English
Related papers

Related papers: Combined hybrid functional and DFT+$U$ calculation…

200 papers

The spectral functions of the one-band half-filled 1D Hubbard chain are calculated using the exchange-correlation potential formalism developed recently. The exchange-correlation potential is adopted from the exact potential derived from…

Strongly Correlated Electrons · Physics 2022-08-31 F. Aryasetiawan , T. Sjöstrand

We conduct a systematic investigation of the role of Hubbard U corrections in electronic structure calculations of two-dimensional (2D) materials containing 3d transition metals. Specifically, we use density functional theory (DFT) with the…

Materials Science · Physics 2024-11-19 Sahar Pakdel , Thomas Olsen , Kristian S. Thygesen

Accurate determination of electronic properties of correlated oxides remains a significant challenge for computational theory. Traditional Hubbard-corrected density functional theory (DFT+U) frequently encounters limitations in precisely…

Materials Science · Physics 2024-03-19 Hyeondeok Shin , Kevin Gasperich , Tomas Rojas , Anh T. Ngo , Jaron T. Krogel , Anouar Benali

Extending density functional theory (DFT) to an {\it ab initio} orbital functional theory (OFT) requires new methodology for nonlocal exchange and correlation potentials. This paper describes such modifications to a standard Dirac-Slater…

Condensed Matter · Physics 2007-05-23 R. K. Nesbet

We examine the performance of our recently developed LFAs-PBE exchange-correlation (XC) potential [C.-R. Pan, P.-T. Fang, and J.-D. Chai, Phys. Rev. A, 2013, 87, 052510] for the high-order harmonic generation (HHG) spectra and related…

Chemical Physics · Physics 2016-06-14 Hsiao-Ling Sun , Wei-Tao Peng , Jeng-Da Chai

We propose a multiconfigurational hybrid density-functional theory which rigorously combines a multiconfiguration self-consistent-field calculation with a density-functional approximation based on a linear decomposition of the…

Chemical Physics · Physics 2012-08-20 Kamal Sharkas , Andreas Savin , Hans Jørgen Aa. Jensen , Julien Toulouse

A density functional theory (DFT) approach to computing transition metal oxide heat of formation without adjustable parameters is presented. Different degrees of $d$-electron localization in oxides are treated within the DFT+$U$ approach…

Materials Science · Physics 2022-04-01 Johannes Voss

We study the lattice dynamics of antiferromagnetic transition-metal oxides by using self-consistent Hubbard functionals. We calculate the ground states of the oxides with the on-site and intersite Hubbard interactions determined…

Strongly Correlated Electrons · Physics 2022-06-01 Wooil Yang , Bo Gyu Jang , Young-Woo Son , Seung-Hoon Jhi

A novel hybrid scheme is proposed. The {\it ab initio} LDA calculation is used to construct the Wannier functions and obtain single electron and Coulomb parameters of the multiband Hubbard-type model. In strong correlation regime the…

Strongly Correlated Electrons · Physics 2007-05-23 V. A. Gavrichkov , M. M. Korshunov , S. G. Ovchinnikov , I. A. Nekrasov , Z. V. Pchelkina , V. I. Anisimov

Motivated by the resurgence of electronic and optical property design in ordered fluoride and oxyfluoride compounds, we present a density functional theory (DFT) study on 19 materials with structures, ranging from simple to complex, and…

Materials Science · Physics 2016-11-23 Nenian Charles , James M. Rondinelli

The LDA+DMFT method is a very powerful tool for gaining insight into the physics of strongly correlated materials. It combines traditional ab-initio density-functional techniques with the dynamical mean-field theory. The core aspects of the…

Strongly Correlated Electrons · Physics 2017-11-22 Eva Pavarini

Defects in a material can significantly tune properties and enhance utility. Hybrid functionals like HSE06 are often used to describe solids with such defects. However, geometry optimization (including accounting for effects such as…

Computational Physics · Physics 2024-10-14 Raj K. Sah , Michael J. Zdilla , Eric Borguet , John P. Perdew

The so-called local density approximation plus the multi-orbital mean-field Hubbard model (LDA+U) has been implemented within the all-electron projector augmented-wave method (PAW), and then used to compute the insulating antiferromagnetic…

Strongly Correlated Electrons · Physics 2009-10-31 O. Bengone , M. Alouani , P. Bloechl , J. Hugel

Multi-center transition metal complexes (MCTMs) with magnetically interacting ions have been proposed as components for information processing devices and storage units. For any practical application of MCTMs as magnetic units, it is…

Chemical Physics · Physics 2023-04-03 Henry C. Fitzhugh , James W. Furness , Mark R. Pederson , Juan E. Peralta , Jianwei Sun

Including on-site electronic interactions described by the multi-orbital Hubbard model we study the correlation effects in the electronic structure of bulk palladium. We use a combined density functional and dynamical mean field theory,…

Strongly Correlated Electrons · Physics 2016-05-04 A. Östlin , W. H. Appelt , I. Di Marco , W. Sun , M. Radonjic , M. Sekania , L. Vitos , O. Tjernberg , L. Chioncel

The magnetic state of UO$_2$ was determined experimentally to be anti-ferromagnetic. Starting from this experimental fact, researchers have calculated other properties within the Hubbard-corrected density-functional theory, DFT+U. Up to…

Materials Science · Physics 2024-01-03 Mahmoud Payami

In this article, we use hybrid density functional (HSE06) to study the crystal and electronic structures and optical properties of well known phase change memory material $\mathrm{Ge_{2}Sb_{2}Te_{5}}$. We calculate the structural…

Materials Science · Physics 2015-06-05 T. Kaewmaraya , M. Ramzan , 1 H. Löfås , Rajeev Ahuja

The density functional theory (DFT) approximations that are the most accurate for the calculation of band gap of bulk materials are hybrid functionals like HSE06, the MBJ potential, and the GLLB-SC potential. More recently, generalized…

Hybrid density functional approximations (DFAs) offer compelling accuracy for ab initio electronic-structure simulations of molecules, nanosystems, and bulk materials, addressing some deficiencies of computationally cheaper, frequently used…

We present a critical analysis of the popular fragment-orbital density-functional theory (FO-DFT) scheme for the calculation of electronic coupling values. We discuss the characteristics of different possible formulations or 'flavors' of…

Materials Science · Physics 2016-02-17 Christoph Schober , Karsten Reuter , Harald Oberhofer