-$0.4 (W31C). We used the Herschel HIFI instrument in dual beam switch mode to observe…
OH+ absorption is a powerful tracer of inflowing and outflowing gas in the predominantly atomic diffuse and turbulent halo surrounding galaxies. In this letter, we present observations of OH+(1_1-1_0), CO(9-8) and the underlying dust…
The HyGAL Stratospheric Observatory for Infrared Astronomy (SOFIA) legacy program aims at characterizing the interstellar medium in the Milky Way using hydrides, [C II], and [O I] absorption lines with the 2.7 m SOFIA telescope toward…
The transition between atomic and molecular hydrogen is associated with important changes in the structure of interstellar clouds, and marks the beginning of interstellar chemistry. Because of the relatively simple networks controlling…
Recent observations with the Submillimeter Wave Astronomy Satellite indicate abundances of gaseous H2O and O2 in dense molecular clouds which are significantly lower than found in standard homogeneous chemistry models. We present here…
One of the surprises of the Herschel mission was the detection of ArH+ towards the Crab Nebula in emission and in absorption towards strong Galactic background sources. Although these detections were limited to the first quadrant of the…
Hydroxyl (OH) is expected to be abundant in diffuse interstellar molecular gas as it forms along with $H_2$ under similar conditions and within a similar extinction range. We have analyzed absorption measurements of OH at 1665 MHz and 1667…
Using high resolution infrared spectroscopy we have surveyed twenty sightlines for H3+ absorption. H3+ is detected in eight diffuse cloud sightlines with column densities varying from 0.6x10^14 cm^-2 to 3.9x10^14 cm^-2. This brings to…
We use UV measurements of interstellar CO towards nearby stars to calculate the density in the diffuse molecular clouds containing the molecules responsible for the observed absorption. Chemical models and recent calculations of the…
The internal energy available in vibrationally excited H2 molecules can be used to overcome or diminish the activation barrier of various chemical reactions of interest for molecular astrophysics. In this article we investigate in detail…
Observations of OH$^+$ are used to infer the interstellar cosmic ray ionization rate in diffuse atomic clouds, thereby constraining the propagation of cosmic rays through and the shielding by interstellar clouds, as well as the low energy…
Recent submillimeter and far-infrared wavelength observations of absorption in the rotational ground-state lines of various simple molecules against distant Galactic continuum sources have opened the possibility of studying the chemistry of…